1、 ENGINEERING MATERIAL SPECIFICATION Date Action Revisions Rev. 0 2011 10 10 Activated Replaces WSK-M4D664-A2 V Cerato, FOE Controlled document at www.MATS Copyright 2011, Ford Global Technologies, LLC Page 1 of 8 POLYAMIDE (PA) 6, HEAT STABILIZED 30% GLASS WSS-M4D664-B1 FIBER REINFORCED MOLDING COMP
2、OUND, INTERIOR POLYAMIDE (PA) 6, HEAT STABILIZED 30% GLASS WRS-M4D664-B2 FIBER REINFORCED MOLDING COMPOUND, INTERIOR, XX% PCR AND/OR PIR CONTENT (The specifications for a recycled version of this resin are under development. Contact Materials Engineering (FoE) for status) 1. SCOPE The material defin
3、ed by this specification is 30% glass fiber reinforced, heat and UV stabilized polyamide 6 molding compound for interior use. Materials with recycled content should be used whenever feasible. 2. APPLICATION This specification was released originally for material used for interior functional parts. 2
4、.1 LIMITATIONS This material absorbs and retains moisture. Part design and tolerances must accommodate changes in part dimensions and physical properties due to moisture absorption or loss in the service/assembly environment. 3. REQUIREMENTS 3.1 STANDARD REQUIREMENTS FOR PRODUCTION MATERIALS Materia
5、l suppliers and part producers must conform to the Companys Standard Requirements for Production Materials (WSS-M99P1111-A). 3.1.1 Many 4D resin specifications prior to 2011, identified certain requirements with the symbol (s), which indicated that the mean and +/- 3 sigma values were to be reported
6、. The specification minimum, maximum or range was established using 3 sigma data. For 2011 and beyond, refer to Table 1 for number of samples required for each test to establish specification limits. 3.1.2 WSS-M4D664-B1 is based on virgin materials. 3.1.3 WRS-M4D664-B2 must contain XX% of recycled c
7、ontent as defined by WRS-M99P42-A1. The remaining portion of the material can come from virgin sources. 3.1.4 The use of regrind is permitted for economic and environmental reasons with compliance as indicated in WSS-M99P1111-A. ENGINEERING MATERIAL SPECIFICATION WSS-M4D664-B1 WRS-M4D664-B2 Copyrigh
8、t 2011, Ford Global Technologies, LLC Page 2 of 8 3.1.5 Dry as molded All test values indicated herein are based on material and specimens with moisture content not exceeding 0.2% except where noted (Moisture Conditioned) (test according to ISO 15512 Method B/ASTM D6869). All test materials have to
9、be sealed in moisture-proof containers and stored at 23 +/- 2 C for at least 24 h immediately after processing. If the moisture content exceeds 0.2%, conditioning the material for a minimum of 16 h at 40 to 50 C at a reduced pressure below 133 kPa. Conduct tests in a controlled atmosphere of 23 +/-
10、2 C and 50 +/- 5% relative humidity. Individual specimens shall not be removed from closed containers until immediately before testing. 3.1.6 Materials used in interior applications must meet the requirements outlined in WSS-M99P2222-C1/Latest, Performance, Vehicle Interior Environment Quality Mater
11、ial/Component Requirements. Data must be included in material submission package. 3.1.7 Mold-in-color parts using this material must comply with all the requirements of WSS-M15P4-F or latest. 3.2 SAMPLE PREPARATION Unless otherwise specified all tests shall be carried out on injection molded, one-en
12、d gated test specimens. The test specimens A and D shall be molded using molding conditions defined in ISO 1874-2. See Tables 1 and 2 for the number of samples required. Specimens shall be as follows: Specimen A 150 minimum x 10 x 4.0 +/- 0.2 mm (ISO 527-2, Specimen Type 1A) Specimen B 355 x 100 x 1
13、.0 +/- 0.1 mm (ISO 3795) Specimen C 145 x 60 x 3.2 +/- 0.2 mm Specimen D Center of Specimen A, 80 x 10 x 4.0 +/- 0.2 mm Specimen E 100 mm diameter x 3.2 mm Specimen F 80 mm diameter x 3.2 mm Specimen G 90 mm x 200 mm Specimen H 50 +/- 1 mm diameter x 3.2 +/- 0.2 mm Specimen I 100 mm x 150 mm, min 3.
14、3 APPEARANCE 3.3.1 Weathering Resistance Rating 4 min (FLTM BO 116-01, 1203.2 kJ/m2 exposure Specimen C from smooth polished mold, ISO 105-A02 / AATCC Evaluation Procedure 1) Every 526.4J/m2 remove the samples from the weatherometer and allow them to cool for one hour. Conduct a tactile evaluation a
15、nd report any tackiness. Visually evaluate and report any spewing or other exudation. ENGINEERING MATERIAL SPECIFICATION WSS-M4D664-B1 WRS-M4D664-B2 Copyright 2011, Ford Global Technologies, LLC Page 3 of 8 After exposure the material shall show no fading or color change in excess of the specified A
16、ATCC rating. In addition, there shall be no cracking, crazing or other deterioration. Use black for initial approval and report the color house used. See Table 2 for additional color durability submission requirements. 3.4 MATERIAL PROPERTIES 3.4.1 Melt Temperature 215 225 C (ISO 11357, 10 C/min hea
17、ting rate) 3.4.2 Glass Fiber Content 27 - 33% (ISO 3451-4, test temperature 600 +/- 25 C, test portion 2 to 2.5 g) 3.4.3 Density 1.34 1.40 g/cm3 (ISO 1183, Method A) 3.4.4 Tensile Strength at Break 150 MPa min (ISO 527-1 60 +/- 2 oC to 120 +/- 2 oC, Cross Flow 11.480 E-5 mm/mm/ C 3.5.3 Water Absorpt
18、ion 0.8-1.4 % 3.5.4 Heat Deflection Temperature At 0.45 MPa 214 C 3.5.5 Flexural Modulus 7.5 GPa 3.5.6 Poissons Ratio 0.40 N/A 3.5.7.1 Impact Strength, Notched Izod At 23 +/- 2 C 10 kJ/m2 3.5.7.2 Impact Strength, Notched Izod At -40 +/- 2 C 8.0 kJ/m2 ENGINEERING MATERIAL SPECIFICATION WSS-M4D664-B1
19、WRS-M4D664-B2 Copyright 2011, Ford Global Technologies, LLC Page 7 of 8 4.2 MATERIAL IDENTIFICATION FOR RECYCLING PURPOSES PA6-GF30 (ISO 1043) Table 1: Minimum Sample Size Initial Approval New Manufacturing Location for Previously Approved Material Para. Test Minimum Lots Specimens per Lot Total Tes
20、t Specimens Lots Specimens per lot Total Test Specimens 3.1 WSS-M99P1111-A 3.1.5 WSS-M99P2222-C1/Latest Total Carbon, Hazardous Substances, Formaldehyde, Acraldehyde, Acetaldehyde (See below for Odor and Fogging) 1 1 1 per test 3.3.1 Weathering Resistance 1 1 1 3.4.1 Melt Temperature* 3 1 3 1 1 1 3.
21、4.2 Filler Content* 3 1 3 1 1 1 3.4.3 Density* 1 3 3 1 3 3 3.4.4 Tensile Strength at Break* 3 5 15 1 5 5 3.4.5 Tensile Modulus 1 10 10 3.4.6 Impact Strength, Notched Charpy (per condition)* 3 10 30 1 10 10 3.4.7 Heat Deflection Temperature* 3 2 6 1 2 2 3.4.8 Heat Aging Performance 3.4.8.1 Impact Str
22、ength, Notched Charpy, Change 1 10 10 3.4.9 Odor 1 9 9 3.4.10 Fogging Photometric 1 3 3 3.4.11 Fogging Gravimetric 1 3 3 3.4.12 Flammability 1 5 5 3.5.1 Mold Shrinkage 1 5 5 1 5 5 3.5.2 Coefficient of Linear Thermal Expansion (per condition) 1 3 3 3.5.3 Water Absorption 1 3 3 3.5.4 Heat Deflection T
23、emperature 1 2 2 3.5.5 Flexural Modulus 3 10 30 1 10 10 3.5.6 Poissons Ratio 1 5 5 3.5.7 Impact Strength, Notched Izod (per condition) 1 10 10 3.5.8 Curves - FTIR - TGA - DSC - CLTE - Stress/Strain Curves (at 23oC and -40oC) 1 1 1 per test * For these requirements the 3 sigma value from the raw data
24、 is used to meet the requirements. ENGINEERING MATERIAL SPECIFICATION WSS-M4D664-B1 WRS-M4D664-B2 Copyright 2011, Ford Global Technologies, LLC Page 8 of 8 Table 2: Minimum Color Property Testing 5. SUMMARY OF REVISIONS Para. Test Lots Specimens per Lot Total Test Specimens Color Test Direction 3.3.
25、1 Weathering Resistance 1 1 1 Every color 3.4.4 Tensile Strength at Break 1 5 5 As directed by Materials Engineering 3.4.5 Tensile Modulus 1 10 10 As directed by Materials Engineering 3.4.6 Impact Strength, Notched Charpy at 23 +/- 2 C 1 10 10 As directed by Materials Engineering 3.4.9 Odor 1 9 9 As directed by Materials Engineering 3.4.11 Fogging Gravimetric 1 3 3 As directed by Materials Engineering 3.4.12 Flammability 1 5 5 Every Color
