1、Designation: D3310 00 (Reapproved 2014)Standard Test Method forDetermining Corrosivity of Adhesive Materials1This standard is issued under the fixed designation D3310; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of las
2、t revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This test method is intended to determine whether anadhesive material, cured or uncured, is corrosive to a metal. Itis a
3、general test method intended to screen out those materialsthat give a visible sign of corrosion.1.2 The values stated in SI units are to be regarded as thestandard. The values given in parentheses are provided forinformation purposes only.1.3 This standard does not purport to address all of thesafet
4、y concerns, if any, associated with its use. It is theresponsibility of the user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:2D907 Terminology of AdhesivesG15
5、Terminology Relating to Corrosion and Corrosion Test-ing (Withdrawn 2010)33. Terminology3.1 Definitions:3.1.1 Definitions of terms in this test method may be foundin Terminologies D907 and G15.3.1.2 corrosivity, nthe tendency to cause corrosion.4. Summary of Test Method4.1 The metal of interest is e
6、nclosed in a glass containerwith the adhesive material. The containers are stored intemperature-controlled ovens at various temperatures with andwithout water present.4.2 Controls, glass jars containing samples (strips) of thesame metal with and without water but no adhesive stored inthe same oven f
7、or comparison.5. Significance and Use5.1 This test method is a subjective test in that determina-tions of degree of corrosivity is based upon a visual inspectionfor a green discoloration or other evidence of corrosion.6. Apparatus6.1 Glass Jars, wide-mouth, with screw cap (8-oz size). Thecap liner s
8、hall be TFE- or FEP-fluorocarbon.6.2 Forced Draft Circulating Air Oven, capable of main-taining 71 6 2C (160 6 4F); 93 6 2C (200 6 4F); 12162C (250 6 4F). Other temperatures can be used withagreement of interested parties.6.3 Open Glass Jars or Cups, 1-oz size.6.4 Metal or metals being checked for c
9、orrosion.7. Procedure7.1 Place 5 to 10 g of the adhesive in a small glass jar withthe metal being evaluated partly embedded in the adhesive.Place this small uncovered jar in a large jar. Screw the cap ofthe large jar tightly in place. Then place the jar in the oven ata temperature as specified in 6.
10、2.NOTE 1Here metal is exposed during cure rather than after cure.7.2 Same as 7.1, except place a small jar half filled withdistilled water in a large jar with the jar containing adhesiveand metal. However, do not use water above 71C.7.3 Same as 7.1 and 7.2, except cure the adhesive inaccordance with
11、 manufacturers instructions before placing itin the large jar.NOTE 2Hot-melt or air-dried materials are considered to be in thecured state.8. Control8.1 Place a metal specimen similar to the specimen beingevaluated in a screw cap jar with no adhesive. Tighten thescrew cap in place, and place the jar
12、 in the same oven at thesame time as the specimen being evaluated. Store another largejar with a control metal specimen and including a small jar withwater in it in the oven in a similar manner.1This test method is under the jurisdiction of ASTM Committee D14 onAdhesives and is the direct responsibi
13、lity of D14.80 on Metal Bonding Adhesives.Current edition approved March 1, 2014. Published March 2014. Originallyapproved in 1974. Last previous edition approved in 2006 as D3310 00 (2006).DOI: 10.1520/D3310-00R14.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM
14、Customer Service at serviceastm.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3The last approved version of this historical standard is referenced onwww.astm.org.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C7
15、00, West Conshohocken, PA 19428-2959. United States19. Cleanliness9.1 Clean the jars and covers so that no foreign matter ispresent.9.2 Abrade the metal strips that are exposed with 600-gritmesh emery paper to achieve a shiny surface.9.3 Expose the metals with corrosion preventive treatmentsas treat
16、ed.10. Observations10.1 Periodically, make observations of the control andexposed specimens. Note the following information on a scaleof five as follows:10.1.1 (1) Exposed sample less tarnished than control,10.1.2 (2) Exposed sample same as control,10.1.3 (3) Exposed sample slightly worse than contr
17、ol,10.1.4 (4) Exposed sample significantly worse than control,10.1.5 (5) Exposed sample badly corroded,10.1.6 Where possible remove the adhesive so that thecorrosive condition in the embedded area may be reported.11. Report11.1 Report the following information:11.1.1 Identification of the adhesive e
18、valuated and curecycle.11.1.2 Identification of the metal in detail (that is, specificalloy, temper and special treatment such as cold working, etc).11.1.3 Description of the condition of test (that is, whetherexposure was during cure, after cure and with or without waterbeing present).11.1.4 Storag
19、e time and temperature.11.1.5 Degree of corrosion on scale of five after convenientintervals. (If corrosion is rapid and severe initial report may beafter 1 h. Otherwise, observations may be made and recordedafter 1, 3, and 7 days.)11.1.6 Any unusual aspect of corrosion such as pitting,cracking, and
20、 adhesive cure inhibition, etc.12. Precision and Bias12.1 Precision and bias statements can not be established,because the test is subjective. The degree of corrosion presenton the test specimen is determined by visual comparison tocontrols, a judgment evaluation. This is not a practical basis forst
21、atements of this nature.13. Keywords13.1 adhesives; corrosion; corrosivity; moisture; waterASTM International takes no position respecting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination
22、 of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdraw
23、n. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM International Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your co
24、mments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown below.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single o
25、r multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org). Permission rights to photocopy the standard may also be secured from the ASTM website (www.astm.org/COPYRIGHT/).D3310 00 (2014)2
