1、865B2018( )6110 2 51 -p210 5 21 2Z/E R/S3 4 5,7,7- 2.2.1-2-5 8- -2-30 15 21A BC D2a bc dAabdcBbadcCbacdDdabc32a bc dAabcdBadcbCdacbDdabc4A BC D5 + 2- - 2-A BC D6 -PA BC D7a bc dAabdc Babcd Cbcad Dbcda8 HBra bc d3Aabcd Bbcda Cdcba Ddcab9a bc dAabcd Bdabc Cdacb Dadcb10 SN2A BC D Walden11A BC Saytzeff
2、D12A 3- B 1-C D 2-13 Fielder-CraftsA BC D14A BC D15ABCD Hinsdberg20 10 2412345610 2 51.2. 3- -2- 3- -1-3- -2- 3- -1-515 3 512 HBr324 3 812316 2 812615 3 51 A (C6H10) Ag(NH3)2OH A NiB(C6H14) B A B2 A C10H12O21700 cm-1: / 2.1 ( , 3H), 2.9 ( , 2H), 4.3 ( , 2 H), 7.2 ( , 5 H)A3 A (C8H10O) B (C8H9OCl)A C (C8H16O) C D (C8H14)D E (CH3COCH2CH2CH2CH(CH3)CO2H) A