1、 , , - , ()INTERSTATE COUNCIL FOR STANDARDIZATION, METROLOGY AND CERTIFICATION(ISC)320152012, - 1.092 . - 1.22009 . , . , , -, 1 - ( ), - ( )2 ()3 , (- 3 2012 . 54-) : ( 3166) 00497 ( 3166) 00497 KZKGRUTJUZ 4 27 2013 . 240- 320152012 - 12014 .5 5403520106 - , - . () - . , , 2014 -, II 3201520121 12
2、13 24 , , 25 46 .47 .88 - .119 1310 .1311 13 14III 320152012 , , - Food products, feeds, food raw materials. Method of determination of anabolic steroids and stylbenderivatives by gas chromatography using mass spectrometry 201407011 , , - - . 0,1 100,0 /. - .2 : 12.1.00588 . - 12.1.00776 . . 12.1.01
3、979 . . - 12.2.0852002 , . . - 6175 . . 177074 ( 104283, 478880) . -, , , . 260379 . . 311877 . . 416676 . . 699577 . -. 13496.080 , . 1364778 . . 1386768 . 241042001* . 2436380 . . 2533682 . , * 532282008.1 320152012 - - , 1 , . (), (-) . , , , , .3 - - (-) - . - - , .4 , , 4.1 :- -, 45 650 (. . .)
4、, 1,0 . . . - : 2 (- 45 350 . . . 1 ) / m/z 284 10/1;- 30 c180 0,25 c180 0,25 30;- - ;- ;- ;- ( ) 18 250 c180 4,6 c180 5 ;- 18 10 c180 4,6 c180 5 ;- 10100 3, 40200 3, 2001000 3, 15 3 2 % (TransferpettorBrand, )*;- I II d = 0,01 , - e = 100 d 24104;- 250 ;- - ;- 20 280 / - 30 100 ;- 3500 / 10 25 , 15
5、, 50 3 1,5 3;- 12 3, - 18 50 ;- ;- 4 3 -;* . - .2 320152012- 40 3 -;- 2 3 100 3;- 2-10-2 1770;- 2-100-2 1770;- 2-1000-2 1770;- -1-100-14/23 25336;- 20 1 3;- - , c1770,01 . - .4.2 :- 60;- Subtilisine A (Sigma, , P-5380)*;- 61, . .;- 3118, . .;- , . .;- - ;- ;- N-N- () (Sigma, , -7891)*;- () (Aldrich,
6、 , 19,552-9)*;- (), . .;- 13647;- N,N- () (Sigma, , T-5634)*;- () (Sigma, T-4252)*;- , . .;- (Aldrich, , 22,690-4)*;- -, . .;- 24363, . .;- - 6995;- , . .;- , . .;- , . .;- 2603, . .;- C18 40 (Varian, , 12213012)*;- Helix pomatia (Merck, , 1.04114)*;- 4166, . .;- , . . ;- ()-, . . 2 . . 3 . . . 1386
7、7.4.3 :- -d6 99,0 % (RIKILT*, BRS 01)*;- -d2 99,0 % (RIKILT, BRS 02)*;- -d4 98,0 % (RIKILT, BRS 03)*;- -d3 98,0 % (RIKILT, BRS 04)*;- -d3 98,0 % (RIKILT, BRS 05)*;-17c98-d3 98,0 % (RIKILT, BRS 54)*;-17c98-d2 98,0 % (RIKILT, BRS 55);-17c97- 99,0 % (RIKILT, BRS 56)*;-17c97- 99,0 % (RIKILT, BRS 57)*;*
8、. .* , .3 320152012-17c98- 99,0 % (RIKILT, BRS 58)*;-17c98-d2 99,0 % (RIKILT, BRS 59)*;-17c98-d3 99,0 % (RIKILT, BRS 72)*;- 17- 98,0 % (Acros, 225730050)*-17c97- 98,0 % (Sigma, E-4876)*- c98- 98,0 % (Sigma, E-8875)*;-17c98- 99,0 % (Acros, 164410050)*;- 99,0 % (Sigma, P-0130)*;- 19- 99,0 % (Fluka, 74640)*;- 98,0 % (Sigma, D-3253)*;- 99,0 % (Sigma, H-7753)*;- 99,0 % (Sigma, D-4628)*;- *:1) (IRMM*,BCR-411);2) (IRMM, BCR-411);3) 17c97- (IRMM, BCR-474/475).5 5.1 1- 2- 12.1.007, , , 12.1.005.5.2 , , - .5.3 .5.4 12.2.085 - , , , .5.5 - - 12.1.019 .5.6 , -
