1、 ENGINEERING MATERIAL SPECIFICATION Date Action Revisions Rev. 6 2017 07 24 Editorial See Summary of Revisions D. Stark, NA 2015 11 11 Editorial See Summary of Revisions D. Stark, NA 2011 05 05 Active A. Pan Controlled document at www.MATS Copyright 2017, Ford Global Technologies, LLC Page 1 of 9 PO
2、LYCARBONATE/ ACRYLONITRILE BUTADIENE WSS-M4D585-C1 STYRENE BLEND (PC+ABS) HIGH IMPACT MOLDING COMPOUND POLYCARBONATE/ ACRYLONITRILE BUTADIENE WRS-M4D585-C2 STYRENE BLEND (PC+ABS) MOLDING COMPOUND, RECYCLED 100% PCR/PIR RESIN CONTENT 1. SCOPE The material defined by this specification is a high impac
3、t thermoplastic molding compound based on a blend of polycarbonate (PC) and acrylonitrile butadiene styrene (ABS) for non-visible or painted applications. High impact PC+ABS is defined as being minimum 80% ductile at -30C. 2. APPLICATION WSS-M4D585-C1 This specification was released originally for m
4、aterial used for taillamp housing, in-mold film or wrapped aluminum substrate top finish panel of floor console, or painted finished molding. WRS-M4D585-C2 This specification was released originally for material used for non-visible interior applications. 2.1 LIMITATIONS WSS-M4D585-C1 This material
5、is not UV stabilized and should not be used for mold in color visible applications. WRS-M4D585-C2 This material is defined by 100% recycled PC +ABS thermoplastic molding compound for non-visible applications and is not UV stable. This material is not suitable for tail lamp housings. When used in dec
6、orated interior applications this material may require additional in process testing. Contact Materials Engineering for these requirements. 3. REQUIREMENTS 3.1 STANDARD REQUIREMENTS FOR PRODUCTION MATERIALS Material suppliers and part producers must conform to the Companys Standard Requirements for
7、Production Materials (WSS-M99P1111-A). 3.1.1 Many 4D resin specifications prior to 2011, identified certain requirements with the symbol (s), which indicated that the mean and 3 sigma values were to be reported. The specification minimum, maximum or range was established using 3 sigma data. For 2011
8、 and beyond, refer to Table 1 for number of samples required for each test to establish specification limits. ENGINEERING MATERIAL SPECIFICATION WSS-M4D585-C1 / WRS-M4D585-C2 Controlled document at www.MATS Copyright 2017, Ford Global Technologies, LLC Page 2 of 9 3.1.2 WSS-M4D585-C1 This specificat
9、ion is based on virgin materials. 3.1.3 WRS-M4D585-C2 This specification must contain 100% Post-Consumer Recycled (PCR) and/or Post-Industrial Recycled (PIR) content as defined by WRS-M99P42-A1 for polycarbonate (PC) and/or acrylonitrile butadiene styrene (ABS). 3.1.4 The use of regrind is permitted
10、 for economic / environmental reasons, with compliance as indicated in Ford Engineering CAD and Drafting Standard E-4. 3.1.5 Materials used in interior applications must meet the requirements outlined in WSS-M99P2222-D1/Latest, Performance, Vehicle Interior Environment Quality, Component and Allerg
11、en Requirements. Data must be included in material submission package. 3.1.6 Performance Criteria: WSS-M4D585-C1: Parts using this specification shall meet the appropriate performance specifications: WSK-M98P10-A/latest for exterior lighting application, WSS-M15P4-F/Latest, non-visible applications
12、requirements only, WSS-M2P188-A1/Latest for painted interior applications, WSS-M15P45-B/Latest for wrapped instrument panel (IP) and soft interior components, and WSS-M15P34-D/Latest for interior trim components with appliqus. WRS-M4D585-C2: Parts using this specification shall meet the appropriate
13、performance specifications: WSS-M15P4-F/Latest, non-visible applications requirements only. 3.1.7 As specified in WSS-M99P1111-A, paragraph 3.2, Ford Materials Engineering may request a Control Plan and Certificate of Analysis (CoA) containing lot testing requirements which must include, but are not
14、 limited to: WSS-M4D585-C1: Melt Flow Rate WRS-M4D585-C2: Impact Strength, Notched Charpy Melt Flow Rate Vicat Softening Temperature 3.2 SAMPLE PREPARATION Unless otherwise specified all tests shall be carried out on injection molded, one-end gated test specimens. The test specimens A and D shall be
15、 molded using molding conditions defined in ISO 2580-2. No annealing is allowed. See Table 1 for the number of specimens required. ENGINEERING MATERIAL SPECIFICATION WSS-M4D585-C1 / WRS-M4D585-C2 Controlled document at www.MATS Copyright 2017, Ford Global Technologies, LLC Page 3 of 9 Specimens shal
16、l be as follows: Specimen A 150 minimum x 10 x 4.0 +/- 0.2 mm (ISO 527-2, Specimen Type 1A) Specimen B 355 x 100 x 1.0 +/- 0.1 mm (ISO 3795) Specimen C 145 x 60 x 3.2 +/- 0.2 mm Specimen D Center of Specimen A. 80 x 10 x 4.0 +/- 0.2 mm Specimen E 100 mm diameter x 3.2 mm Specimen F 80 mm diameter x
17、3.2 mm Specimen G 90 mm x 200 mm Specimen H 50 +/- 1 mm diameter x 3.2 +/- 0.2 mm Specimen I 100 mm x 150 mm, min 3.3 MATERIAL PROPERTIES 3.3.1 Density 1.10 - 1.20 g/cm3 (ISO 1183, Method A) 3.3.2 Tensile Strength at Yield C1 C2 (ISO 527-1 Flow Cross Flow 7.3 8.0 E-5 mm/mm/C E-5 mm/mm/C 3.4.3 Moldin
18、g Shrinkage After 48 h at 23 2 C (For specific method and sample size, contact Materials Engineering) Flow Cross Flow 0.75 0.76 % % 3.4.4 Post Shrinkage (For specific method and sample size, contact Materials Engineering. Values show total shrinkage) - After 48 h at 80 C Flow Cross Flow - After 30 m
19、inutes at 120 C Flow Cross Flow 0.83 0.86 0.83 0.84 % % % % 3.4.5 Impact Strength, Multiaxial; Max Load Energy at 23 2 C; 2.2 m/s 56 J 3.4.5 Impact Strength, Multiaxial; Max Load Energy at -30 2 C; 2.2 m/s 59 J 3.4.5 Impact Strength, Multiaxial; Max Load Energy at 23 2 C; 6.6 m/s 51 J 3.4.5 Impact S
20、trength, Multiaxial; Max Load Energy at -30 2 C; 6.6 m/s 60 J 3.4.6 Poissons Ratio 0.35 N/A 3.4.7.1 Impact Strength, Notched Izod; At 23 2 C 50 kJ/m2 3.4.7.2 Impact Strength, Notched Izod; At -40 2 C 31 kJ/m2 3.4.8 Tensile Strength at Break WRS-M4D585-C2 Only 30-50 MPa 3.4.9 Elongation at Break WRS-
21、M4D585-C2 Only 15-60 % 4.3 GENERIC IDENTIFICATION AND MARKING OF PLASTIC PRODUCTS PC+ABS (ISO 1043/11469) ENGINEERING MATERIAL SPECIFICATION WSS-M4D585-C1 / WRS-M4D585-C2 Controlled document at www.MATS Copyright 2017, Ford Global Technologies, LLC Page 8 of 9 Table 1: Minimum Sample Size Initial Ap
22、proval * New Manufacturing Location for Previously Approved Material Para. Test Minimum Lots Specimens per Lot Total Test Specimens Lots Specimens per lot Total Test Specimens 3.1 WSS-M99P1111-A 3.1.5 WSS-M99P2222-D1 Total Carbon, Hazardous Substances, Formaldehyde, Acraldehyde, Acetaldehyde (See be
23、low for odor and fogging) 1 1 1 per test 1* 1* 1 per test* 3.3.1 Density 1 3 3 3.3.2 Tensile Strength at Yield* 3 5 15 1 5 5 3.3.3 Elongation at Yield* 3 5 15 1 5 5 3.3.4 Tensile Modulus 1 10 10 3.3.5 Flexural Modulus* 3 10 30 1 10 10 3.3.6 Impact Strength Charpy, Notched (per condition)* 3 10 30 1
24、10 10 3.3.7 Heat Deflection Temperature* 3 2 6 1 2 2 3.3.8 Vicat Softening Temperature* 3 2 6 1 2 2 3.3.9 Heat Aging Performance 3.3.9.1 Tensile Strength at Yield, Change 1 5 5 3.3.9.2 Impact Strength, Notched Charpy, Change 1 10 10 3.3.10 Hydrolytic Stability 1 10 10 3.3.11 Odor 1 9 9 3.3.12 Foggin
25、g Photometric 1 3 3 3.3.13 Flammability 1 5 5 3.4.1 Melt Flow Rate 1 1 1 3.4.2 Coefficient of Linear Thermal Expansion (per condition) 1 3 3 3.4.3 Mold Shrinkage 1 5 5 3.4.4 Post Shrinkage 1 5 5 3.4.5 Impact Strength, Multiaxial (per condition) * 3 10 30 1 10 10 3.4.6 Poissons Ratio 1 5 5 3.4.7 Impa
26、ct Strength, Izod, Notched (per condition) 1 10 10 3.4.8 Tensile Strength at Break* 3 5 15 3.4.9 Elongation at Break* 3 5 15 3.4.10 Curves - FTIR - TGA - DSC - CLTE Engineering Stress/Strain at 23 C 1 1 1 per test * For these requirements the 3 sigma value from the raw data is used to meet the requi
27、rements. * Testing applies to WRS-M4D585-C2 materials only * Recycled resins must always follow the initial approval testing. The New manufacturing location for previously approved materials is not applicable for recycled resins. ENGINEERING MATERIAL SPECIFICATION WSS-M4D585-C1 / WRS-M4D585-C2 Contr
28、olled document at www.MATS Copyright 2017, Ford Global Technologies, LLC Page 9 of 9 5. SUMMARY OF REVISIONS 2017 07 24 Editorial: Paragraph 3.1.3 Clarified the recycled content source Paragraph 3.1.7 Modified the lot testing requirements for WRS-M4D585-C2 2015 11 11 Editorial: Corrected C2 title Cl
29、arified limitations for C2 suffix. 2015 03 27 Added Recycled and Polycarbonate resin to C2 title Added a statement in limitations and 3.1.3 for C2 that recycled is for PC content only, ABS content is virgin. 2013 10 31 Added C2 Suffix Added section 2.1 limitations Modified performance criteria Updat
30、ed WSS-M99P2222-B1 to D1 Modified the following properties: density, tensile at yield, elongation at yield, impact strength, notched charpy, impact strength multiaxial, Removed gravimetric fogging Added the following for the C2 suffix only: tensile strength at break, elongation at break Updated typical property section Updated table 1 to reflect changes in spec. Added statement about testing recycled resin in table 1. 2011 08 19 Editorial update to the note after Table 1
