1、 , () INTERSTATE COUNCIL FOR STANDARDIZATION, METROLOGY AND CERTIFICATION (ISC) ISO 4731 2014 (Pelargonium ssp.) (ISO 4731:2012, IDT) 2015 ISO 4731 2014 II , - 1.092 . - 1.2 2009 . -, . , , , 1 ( -) -, 5 2 3 , (- 30 2014 . 70-) : ( 3166) 00497 ( 3166) 00497 BY KG MD RU TJ - 4 15 - 2014 . 1335- ISO 4
2、7312014 - 1 2016 . 5 ISO 4731:2012 Essential oil of geranium (Pelargonium ssp.) (Pelargonium ssp.). ISO/TC 217 (ISO). (en). , - , - . - . (IDT). , - 6 ISO 4731 2014 III - , . () - - . , , 2015 -, - ISO 4731 2014 1 (PELARGONIUMSSP.) Essential oil of geranium (Pelargoniumssp.). Specifications 2016 01
3、01 1 (Pelargonium ssp.), Pelargonium, , Pelargonium graveolens, . 2 . - , - ( ) ISO/TR 210:1999 Essential oils General rules for packaging, conditioning and storage ( . , ) ISO/TR 211:1999 Essential oils General rules for labelling and marking of containers ( . ) ISO 212:2007 Essential oils Sampling
4、 ( . ) ISO 279:1998 Essential oils Determination of relative density at 20 degrees C Reference method ( . 20C. ) ISO 280:1998 Essential oils Determination of refractive index ( . - ) ISO 592:1998 Essential oils Determination of optical rotation ( . ) ISO 875:1999 Essential oils Evaluation of miscibi
5、lity in ethanol ( . - ) ISO 1242:1999 Essential oils Determination of acid value ( . - ) ISO 11024-1:1998 Essential oils General guidance on chromatographic profiles Part 1: Preparation of chromatographic profiles for presentation in standards ( . - . 1. ) ISO 11024-2:1998 Essential oils General gui
6、dance on chromatographic profiles Part 2: Utilization of chromatographic profiles of samples of essential oils ( . - . 2. ) 3 : ISO 4731 2014 2 3.1 (essential oil of geranium): , Pelargonium ssp. -, -. CAS . ISO/TR 21092 2. 4 4.1 , . 4.2 - -. 1): - -. 4.3 , . 4.4 20 C, 2020d 0,885 0,882 0,885 0,887
7、0,905 0,899 0,897 0,897 4.5 20 C ! -. 1,461 1,460 1,460 1,462 1,475 1,472 1,470 1,471 4.6 10 10 10 10 4.7 20 C 14 14 17 17 8 7 9 9 4.8 20 C 70 % . 1) ( ). ISO 4731 2014 3 4.9 . - , 1. . ISO 4731 2014 4 1 . % . % . % . % . % . % . % . % (Z)- (Z)-rose oxide 0,7 1,5 1,5 3,5 0,3 1,1 0,4 1,4 (N)- (N)-ros
8、e oxide 0,3 0,6 0,5 1,5 0,1 0,5 0,1 0,6 (Menthone) .b 2,1 .b 2,5 .b 2,0 .b 2,0 (Isomenthone) 4,0 8,0 4,0 7,0 5,0 10,0 5,0 10,0 (Linalool) 4,0 8,5 2,0 4,5 8,0 11,0 4,0 10,0 -6,9- (Guaia-6,9-diene) .b 0,5 4,0 7,0 5,0 8,5 5,0 9,0 (Citronellyl formate) 4,0 8,0 7,0 12,0 6,5 11,0 6,5 11,0 - (-Terpineol) 0
9、,3 0,6 0,1 0,5 0,3 1,2 0,3 1,0 (Gera-nyl formate) 2,0 7,0 1,0 3,0 4,0 8,0 3,8 7,0 (Citronel-lol) 25,0 36,0 32,0 43,0 18,0 26,0 18,0 26,0 (Geraniol) 10,0 18,0 5,0 12,0 12,0 20,0 10,0 20,0 (Gera-nyl Butyrate) 0,7 2,0 0,4 1,0 0,7 2,0 0,7 1,7 10- (10-epi-Eudesmol) 3,0 6,2 .b .b .b .b .b .b (Geranyl tigl
10、ate) 0,9 2,0 1,0 1,6 0,7 2,0 0,7 2,0 - (-phenylethyl tiglate) 0,5 1,2 0,4 1,0 0,4 1,0 0,4 1,0 , , . a ( ). b . 4.10 . ISO 4731 2014 5 5 ISO 212. : 50 3. , , . 6 6.1 20 C, 2020d ISO 279. 6.2 20 C ISO 280. 6.3 20 C ISO 592. 6.4 ISO 1242. 6.5 70 % 20 C ISO 875. 6.6 ISO 11024. 7 , , , , ISO/TR 210 ISO/T
11、R 211. ISO 4731 2014 6 () (Pelargonium ssp.), 1 (Linalool) 2 (Z)- (Z)-rose oxide) 3 ()- (N)-rose oxide) 4 (Menthone) 5 (Isomenthone) 6 - (-Terpineol) 7 (Citronellol) 8 (Geraniol) 9 (Citronellyl formate) 10 (Geranyl formate) 11 -6,9- (Guaia-6,9-diene) 12 (Geranyl Butyrate) 13 (-phenylethyl tiglate) 1
12、4 10- (10-epi-Eudesmol) 15 (Geranyl tiglate) : , 50 , 0,2 . : . : 0,25 . : - 65 C 230 C, 2 C/. : 230 C. : 250 C. : -. -: . : 0,2 3. -: 1,1 3/. : 1/100. t , .1 ISO 4731 2014 7 1 (Z)- (Z)-rose oxide) 2 ()- (N)-rose oxide) 3 (Menthone) 4 (Isomenthone) 5 (Linalool) 6 -6,9- (Guaia-6,9-diene) 7 (Citronell
13、yl formate) 8 - (-Terpineol) 9 (Geranyl formate) 10 (Citronellol) 11 (Geraniol) 12 (Geranyl Butyrate) 13 10- (10-epi-Eudesmol) 14 (Geranyl tiglate) 15 (-phenylethyl tiglate) : , 50 , - 0,2 . : () Carbomax 20 Ma. : 0,25 . : - 65 C 230 C, 2 C/. : 230 C. : 250 C. : -. -: . : 0,2 3. -: 1,1 3/. : 1/100. t-, Carbomax 20M , . - . .2 ISO 4731 2014 8 () .1 , , , , , - . (. ISO/TR 11018 1) , - - , , : - ; - ; - , -, , . , - , , , . , , . . ISO/TR 11018 1. .2 .1. .1 , C 86 84 83 83 Luchaire2). 2) . - . ISO
