1、Designation: B967/B967M 10Standard Specification forCopper-Zinc-Tin-Bismuth Alloy Rod, Bar and Wire1This standard is issued under the fixed designation B967/B967M; the number immediately following the designation indicates the yearof original adoption or, in the case of revision, the year of last re
2、vision. A number in parentheses indicates the year of last reapproval.A superscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope*1.1 This specification establishes the requirements forcopper-zinc-tin-bismuth alloy rod, bar and wire of alloy UNSNos. C49260,
3、C49300, C49340, and C49350 intended for usein plumbing applications and drinking water systems.1.2 Typically, rod and bar product made to this specificationis furnished as straight lengths. Wire (H04) 0.08-0.3 in. 2-8mm inclusive is furnished in coil form, and H50 shapes.1.3 The following safety haz
4、ard caveat pertains only to thetest method(s) described in this specification.1.3.1 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and det
5、ermine the applica-bility of regulatory limitations prior to use.1.4 UnitsThe values stated in either SI units or inch-pound units are to be regarded separately as standard. Thevalues stated in each system may not be exact equivalents;therefore, each system shall be used independently of the other.C
6、ombining values from the two systems may result in non-conformance with the standard.2. Referenced Documents2.1 ASTM Standards:2B249/B249M Specification for General Requirements forWrought Copper and Copper-Alloy Rod, Bar, Shapes andForgingsB250/B250M Specification for General Requirements forWrough
7、t Copper Alloy WireB846 Terminology for Copper and Copper AlloysE8 Test Methods for Tension Testing of Metallic MaterialsE8M Test Methods for Tension Testing of Metallic Materi-als Metric3E62 Test Methods for Chemical Analysis of Copper andCopper Alloys (Photometric Methods)3E92 Test Method for Vick
8、ers Hardness of Metallic Materi-alsE478 Test Methods for ChemicalAnalysis of CopperAlloys2.2 Other Standards:ISO No. 3110 (AA) Copper Alloys Determination of Alu-minum as an Alloying Element Volumetric4(Interna-tional Organization of Standardization)JIS H 1068:2005 Method for Determination of Bismut
9、h inCopper and Copper Alloys5(Japanese Industrial Stan-dards)3. General Requirements3.1 The following sections of Specifications B249/B249Mor B250/B250M constitute a part of this specification:3.1.1 Terminology,3.1.2 Materials and Manufacture,3.1.3 Sampling,3.1.4 Number of Tests and Retests,3.1.5 Sp
10、ecimen Preparation,3.1.6 Certification,3.1.7 Test Reports.3.2 In addition, when a section with a title identical to thatreferenced in X.1, above, appears in this specification, itcontains additional requirements which supplement those ap-pearing in Specifications B249/B249M or B250/B250M.4. Terminol
11、ogy4.1 For definitions of terms related to copper and copperalloys, refer to Terminology B846.5. Ordering Information5.1 Include the following information when placing ordersfor product under this specification, as applicable:5.1.1 ASTM designation and year of issue,5.1.2 Copper Alloy UNS designatio
12、n,5.1.3 Temper (Section 8),5.1.4 Dimensions, diameter, or distance between parallelsurfaces,1This test method is under the jurisdiction of ASTM Committee B05 on Copperand Copper Alloys and is the direct responsibility of Subcommittee B05.02 on Rod,Bar, Wire, Shapes and Forgings.Current edition appro
13、ved April 1, 2010. Published May 2009. Originallyapproved in 2009. Last previous edition approved in 2009 as B967/B967M 09.DOI: 10.1520/B0967_B0967M-10.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMSta
14、ndards volume information, refer to the standards Document Summary page onthe ASTM website.3Withdrawn. The last approved version of this historical standard is referencedon www.astm.org.4Available from International Organization of Standards, http:/www.ISO/ISO/store.htm5Japanese Industrial Standard,
15、 available through http:/www.JIS.or.jp/1*A Summary of Changes section appears at the end of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.5.1.5 How furnished: straight lengths or coils,5.1.6 Quantity: total weight or t
16、otal length or number ofpieces of each size,5.1.7 If product is purchased for agencies of the U.S.Government (see the Supplementary Requirements section ofSpecifications B249/B249M or B250/B250M for additionalrequirements, if specified).5.1.8 ShapesWhen product is shapes, the dimensionaltolerances s
17、hall be as agreed upon between the manufacturer orsupplier and purchaser and shall be specified (see 11.1.7).5.2 The following options are available and should bespecified at the time of placing of the order when required:5.2.1 Heat identification or traceability details,5.2.2 Certification, and5.2.
18、3 Mill Test Report.6. Materials and Manufacture6.1 Materials:6.1.1 The material of manufacture shall be a form of CopperAlloy UNS Nos. C49260, C49300, C49340, and C49350 ofsuch purity and soundness as to be suitable for processing intothe products prescribed herein.6.1.2 In the event heat identifica
19、tion or traceability isrequired, the purchaser shall specify the details desired.NOTE 1Due to the discontinuous nature of the processing of castingsinto wrought products, it is not always practical to identify a specificcasting analysis with a specific quantity of finished material.6.2 Manufacture:6
20、.2.1 The product shall be manufactured by such hot work-ing, cold working, and annealing processes as to produce auniform wrought structure in the finished product.6.2.2 The product shall be hot or cold worked to the finishedsize, and subsequently annealed when required, to meet thetemper properties
21、 specified.7. Chemical Composition7.1 The material shall conform to the chemical compositionrequirements in Table 1 for the copper alloy UNS Numbersspecified in the ordering information.7.2 These composition limits do not preclude the presenceof other elements. By agreement between the manufacturer
22、andpurchaser, limits may be established and analysis required forunnamed elements.7.3 For alloys in which zinc is listed as “remainder,” zinc isthe difference between the sum of results of all elementsdetermined and 100 %. When all elements in Table 1 aredetermined, the sum of results shall be 99.5
23、% min.8. Temper8.1 The standard tempers for products described in thisspecification are given in Table 2.8.1.1 Annealed: 061 for rod and bar8.1.2 As Hot Extruded: M30 for rod and bar8.1.3 Cold drawn half hard temper: H02 for rod and bar8.1.4 Cold drawn hard temper: H04 for wire8.1.5 Hot extruded and
24、 drawn: H50 for Shapes in all sizes.9. Mechanical Property Requirements9.1 Tensile Strength Requirements:9.1.1 Product furnished under this specification shall con-form to the tensile requirements prescribed in Table 2, whentested in accordance with Test Methods E8 or E8M.9.1.2 Acceptance or rejecti
25、on shall be based upon the tensileproperties prescribed in Table 2.10. Other Requirements10.1 Purchases for the U.S. Government Product pur-chased for agencies of the U.S. Government shall conform tothe additional requirements prescribed in the SupplementaryRequirements section of Specifications B24
26、9/B249M or B250/B250M.11. Dimensions, Mass, and Permissible Variation11.1 The dimensions and tolerances for product describedby this specification shall be as specified in SpecificationB249/B249M or B250/B250M for wire as noted, with particu-lar reference to the following Tables and related paragrap
27、hs:11.1.1 Diameter or Distance Between Parallel Surfaces11.1.1.1 Rod, Cold-Drawn, H02, H04 Table 1, B249/B249M.11.1.1.2 Rod and Bar, As Extruded, O61 Table 4, B249/B249M.11.1.1.3 Wire Cold Drawn Hard, H04 Table 1, B250/B250M.11.1.2 Thickness Tolerance for Rectangular and Square Bar,Table 7, B249/B24
28、9M.11.1.3 Width Tolerance for Rectangular Bar, Table 10,B249/B249M.11.1.4 Length: Table 13, Full Length Tolerances for Rod,Bar, and Table 15, Schedule of Lengths with Ends for Rod andBar, B249/B249M.11.1.5 Straightness: Table 16, Straightness Tolerances forRod, Bar, For General Use section, B249/B24
29、9M.11.1.6 Edge Contour: Refer to Edge Contours section inB249/B249M or B250/B250M.TABLE 1 Chemical CompositionCopper AlloyUNS No.Copper LeadmaxIronmaxTin Zinc PhosphorusmaxAluminummaxAntimonymaxBismuth ManganesemaxNickelmax, incl CoSeleniummaxSiliconmaxC49300 58.062.0 0.01 0.10 1.31.8 Rem 0.20 0.50
30、0.50 .502.0 0.03 1.5 0.20 0.10C49260A58.063.0 0.09 0.50 0.50 Rem 0.500.15 . . . . . . 0.501.8 . . . . . . . . . 0.10C49340A60.0-63.0 0.09 0.12 0.50-1.5 Rem 0.050.15 . . . . . . 0.502.0 . . . . . . . . . 0.10C49350 61.063.0 0.09 0.12 1.53.0 Rem 0.040.15 . . . 0.02-0.10 0.502.5 . . . . . . . . . 0.30A
31、Cadmium 0.001 max.B967/B967M 10211.1.7 Shapes: The dimensional tolerances for shapes shallbe agreed upon between the manufacturer or supplier and thepurchaser and shall be specified in the order or purchasecontract.12. Workmanship, Finish, and Appearance12.1 The product shall be free of defects, but
32、 blemishes ofa nature that do not interfere with the intended application areacceptable.13. Sampling13.1 Refer to sampling section in Specifications B249/B249M or B250/B250M.14. Number of Tests and Retests14.1 Test:14.1.1 Chemical AnalysisChemical composition shall bedetermined in accordance with th
33、e element mean of the resultsfrom at least two replicate analyses of the sample(s).14.2 Retest:14.2.1 When requested by the manufacturer or supplier, aretest shall be permitted when results of tests obtained by thepurchaser fail to conform to the requirements of the productspecification.14.2.2 The r
34、etest shall be as directed in the product speci-fication for the initial test, except the number of test specimensshall be twice that normally required for the specified test.14.2.3 All test specimens shall conform to the productspecification requirement(s) in retest. Failure to conform shallbe caus
35、e for rejection.15. Test Methods15.1 Chemical Analyses:15.1.1 In cases of disagreement, the resolution of thedispute shall be subject to agreement between the manufactureror supplier and purchaser. The following methods may be used:Element MethodCopper E478Aluminum ISO No. 3110 (AA)Phospho-rusE62Nic
36、kel E478Tin E478Zinc E478Bismuth JIS H 1068: 200515.1.2 Test method(s) to be followed for the determinationof element(s) resulting from contractual or purchase orderagreement shall be as agreed upon between the manufacturer orsupplier and purchaser.15.2 Other Tests:15.2.1 The product furnished shall
37、 conform to specifiedrequirements when subjected to test in accordance with thefollowing table:Test MethodTensile Properties E8 E8MHardness, Vickers E9215.2.2 Yield StrengthThe yield strength shall be deter-mined by the 0.2 % offset method of Test Method E8 or E8M.When test results are obtained from
38、 both full-size and ma-chined specimens, and they differ, the test results from thefull-size specimens shall prevail.16. Significance of Numerical Limits16.1 For the purpose of determining compliance with thespecified limits for requirements of the properties listed in thefollowing table and for dim
39、ensional tolerances, an observedvalue or a calculated value shall be rounded as indicated inaccordance with the rounding method of Practice E92:Property Rounded Unitfor Observed orCalculated ValueChemical CompositionHardnessNearest unit in the last right-handsignificant digit used inexpressing the l
40、imiting valueTensile StrengthYield StrengthNearest ksi 5 MPaTABLE 2 Mechanical Property Requirements Round and Hexagonal Rod, BarAand WireTemper Diameter or DistanceBetween Parallel Surfaces,in. (mm)Tensile Strength,ksi (MPa)minYield Strength0.2 offsetksi (MPa)minElongationin 4 3 dia.%minVickers Har
41、dness5000 gmsTyp.Code NameCopper Alloys UNS No. C49260, C49300, and C49340M30 As Hot Extruded 1 to 4.375 incl. (25 110) incl. 50 (345) 20 (140) 18O61 Annealed .3 1 incl. (8 25) incl.1 2.5 incl. (26 65) incl.50 (345)48 (330)20 (140)16 (110)15158080H0212 Hard .3 1 incl. (8 25) incl.1 2.5 incl. (26 65)
42、 incl.55 (380)50 (345)25 (170)20 (140)15158080H04 Hard Wire .08 .3 incl. (2 8) incl. 67 (460) 45 (310) 3H50 Hot extruded and Drawn All Sizes 50 (345) 20 (140)Copper Alloy UNS No C49350M30 As Hot extruded 1 4.375 incl. 50 (345) 20 (140) 15O61 Annealed .3 2.5 incl. 48 (330) 16 (110) 12AFor rectangular
43、 bar, the Distance Between Parallel Surfaces refers to thickness.B967/B967M 103Elongation Nearest 1 %17. Inspection17.1 The manufacturer, or supplier, shall inspect and maketests necessary to verify the furnished product conforms tospecification requirements.17.2 Source inspection of the product by
44、the purchaser maybe agreed upon between the manufacturer, or supplier, and thepurchaser as part of the purchase order. In such case, the natureof the facilities needed to satisfy the inspector, representing thepurchaser, that the product is being furnished in accordancewith the specification shall b
45、e included in the agreement. Alltesting and inspection shall be conducted so as not to interfereunnecessarily with the operation of the works.17.3 When mutually agreed upon, the manufacturer, orsupplier, and the purchaser shall conduct the final inspectionsimultaneously.18. Rejection and Rehearing18
46、.1 Rejection:18.1.1 Product that fails to conform to the specificationrequirements when tested by the purchaser or purchasers agentshall be subject to rejection.18.1.2 Rejection shall be reported to the manufacturer orsupplier promptly. In addition, a written notification of rejec-tion shall follow.
47、18.1.3 In case of dissatisfaction with results of the test uponwhich rejection is based, the manufacturer, or supplier, shallhave the option to make claim for a rehearing.18.2 Rehearing:18.2.1 As a result of product rejection, the manufacturer, orsupplier, shall have the option to make claim for a r
48、etest to beconducted by the manufacturer, or supplier, and the purchaser.Samples of the rejected product shall be taken in accordancewith the product specification and subjected to test by bothparties using the test method(s) specified in the productspecification, or alternately, upon agreement of b
49、oth parties, anindependent laboratory may be selected for the test(s) using thetest method(s) specified in the product specification.19. Certification19.1 When specified in the purchase order or contract, thepurchaser shall be furnished certification that samples repre-senting each lot have been either tested or inspected as directedin this specification and requirements have been met.20. Test Report20.1 When specified in the contract or purchase order, areport of test results shall be furnished.21. Product Identifica
