1、Designation: F15 04 (Reapproved 2013)Standard Specification forIron-Nickel-Cobalt Sealing Alloy1This standard is issued under the fixed designation F15; the number immediately following the designation indicates the year of originaladoption or, in the case of revision, the year of last revision.Anum
2、ber in parentheses indicates the year of last reapproval.Asuperscriptepsilon () indicates an editorial change since the last revision or reapproval.1. Scope1.1 This specification covers an iron-nickel-cobalt alloy,UNS K94610 containing nominally 29 % nickel, 17 % cobalt,and 53 % iron, in the forms o
3、f wire, rod, bar, strip, sheet, andtubing, intended primarily for sealing to glass in electronicapplications.1.2 The values stated in inch-pound units are to be regardedas standard. The values given in parentheses are mathematicalconversions to SI units that are provided for information onlyand are
4、not considered standard.1.3 The following hazard caveat pertains only to the testmethod portion, Sections 13 and 14 of this specification. Thisstandard does not purport to address all of the safety concerns,if any, associated with its use. It is the responsibility of the userof this standard to esta
5、blish appropriate safety and healthpractices and determine the applicability of regulatory limita-tions prior to use.2. Referenced Documents2.1 ASTM Standards:2E3 Guide for Preparation of Metallographic SpecimensE8 Test Methods for Tension Testing of Metallic MaterialsE18 Test Methods for Rockwell H
6、ardness of Metallic Ma-terialsE92 Test Method for Vickers Hardness of Metallic Materials(Withdrawn 2010)3E112 Test Methods for Determining Average Grain SizeE140 Hardness Conversion Tables for Metals RelationshipAmong Brinell Hardness, Vickers Hardness, RockwellHardness, Superficial Hardness, Knoop
7、Hardness, andScleroscope HardnessE228 Test Method for Linear Thermal Expansion of SolidMaterials With a Push-Rod DilatometerF14 Practice for Making and Testing Reference Glass-MetalBead-SealF140 Practice for Making Reference Glass-Metal Butt Sealsand Testing for Expansion Characteristics by Polarime
8、tricMethodsF144 Practice for Making Reference Glass-Metal SandwichSeal and Testing for Expansion Characteristics by Polari-metric Methods3. Ordering Information3.1 Orders for material under this specification shall includethe following information:3.1.1 Size,3.1.2 Temper (Section 6),3.1.3 Surface fi
9、nish (Section 10),3.1.4 Marking and packaging (Section 17), and3.1.5 Certification if required.4. Chemical Requirements4.1 The material shall conform to the requirements as tochemical composition prescribed in Table 1.5. Surface Lubricants5.1 All lubricants used during cold-working operations,such a
10、s drawing, rolling, or spinning, shall be capable of beingremoved readily by any of the common organic degreasingsolvents.6. Temper6.1 The desired temper of the material shall be specified inthe purchase order.6.2 TubeUnless otherwise agreed upon by the supplier ormanufacturer and the purchaser, the
11、se forms shall be given afinal bright anneal by the manufacturer and supplied in theannealed temper.6.3 Strip and SheetThese forms shall be supplied in one ofthe tempers given in Table 2 or in deep-drawing temper, asspecified.6.4 Wire and Rod These forms shall be supplied in one ofthe tempers given
12、in Table 3 as specified. Unless otherwisespecified, the material shall be bright annealed and supplied intemper A (annealed).1This specification is under the jurisdiction of ASTM Committee F01 onElectronics and is the direct responsibility of Subcommittee F01.03 on MetallicMaterials.Current edition
13、approved May 1, 2013. Published May 2013. Originallyapproved in 1961 as F15 61T. Last previous edition approved in 2009 as F15 04(2009). DOI: 10.1520/F0015-04R13.2For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm.org. For Annual Book
14、of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.3The last approved version of this historical standard is referenced onwww.astm.org.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959. United States11
15、50FIG. 1 Normal Annealed Specimen Showing No Transformation150FIG. 2 Partially Transformed SpecimenF15 04 (2013)27. Grain Size7.1 Strip and sheet for deep drawing shall have an averagegrain size not larger than ASTM No. 5 (Note 1), and no morethan 10 % of the grains shall be larger than No. 5 whenme
16、asured in accordance with Test Methods E112.NOTE 1This corresponds to a grain size of 0.065 mm, or 16 grains/in.2of image at 100 .8. Hardness8.1 Deep-Drawing TemperFor deep drawing, the hardnessshall not exceed 82 HRB for material 0.100 in. (2.54 mm) andless in thickness and 85 HRB for material over
17、 0.100 in. inthickness when determined in accordance with Test MethodsE18. See also Test Method E92 for Vickers Hardness and Table3, E140 for the appropriate conversion between various hard-ness scales.8.2 Rolled and Annealed TempersHardness tests whenproperly applied can be indicative of tensile st
18、rength. Hardnessscales and ranges for these tempers, if desirable, shall benegotiated between supplier and purchaser.9. Tensile Strength9.1 Sheet and Strip:9.1.1 Tensile strength shall be the basis for acceptance orrejection for the tempers given in Table 2 and shall conformwith the requirements pre
19、scribed.9.1.2 Tension test specimens shall be taken so the longitu-dinal axis is parallel to the direction of rolling and the test shallbe performed in accordance with Test Methods E8.9.2 Wire and Rod:9.2.1 Tensile strength shall be the basis for acceptance orrejection for the tempers given in Table
20、 3. and shall conform tothe requirements prescribed.9.2.2 The test shall be performed in accordance with TestMethod E8.10. Surface Finish10.1 The standard surface finishes available shall be thoseresulting from the following operations:10.1.1 Hot rolling,10.1.2 Forging,10.1.3 Centerless grinding (ro
21、d),10.1.4 Belt polishing,10.1.5 Cold rolling, and10.1.6 Wire drawing.11. Thermal Expansion Characteristics11.1 The average linear coefficients of thermal expansionshall be within the limits specified in Table 4.12. Test for Thermal Expansion12.1 Heat the specimen in a hydrogen atmosphere for1hat900C
22、, followed by 15 min at 1100C. Between the 900 and1100C heat-treatment periods, the specimen may be cooled toroom temperature if desired. Cool the specimen from 1100 to200C in the hydrogen atmosphere at a rate not to exceed5C/min.12.2 Determine the thermal expansion characteristics inaccordance with
23、 Test Method E228.NOTE 2For critical glass sealing applications, it is recommended thatthe user conduct functional testing in accordance with Practices F14, F140or F144. Such tests circumvent possible problems with thermal expansionmeasurements and glass setting point estimates.NOTE 3The thermal tre
24、atment described in this section is for purposesof the thermal expansion test only. Consult the non-mandatory appendixof this document for guidance on annealing conditions for various productforms.13. Transformation13.1 The temperature of the gamma-to-alpha transformationshall be below 78.5C when th
25、e material is tested in accor-dance with Section 14. However, for material whose smallestTABLE 1 Chemical RequirementsElement Composition, %Iron, nominal 53ANickel, nominal 29ACobalt, nominal 17AManganese, max 0.50Silicon, max 0.20Carbon, max 0.04Aluminum, max 0.10BMagnesium, max 0.10BZirconium, max
26、 0.10BTitanium, max 0.10BCopper, max 0.20Chromium, max 0.20Molybdenum, max 0.20AThe iron, nickel, and cobalt requirements listed are nominal. They shall beadjusted by the manufacturer so that the alloy meets the requirements forcoefficient of thermal expansion given in Table 4.BThe total of aluminum
27、, magnesium, zirconium, and titanium shall not exceed0.20 %.TABLE 2 Tensile Strength Requirements for Sheet and StripTemperDesignationTemper Name Tensile Strength, ksi(MPa)A annealed 82 max (570 max)B14 hard 75 to 90 (520 to 630)C half hard 85 to 100 (590 to 700)D34 hard 95 to 110 (660 to 770)E hard
28、 100 min (700 min)TABLE 3 Tensile Strength Requirements for Wire and RodTemper Designation Tensile Strength, ksi (MPa)A 85 (585) maxB 85 to 105 (585 to 725)C 95 to 115 (655 to 795)D 105 to 125 (725 to 860)E 125 (860) minTABLE 4 Coefficients of Thermal ExpansionTemperature Range, CAverage Linear Coef
29、ficientof Thermal Expansion,Am/mC30 to 40030 to 4504.60 to 5.205.10 to 5.50ATypical thermal expansion data for the alloy covered by these specifications areprovided in Appendix X1.F15 04 (2013)3dimension is over78 in. (22.2 mm), some localizedtransformation, acceptable to the purchaser, may be toler
30、ated.NOTE 4Lower transformation temperatures, ranging to as low as196C, may be negotiated between supplier and purchaser. The 196Ctransformation temperature corresponds to immersing a sample (preparedaccording to 14.1) in liquid nitrogen for a minimum of 1 h.14. Test for Transformation14.1 Cut the s
31、pecimen from any part of the material, butpreferably including the entire cross section, degrease it, thenheat treat it as described in 12.1. When cool, polish the crosssection of the specimen and etch (Note 5) it in accordance withMethod E3. Then subject the specimen to the temperatureproduced by a
32、n excess of dry ice in acetone (78.5C) for atleast 4 h. After the low-temperature treatment, examine thespecimen at a mangification of 150 for the presence of theacicular crystals characteristic of the alpha phase. Becausethese crystals may occur only in small localized areas, examinecarefully the e
33、ntire polished cross section.14.2 Specimens that show no transformation and that showpartial transformation are illustrated in Fig. 1 and Fig. 2,respectively.NOTE 5A suggested etchant is a solution of three parts by volume ofconcentrated hydrochloric acid and one part of concentrated nitric acidsatu
34、rated with cupric chloride (CuCl22H2O). This etchant is moreeffective when allowed to stand for 20 min after mixing. After severalhours it loses its strength and should be discarded at the end of the day.Etching is best accomplished by swabbing the specimen with cottonsoaked with the etchant. Etchin
35、g is usually complete when the surface ofthe metal appears to have turned dull.15. Dimensions and Permissible Variations15.1 Cold-Rolled StripCold-rolled strip shall conform tothe permissible variations in dimensions prescribed in Table 5,Table 6, and Table 7.15.2 Round Wire and RodWire and rod shal
36、l conform tothe permissible variations in dimensions prescribed in Table 8.15.3 Cold-Drawn TubingCold-drawn tubing, available ei-ther as seamless or welded, shall conform to the permissiblevariations prescribed in Table 9.16. General Requirements16.1 The material shall be commercially smooth, unifor
37、m incross section, in composition, and in temper; it shall be free ofscale, corrosion, cracks, seams, scratches, slivers, and otherdefects as best commercial practice will permit.17. Packaging and Marking17.1 Packaging shall be subject to agreement between thepurchaser and the seller.17.2 The materi
38、al as furnished under this specification shallbe identified by the name or symbol of the manufacturer and bymelt number. The lot size for determining compliance with therequirements of this specification shall be one heat.18. Investigation of Claims18.1 Where any material fails to meet the requireme
39、nts ofthis specification, the material so designated shall be handled inaccordance with a mutual agreement between the purchaserand the seller.19. Keywords19.1 controlled expansion alloy; glass to metal sealing;iron-nickel-cobalt alloy; UNS #K94610; vacuum electronicapplicationsTABLE 5 Permissible V
40、ariations in Thickness of Cold-Rolled StripNOTE 1 Measurement shall be made at least38 in. (9.5 mm) from the edge of strip over 1 in. (25.4 mm) wide.Specified Thickness, in. (mm)Permissible Variations in Thickness for Width Given, in. (mm)Under 3 (76) Over 3 to 6 (76 to 152) Over 6 to 12 (152 to 305
41、) Over 12 to 16 (305 to 406)0.160 to 0.100 (4.06 to 2.54), incl 0.002 (0.051) 0.003 (0.076) 0.004 (0.102) 0.004 (0.102)0.099 to 0.069 (2.51 to 1.75), incl 0.002 (0.051) 0.003 (0.076) 0.003 (0.076) 0.004 (0.102)0.068 to 0.050 (1.73 to 1.27), incl 0.002 (0.051) 0.003 (0.076) 0.003 (0.076) 0.003 (0.076
42、)0.049 to 0.035 (1.24 to 0.89), incl 0.002 (0.051) 0.0025 (0.064) 0.003 (0.076) 0.003 (0.076)0.034 to 0.029 (0.86 to 0.74), incl 0.0015 (0.038) 0.002 (0.051) 0.0025 (0.064) 0.0025 (0.064)0.028 to 0.026 (0.71 to 0.66), incl 0.0015 (0.038) 0.0015 (0.038) 0.002 (0.051) 0.002 (0.051)0.025 to 0.020 (0.64
43、 to 0.51), incl 0.001 (0.025) 0.0015 (0.038) 0.002 (0.051) 0.002 (0.051)0.019 to 0.017 (0.48 to 0.43), incl 0.001 (0.025) 0.001 (0.025) 0.0015 (0.038) 0.002 (0.051)0.016 to 0.012 (0.41 to 0.31), incl 0.001 (0.025) 0.001 (0.025) 0.0015 (0.038) 0.0015 (0.038)0.011 to 0.0101 (0.28 to 0.26), incl 0.001
44、(0.025) 0.001 (0.025) 0.001 (0.025) 0.0015 (0.038)0.010 to 0.0091 (0.25 to 0.23), incl 0.001 (0.025) 0.001 (0.025) 0.001 (0.025) 0.001 (0.025)0.009 to 0.006 (0.23 to 0.15), incl 0.00075 (0.019) 0.00075 (0.019) . .Under 0.006 (0.15) 0.0005 (0.013) 0.0005 (0.013) . .F15 04 (2013)4TABLE 6 Permissible V
45、ariations in Thickness Across Width of StripSpecified ThicknessMaximum Variation in Thickness Across Width of Strip, Within Those Provided for inTable 4 for Edge Measurements for Widths and Thicknesses Given, in. (mm)in. mm5 (127) and Under Over 5 to 12 (127 to 300)Over 12 to 24 (300 to600), inclin.
46、 mm in. mm in. mm0.005 to 0.010, incl 0.17 to 0.03, incl 0.00075 0.0191 0.001 0.025 0.0015 0.038Over 0.010 to 0.025, incl 0.03 to 0.06, incl 0.001 0.025 0.0015 0.038 0.002 0.051Over 0.025 to 0.065, incl 0.06 to 0.16, incl 0.0015 0.038 0.002 0.051 0.0025 0.064Over 0.065 to316 , excl 0.16 to 0.48, exc
47、l 0.002 0.051 0.0025 0.064 0.003 0.076TABLE 7 Permissible Variations in Width of Cold-Rolled Strip Supplied in CoilsSpecified Thickness, in. (mm)Permissible Variations in Width for Widths Given, in. (mm)Under12 to316(12.7to4.8)12 to6(12.7to152)Over 6 to 9 (152to 229)Over 9 to 12 (229to 305)Over 12 t
48、o 20(305 to 508)Over 20 to 231516(508 to 608)0.187 to 0.161 (4.75 to 4.09) . 0.016 (0.41) 0.020 (0.51) 0.020 (0.51) 0.031 (0.79) 0.031 (0.79)0.160 to 0.100 (4.06 to 2.54) 0.010 (0.25) 0.010 (0.25) 0.016 (0.41) 0.016 (0.41) 0.020 (0.51) 0.020 (0.51)0.099 to 0.069 (2.51 to 1.75) 0.008 (0.20) 0.008 (0.
49、20) 0.010 (0.25) 0.010 (0.25) 0.016 (0.41) 0.020 (0.51)0.068 (1.73) and under 0.005 (0.13) 0.005 (0.13) 0.005 (0.13) 0.010 (0.25) 0.016 (0.41) 0.020 (0.51)TABLE 8 Permissible Variations in Diameter of Wire and RodSpecified Diameter, in. (mm)Permissible Variations in Diameter, in.(mm)Wire (Coiled, Spooled or Straight Lengths)0.002 to 0.0043 (0.05 to 0.110) 0.0002 (0.005)0.0044 to 0.0079 (0.111 to 0.202) 0.00025 (0.006)0.008 to 0.0149 (0.20 to 0.379) 0.0003 (0.008)0.015 to 0.0199 (0.38 to 0.507) 0.0004 (0.010)0.020 to 0.0309 (0
