1、Comments, suggestions, or questions on this document should be addressed to: Commander, Naval Sea Systems Command, ATTN: SEA 05S, 1333 Isaac Hull Avenue, SE, Stop 5160, Washington Navy Yard DC 20376-5160 or emailed to CommandStandardsnavy.mil, with the subject line “Document Comment”. Since contact
2、information can change, you may want to verify the currency of this address information using the ASSIST Online database at https:/assist.daps.dla.mil. AMSC N/A FSC 8010 METRIC MIL-DTL-15090E 12 October 2010 SUPERSEDING MIL-DTL-15090D 6 November 1996 DETAIL SPECIFICATION ENAMEL, EQUIPMENT, LIGHT GRA
3、Y (NAVY FORMULA NO. 111) This specification is approved for use by all Departments and Agencies of the Department of Defense. 1. SCOPE 1.1 Scope. This specification covers a 250-gram per liter (maximum) (2.08 pounds per gallon maximum) volatile organic content (VOC) complying paint. The paint is a l
4、ight gray equipment enamel (Navy Formula Number 111) for shipboard use as a topcoat on equipment, machinery, furniture and electrical equipment, such as switchboard installations. This product may be used wherever VOC air pollution regulations apply. The light gray equipment enamel covered by this s
5、pecification is an air dry, solvent base coating for use in all interior dry areas including applications covered by reactor plant painting schedules. This product is supplied in a single can and used as supplied without thinning. 2. APPLICABLE DOCUMENTS 2.1 General. The documents listed in this sec
6、tion are specified in sections 3, 4, or 5 of this specification. This section does not include documents cited in other sections of this specification or recommended for additional information or as examples. While every effort has been made to ensure the completeness of this list, document users ar
7、e cautioned that they must meet all specified requirements of documents cited in sections 3, 4, or 5 of this specification, whether or not they are listed. 2.2 Government documents. 2.2.1 Specifications, standards, and handbooks. The following specifications, standards, and handbooks form a part of
8、this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. FEDERAL SPECIFICATIONS TT-P-645 - Primer, Paint, Zinc-Molybdate, Alkyd Type FEDERAL STANDARDS FED-STD-141 - Paint, Varnish, Lacquer and Related Mat
9、erials: Methods of Inspection, Sampling and Testing FED-STD-313 - Material Safety Data, Transportation Data, and Disposal Data for Hazardous Materials Furnished to Government Activities FED-STD-595/26307 Gray, Semigloss DEPARTMENT OF DEFENSE SPECIFICATIONS MIL-PRF-680 - Degreasing Solvent Provided b
10、y IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-15090E MIL-A-22262 - Abrasive Blasting Media Ship Hull Blast Cleaning MIL-DTL-24441 - Paint, Epoxy-Polyamide, General Specification for MIL-PRF-24635 - Coating Systems, Weather-Resistant, Exterior Use MIL
11、-PRF-24763 - Enamel, Emulsion Type, for Shipboard Use (Copies of these documents are available online at https:/assist.daps.dla.mil/quicksearch/ or from the Standardization Document Order Desk, 700 Robbins Avenue, Building 4D, Philadelphia, PA 19111-5094.) 2.2.2 Other Government documents, drawings,
12、 and publications. The following other Government documents, drawings, and publications form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those cited in the solicitation or contract. CODE OF FEDERAL REGULATIONS (CFR) 29 CFR 191
13、0.1200, Subpart Z - Toxic and Hazardous Substances 29 CFR 1910.1200 - Hazard Communication 29 CFR 1915.1001, Appendix K Method ID-191 - Polarized Light Microscopy of Asbestos 40 CFR 60, Appendix A-7, Method 24 - Determination of Volatile Matter Content, Water Content, Density, Volume Solids, and Wei
14、ght Solids of Surface Coatings 40 CFR 82 - Protection of Stratospheric Ozone 40 CFR 261.24(a), Method 1311 - Toxicity Characteristic Leaching Procedure (TCLP) 40 CFR 355, Appendices A and B - The List of Extremely Hazardous Substances and Their Threshold Planning Quantities 40 CFR 372.65, Subpart D
15、- Specific Toxic Chemical Listings (Copies of these documents are available from the Superintendent of Documents, U.S. Government Printing Office, Washington DC 20401 or online at www.gpoaccess.gov/index.html.) NAVAL SEA SYSTEMS COMMAND (NAVSEA) PUBLICATIONS S9510-AB-ATM-010 - Nuclear Powered Submar
16、ine Atmosphere Control Manual (Copies of the chapter titled “Material Control Program” are available from Commander, Naval Sea Systems Command, ATTN: SEA 05Z4, 1333 Isaac Hull Ave. SE Stop 5122, Washington Navy Yard, DC 20376-5122 or online at https:/smcl.dt.navy.mil.) U.S. ENVIRONMENTAL PROTECTION
17、AGENCY (EPA) EPA 600/4-79-020 - Methods for Chemical Analysis of Water and Wastes EPA SW-846 - Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (Copies of these documents are available from the Environmental Protection Agency, Ariel Rios Building, 1200 Pennsylvania Avenue, N.W., Wa
18、shington DC 20460 or online at www.epa.gov.) 2 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-15090E 2.3 Non-Government publications. The following documents form a part of this document to the extent specified herein. Unless otherwise speci
19、fied, the issues of these documents are those cited in the solicitation or contract. ASTM INTERNATIONAL ASTM D185 - Standard Test Methods for Coarse Particles in Pigments ASTM D476 - Standard Classification for Dry Pigmentary Titanium Dioxide Products ASTM D522 - Standard Test Methods for Mandrel Be
20、nd Test of Attached Organic Coatings ASTM D523 - Standard Test Method for Specular Gloss ASTM D562 - Standard Test Method for Consistency of Paints Measuring Krebs Unit (KU) Viscosity Using a Stormer-Type Viscometer ASTM D823 - Standard Practices for Producing Films of Uniform Thickness of Paint, Va
21、rnish, and Related Products on Test Panels ASTM D869 - Standard Test Method for Evaluating Degree of Settling of Paint ASTM D1210 - Standard Test Method for Fineness of Dispersion of Pigment-Vehicle Systems by Hegman-Type Gage ASTM D1296 - Standard Test Method for Odor of Volatile Solvents and Dilue
22、nts ASTM D1364 - Standard Test Method for Water in Volatile Solvents (Karl Fischer Reagent Titration Method ASTM D1475 - Standard Test Method for Density of Liquid Coatings, Inks, and Related Products ASTM D1849 - Standard Test Method for Package Stability of Paint ASTM D2244 - Standard Practice for
23、 Calculation of Color Tolerances and Color Differences from Instrumentally Measured Color Coordinates ASTM D2245 - Standard Test Method for Identification of Oils and Oil Acids in Solvent-Reducible Paints ASTM D2369 - Standard Test Method for Volatile Content of Coatings ASTM D2698 - Standard Test M
24、ethod for Determination of the Pigment Content of Solvent-Reducible Paints by High-Speed Centrifuging ASTM D2805 - Standard Test Method for Hiding Power of Paints by Reflectometry ASTM D3278 - Standard Test Methods for Flash Point of Liquids by Small Scale Closed-Cup Apparatus ASTM D3359 - Standard
25、Test Methods for Measuring Adhesion by Tape Test ASTM D3363 - Standard Test Method for Film Hardness by Pencil Test ASTM D4400 - Standard Test Method for Sag Resistance of Paints Using a Multinotch Applicator ASTM D5895 - Standard Test Methods for Evaluating Drying or Curing During Film Formation of
26、 Organic Coatings Using Mechanical Recorders 3 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-15090E ASTM E1347 - Standard Test Method for Color and Color-Difference Measurement by Tristimulus Colorimetry ASTM F718 - Standard for Shipbuilder
27、s and Marine Paints and Coatings Product/Procedure Data Sheet (Copies of these documents are available from ASTM International, 100 Barr Harbor Dr., PO Box C700, West Conshohocken, PA 19428-2959 or online at www.astm.org.) SOCIETY FOR PROTECTIVE COATINGS (SSPC) SSPC-SP 10 - Near-White Blast Cleaning
28、 (Copies of this document are available from SSPC Publication Sales, 40 24thStreet, 6thFloor, Pittsburgh, PA 15222-4656 or online at www.sspc.org.) 2.4 Order of precedence. Unless otherwise noted herein or in the contract, in the event of a conflict between the text of this document and the referenc
29、es cited herein, the text of this document takes precedence. Nothing in this document, however, supersedes applicable laws and regulations unless a specific exemption has been obtained. 3. REQUIREMENTS 3.1 First article. When specified (see 6.2), a sample shall be subjected to first article inspecti
30、on in accordance with 4.2. 3.2 Formula. The enamel shall consist of an alkyd resin, pigments, extender pigments, and solvent listed in table I and table II, that when combined, shall result in a paint conforming to the requirements of the applicable paragraphs of this specification. 3.2.1 Formula no
31、. 111. The formula shown in table I is designated Navy Formula No. 111. When Formula No. 111 is specified, or when this specification is referenced without reference to the formula number, the enamel shall conform to the requirements of this specification. Manufacturers may use alternate ingredients
32、 as long as the alternate ingredients are specifically approved by the Naval Sea Systems Command and the enamel is shown to meet all the requirements of this specification by first article testing (see 6.4) and conformance testing. Conformance testing may be conducted by the Government at any time t
33、o verify that the product being acquired meets the requirements of this specification. 3.2.2 Composition. The paint shall consist of the ingredients listed in table I footnotes in the proportions shown in table I and table II except that the amount of carbon black may be varied as necessary to meet
34、color requirements. In addition, to assist in meeting drying times, brushing, condition in container, and storage stability requirements, driers, antisettling, antisagging, and antiskinning agents may be varied as necessary to meet the other requirements of this specification. 3.2.3 Recycled, recove
35、red, or environmentally preferable materials. Recycled, recovered, or environmentally preferable materials should be used to the maximum extent possible, provided that the material meets or exceeds the operational and maintenance requirements, and promotes economically advantageous life cycle costs.
36、 3.3 Toxicity. When evaluated in accordance with 4.8, the enamel shall have no adverse effect on the health of personnel when used for its intended purpose and shall not cause any environmental problems during waste disposal (see 4.8 and 6.8). The materials content used in the enamel shall have no k
37、nown reportable carcinogenic or potentially carcinogenic materials and shall have no extremely hazardous substances (EHS) or toxic chemicals identified in 40 CFR 355 and 372.65, respectively. The enamel shall not contain more than 0.005 percent cobalt compounds by weight in its formulation, unless a
38、 cobalt drier is used (see table V). 3.4 Manufacture. The component raw materials shall be mixed, ground, and blended as required to produce a product that is uniform, free from grit, lumps, skins, and floating pigment. The enamel shall be entirely suitable for the purpose intended and shall be in f
39、ull conformance to the requirements of this specification. 4 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-15090E TABLE I. Formula no. 111. Ingredients Kilograms (kg) Pounds (lb) %WT Alkyd resin solution 1/ 291.44 642.52 56.41 Titanium diox
40、ide 2/ 56.23 123.96 10.88 Magnesium silicate 3/62.97 138.83 12.2 Parachlorobenzotrifluoride 4/ 45.22 99.7 8.75 Paint thinner 5/ 36.35 80.15 7.04 Suspending agent 6/ 9.0 19.83 1.74 Dispersant 7/ 1.8 3.96 0.35 Calcium drier 8/ 4.9 10.81 0.95 Zirconium drier 9/ 2.45 5.4 0.47 Antiskinning agent 10/ 0.9
41、1.98 0.17 Cobalt drier 11/ 0.73 1.62 0.14 Yellow iron oxide 12/2.70 5.95 0.52 Antifloat 13/1.35 2.98 0.26 Carbon black 14/0.63 1.4 0.12 Totals 15/516.67 1139.1 100.0 NOTES: 1/ The alkyd resin complies with the table II requirements. 2/ASTM D476, Types I or II. 3/Talcron MP-1250, Specialty Minerals,
42、Inc., Bethlehem, PA. 4/Oxsol100, is no longer manufactured by the Occidental Chemical Corp., Dallas, TX. (Oxsol100 was used for this formulation. There are chemically identical alternatives available from other manufacturers.) 5/Mineral Spirits (see MIL-PRF-680). 6/Bentone 38 (10%) Gel, NCP Coatings
43、, Niles, MI. 7/Spurso, OMG Mooney Chemicals; Cleveland, OH. 8/Calcium Neodecanoate (6%), OMG Mooney Chemicals, Cleveland, OH. 9/Zirconium Neodecanoate (18%), OMG Mooney Chemicals, Cleveland, OH. 10/Exkin #2, OMG Mooney Chemicals, Cleveland, OH. 11/Cobalt Neodecanoate (12%), OMG Mooney Chemicals, Cle
44、veland, OH. 12/Y25-LO, Elementis Pigments, Inc. Fairview Heights, IL. 13/Troysol AFL, Troy Chemical Co., Newark, NJ. 14/Raven 14, Colombian Chemical Co., Marietta, GA. 15/This formula makes approximately 100 gallons of paint. 5 Provided by IHSNot for ResaleNo reproduction or networking permitted wit
45、hout license from IHS-,-,-MIL-DTL-15090E TABLE II. Alkyd resin requirements. Requirements Characteristics Minimum Maximum Nonvolatile resin, %WT of solution 49 51 Phthalic anhydride, %WT of non- volatile vehicle 30 - Drying oil acids, %WT of non- volatile vehicle 45 55 Acid number 5 12 Dihydric alco
46、hol, %WT of non-volatile resin - 7 Viscosity (G-H) at 25 C U Z Color, gardener - 10 Weight per gallon, kg/liter (pounds/gallon) 1.16(9.7) 1.28 (10.7) Soya oil Positive (by certification) Rosin Negative (by certification) Phenolic resin Negative (by certification) 3.5 Quantitative requirements. The e
47、namel shall conform to the quantitative requirements in tables III, IV, V, 3.5.1, 3.5.2, and 3.6. TABLE III. Formula no. 111 quantitative requirements. Requirements Characteristics Minimum Maximum Pigment, %WT of enamel 22.0 25.0 Volatiles, %WT of enamel 46.0 49.0 Nonvolatile vehicle, %WT of enamel
48、(calculated by difference) 28.0 31.0 Water, %WT of enamel - 0.5 Coarse particles and skins (as residue on N. 325 sieve) %WT of enamel - 0.2 Viscosity, Krebs units 75 85 Weight per gallon, kg/liter (pounds/gallon) 1.31 (10.9) 1.42 (11.9) 60oSpecular gloss 35 50 Contrast ratio 0.97 - Color, E - 0.5 Ti
49、me to dry to touch (hours) - 2.0 Time to dry through (hours) - 8.0 Pencil hardness HB - Fineness of grind, Hegman units 5 - Flashpoint, C ( F) 38 (100) - 6 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-DTL-15090E TABLE III. Formula no. 111 quantitative requirements - Continued. Requirements Characteristics Mi
