1、Designation: D1611 00 (Reapproved 2010)Standard Test Method forCorrosion Produced by Leather in Contact with Metal1This standard is issued under the fixed designation D1611; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year
2、of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope1.1 This test method covers the qualit
3、ative and quantitativedetermination of corrosion produced by leather in contact withmetal. This test method does not apply to wet blue.1.2 The values stated in inch-pound units are to be regardedas the standard.1.3 This standard does not purport to address all of thesafety concerns, if any, associat
4、ed with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D91 Test Method for Precipitation Number of LubricatingOils2.
5、2 Military Standard:3MIL-H-6083 (latest revision) Hydraulic Fluid, PetroleumBase, for Preservation and Operation3. Terminology3.1 Definitions:3.1.1 corrosiona modification of the metal surface incontact with a leather specimen, evidenced by visible pittingand erosion of the metal surface or by a cha
6、nge in mass of themetal tested in comparison with a blank determination. Anypermanent discoloration in film form on the specimen (metal)that does not readily buff off with a nonabrasive cloth shall becalled incipient corrosion, while any visible pitting of the metalsurface or formation of a layer of
7、 reaction products on themetal surface shall be considered as corrosion. In the latter caseand for quantitative purposes, the corrosion level should beassessed by determination of the mass changes which occur inthe metal panel.3.1.2 staininga discoloration of the metal surface aftercontact with a le
8、ather specimen, which discoloration is causedby minor amounts of leathermetal interreaction productsformed on the metal surface. Such stains should readily buff offthe metal surface without permanent marring of its surfaceappearance.4. Summary of Test Method4.1 A conditioned piece of leather and two
9、 plates of thesame metal are dipped in a noncorrosive oil and drained to thedrip point. They are stacked together under a load of 25 6 5 lbf(111 6 22 N) and placed in a desiccator containing a relativehumidity of 90 to 95 % at 73.5 6 2F (23 6 1C) for a periodof 14 days. For quantitative purposes, th
10、e metal plates areweighed before and after the test.5. Significance and Use5.1 The procedure is primarily intended to evaluate chromeleather intended for use in hydraulic systems under circum-stances where metal corrosion is a serious factor. A highrelative humidity is used for the purpose of accele
11、rating theresults.6. Apparatus6.1 Desiccator, containing a saturated solution of ammo-nium dihydrogen phosphate.6.2 Four Plates of the Metal to Be Tested4The surfaceroughness should be 8 to 16 m (203 to 406 nm) rms finish.They should be approximately 2 by 4 in. (51 by 102 mm) andof uniform thickness
12、.1This test method is under the jurisdiction of ASTM Committee D31 on Leatherand is the direct responsibility of D31.01 on Vegetable Leather. This test method wasdeveloped in cooperation with the American Leather Chemists Assn. (StandardMethod E52-1961).Current edition approved April 1, 2010. Publis
13、hed May 2010. Originallyapproved in 1958. Last previous edition approved in 2005 as D161100 (2005).DOI: 10.1520/D1611-00R10.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, r
14、efer to the standards Document Summary page onthe ASTM website.3Available from Standardization Documents Order Desk, Bldg. 4 Section D, 700Robbins Ave., Philadelphia, PA 19111-5094, Attn: NPODS.4The sole source of supply of the steel test panels-Q Panel QD35, 3 by 5 in.,surface roughness 203305 nm,
15、known to the committee at this time is The Q PanelCompany, 15610 Industrial Parkway, Cleveland, OH 44135. If you are aware ofalternative suppliers, please provide this information to ASTM Headquarters. Yourcomments will receive careful consideration at a meeting of the responsibletechnical committee
16、1, which you may attend.1Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.6.3 Mass,256 5lb(11.36 2.3 kg).6.4 Nonabrasive ClothThe cloth should not scratch ormar the surface of the metal plates when the plates are rubbedwith the cloth,
17、or cause any change in the mass of the metalplates.6.5 Forceps.6.6 Analytical Balance.6.7 Piece of Glass, of approximately the length and width ofthe metal panels.7. Reagents7.1 Noncorrosive Oil, conforming to Military SpecificationMIL-H6083 is recommended.7.2 Precipitation Naphtha, conforming to sp
18、ecificationsgiven in Test Method D91.8. Test Specimen8.1 The specimen shall be a piece of leather 25 by 80 mmand split to a uniform thickness.9. ProcedureQualitative9.1 Condition the leather specimen by placing it in adesiccator at 90 to 95 % relative humidity and 73.5 6 2F (236 1C) for a period of
19、72 h.9.2 Buff the metal plates with a nonabrasive cloth and washthem with precipitation naphtha.9.3 Immerse the humidified specimen and the metal platesin a noncorrosive oil and drain them to the drip point. Place thespecimen between the two metal plates, hold them togetherunder a mass of 25 6 5lb(1
20、1.36 2.3 kg), and place them inthe desiccator. Insert a glass plate between the top metal plateand the mass to avoid contact between dissimilar metals. Alsoprepare two control plates in the same manner. Place them inthe desiccator so that they do not touch each other or thespecimen. Then close the d
21、esiccator and hold the specimen andplates at 90 to 95 % relative humidity at 73.5 6 2F (23 61C) for a period of 14 days.9.4 At the end of 14 days, inspect the surfaces of the platesthat were in contact with the leather specimen and comparethem with the control plates. To facilitate inspection andeva
22、luation, the plates may be washed with precipitation naph-tha and buffed with the nonabrasive cloth.10. ProcedureQuantitative10.1 For quantitative evaluation, the procedure shall be thesame as for qualitative testing, except that the metal plates shallbe handled with forceps and weighed to the neare
23、st 1 mg afterbuffing and washing with precipitation naphtha and beforedipping in the noncorrosive oil. At the conclusion of the test,weigh the plates again after washing in naphtha and buffingwith the nonabrasive cloth.10.2 Handle the two metal control plates having the samedimensions as the test pl
24、ates in exactly the same manner as thetest plates with the exception that they shall not be brought intocontact with the specimen.10.3 At the conclusion of the test, apply any change in massof the control plates as a correction to the change in mass of thetest plates. The result is the change in mas
25、s of the test platesfrom being in contact with the leather specimen.11. Report11.1 For qualitative purposes, report the leather as beingeither noncorrosive, causing staining, causing incipient corro-sion, or causing corrosion.11.2 For quantitative purposes, if visible pitting is evidentrecord the to
26、tal number of pit marks. If erosion is evident,report the percent area of erosion. In the absence of visiblepitting or erosion, express the corrosion level as a gain or lossin milligrams per square centimetre. This is obtained bydividing the change in mass of the test plates from being incontact wit
27、h the specimen (10.3) by the area of the leatherspecimen in contact with the plates. If there is no change in themass of the plates from being in contact with the specimenreport the leather as being noncorrosive.12. Precision and Bias12.1 The precision of the quantitative results depends on thepreci
28、sion of the measurement of the mass changes of the metalpanels, the method of determining the area of erosion, andcorrectly counting pit marks.13. Keywords13.1 corrosion; leather; metal corrosion by leatherASTM International takes no position respecting the validity of any patent rights asserted in
29、connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the res
30、ponsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive caref
31、ul consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International
32、, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).D1611 00 (2010)2
