GOST R 54282-2010 Gasoline Determination of oxigenates by method of gas chromatography and oxygen selective flame ionization detection《汽油 气相色谱法和氧离子燃烧法测定气体氧化反应》.pdf

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GOST R 54282-2010 Gasoline Determination of oxigenates by method of gas chromatography and oxygen selective flame ionization detection《汽油 气相色谱法和氧离子燃烧法测定气体氧化反应》.pdf_第1页
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GOST R 54282-2010 Gasoline Determination of oxigenates by method of gas chromatography and oxygen selective flame ionization detection《汽油 气相色谱法和氧离子燃烧法测定气体氧化反应》.pdf_第2页
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GOST R 54282-2010 Gasoline Determination of oxigenates by method of gas chromatography and oxygen selective flame ionization detection《汽油 气相色谱法和氧离子燃烧法测定气体氧化反应》.pdf_第3页
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GOST R 54282-2010 Gasoline Determination of oxigenates by method of gas chromatography and oxygen selective flame ionization detection《汽油 气相色谱法和氧离子燃烧法测定气体氧化反应》.pdf_第4页
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GOST R 54282-2010 Gasoline Determination of oxigenates by method of gas chromatography and oxygen selective flame ionization detection《汽油 气相色谱法和氧离子燃烧法测定气体氧化反应》.pdf_第5页
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1、 542822010 - 27 2002 . 184- , 1.02004 . 1 - ( ) - , 42 31 3 27 2010 . 1118-4 ATM 559900 (2005) - - - (ASTM D 559900 (2005) Standard test method for determination of oxygenates ingasoline by gas chromatography and oxygen selective flame ionization detection). - 1.52004 ( 3.5). - - , 5 , - . - () . ,

2、, 2012 , - - II 5428220101 12 13 24 25 26 OFID .37 .38 .49 510 611 912 .913 1114 .12 () ( - ) 14III 542822010 - Gasoline.Determinationofoxigenatesbymethodofgaschromatographyandoxygenselectiveflameionizationdetection 201207011 1.1 , 220 C, , 130 C . 0,1 % . 20 % .1.2 - , . . , , - , . - , , . - . - ,

3、 , .1.3 , , . - .1.4 - , . . - , .2 1): 1744 (ASTM D 1744, Test method for determination of water in liquid petroleum products by KarlFischer reagent)2) 4175 , , (ASTM D 4175, Terminology relating to petroleum, petroleum products, and lubricants)1) ACTM ATM www.astm/org - ATM: serviceastm.org. (Annu

4、al Book of ASTMStandards) .2) .1 542822010 4307 (ASTM D 4307, Practice for preparation of liquid blends for use as analyticalstandards) E 594 - , (ASTM E 594, Practice for testing flame ionizationdetectors used in gas or supercritical fluid chromatography) E 1064 - (ASTM E 1064, Test method for wate

5、r in organic liquids by coulometric KarlFischer titration)ATM 1510 , ( )(ASTM E 1510, Practice for installing fused silica open tubular capillary columns in gas chromatographs)3 3.1 :3.1.1 (independent reference standards): - , .3.1.2 (oxygenate): , , ( 4175).3.1.3 (quality control check standards):

6、 , - .4 4.1 , 1,2- (- ) . , , . -, - - (OFID). 6.4.2 ( ) , . - 8.2.4.3 - . , 1,2- , , , .5 5.1 , , - . , . , .5.2 - , , .2 5428220106 OFID6.1 , () - (FID). - , , - (Pt/Rh) . () -, , xHyOzc174 zCO+(y/2)H2+(xz)C. (1)6.2 () - , , (, ), , , . () .6.3 , , - CO+3H2c174 H4+H2O. (2) FID.6.4 () , - (PLOT), ,

7、 . FID, 350 C 450 C. -, , , - .7 7.1 , :7.1.1 . , - , .7.1.2 . , 0,11,0 - . , . , 10:1500:1.7.1.3 - . - , -, . . , , 70(10psig)-, , -. 550 (80 psig).7.2 OFID OFID , () - (FID). OFID 1.7.2.1 594 FID, .3 5428220107.2.2 FID - :) , 103;b) 100 ppm . (1 ng O/s);c) , 106 - ;d) 0,11,0 ;e) .7.3 60 , 0,25 , 1

8、,0 . , .7.4 . :7.4.1 .7.4.2 .7.4.3 .7.4.4 ().7.4.5 .8 8.1 . . , , 1). , , .1)Reagent Chemicals, American Chemical Society Specifications, American Chemical Society, Washington, DC. , , . AnalarStandards for Laboratory Chemicals, BDH Ltd., Poole, Dorset, U.K., the United States Pharmacopeia and NationalFormulary, U.S. Pharmacopeial Convention, Inc. (USPC), Rockville, MD.4 5428220101 ; 2- (+2+ n5, ); 3 CnHmOx; 4 ;5

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