1、October 2016 English price group 28No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 13.040.40!%18“2581421www.din.deD
2、IN EN 19694-3Stationary source emissions Determination of greenhouse gas (GHG) emissions in energyintensive industries Part 3: Cement industry;English version EN 196943:2016,English translation of DIN EN 19694-3:2016-10Emissionen aus stationren Quellen Bestimmung von Treibhausgasen (THG) aus energie
3、intensiven Industrien Teil 3: Zementindustrie;Englische Fassung EN 196943:2016,Englische bersetzung von DIN EN 19694-3:2016-10missions de sources fixes Dtermination des missions de gaz effet de serre (GES) dans les industries nergointensives Partie 3: Industrie du ciment;Version anglaise EN 196943:2
4、016,Traduction anglaise de DIN EN 19694-3:2016-10www.beuth.deDocument comprises 78 pagesDTranslation by DIN-Sprachendienst.In case of doubt, the German-language original shall be considered authoritative.This standard has been included in the VDI/DIN Handbook on air quality, Volume 2. 10.16 DIN EN 1
5、9694-3:2016-10 2 A comma is used as the decimal marker. National foreword This document has been prepared by Technical Committee CEN/TC 264 “Air quality”, Working Group WG 33 “Greenhouse gas (GHG) emissions in energy-intensive industries”. The responsible German body involved in its preparation was
6、the Kommission Reinhaltung der Luft im VDI und DIN Normenausschuss KRdL (Commission on Air Pollution Prevention of VDI and DIN Standards Committee KRdL), Section I Umweltschutztechnik. EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 19694-3 July 2016 ICS 13.040.40 English Version Stationary sou
7、rce emissions - Determination of greenhouse gas (GHG) emissions in energy-intensive industries - Part 3: Cement industry missions de sources fixes - Dtermination des missions de gaz effet de serre (GES) dans les industries nergo-intensives - Partie 3: Industrie du ciment Emissionen aus stationren Qu
8、ellen - Bestimmung von Treibhausgasen (THG) aus energieintensiven Industrien - Teil 3: Zementindustrie This European Standard was approved by CEN on 5 May 2016. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this European Standard
9、the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN member. This European Standard exists in three official versions (English, Fr
10、ench, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgium, Bulgari
11、a, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turke
12、y andUnited Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2016 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref
13、. No. EN 19694-3:2016 EEN 19694-3:2016 (E) 2 Contents Page European foreword . 4 Introduction 5 1 Scope 9 2 Normative references 9 3 Terms and definitions . 9 4 Symbols and abbreviated terms . 12 5 Determination of GHGs based on the mass balance method 13 5.1 General . 13 5.2 Major GHG in cement 14
14、5.3 Determination based on mass balance 14 5.4 Determination by stack emission measurements 14 5.5 Gross and net emissions 14 6 System boundaries 21 6.1 General . 21 6.2 Operational boundaries . 21 6.3 Organizational boundaries . 22 7 Direct GHG emissions and their determination 25 7.1 General . 25
15、7.2 CO2from raw material calcinations . 28 7.3 Reporting of CO2emissions from raw material calcination based on clinker output: summary of IPCC and CSI recommendations and default emission factor for clinker . 37 7.4 Determining the FD calcination rate . 38 7.5 Direct determination of the CO2emissio
16、n factor of FD from analysis of CO2content . 39 7.6 Cement specific issues for fuels 39 7.7 GHG from fuels for kilns . 41 7.8 GHG from non-kiln fuels 41 7.9 GHG from the combustion of wastewater 42 7.10 Non-CO2GHG emissions from the cement industry . 42 8 Energy indirect and other indirect GHG emiss
17、ions and their determination 43 8.1 General . 43 8.2 CO2from external electricity production 43 8.3 CO2from bought clinker 44 9 Baselines, acquisitions and disinvestments . 44 10 Reporting 45 10.1 General . 45 10.2 Corporate environmental reporting . 45 10.3 Reporting periods 46 10.4 Performance ind
18、icators . 47 11 Uncertainty of GHG inventories 53 11.1 Introduction to uncertainty assessment . 53 11.2 Uncertainty of activity data 56 11.3 Uncertainties of fuel and material parameters . 56 DIN EN 19694-3:2016-10 EN 19694-3:2016 (E) 3 11.4 Uncertainties of continuous stack emission measurements 57
19、 11.5 Evaluation of the overall uncertainty of a GHG inventory . 58 11.6 Application of default values instead of analysing results 58 12 Considerations for applying this standard (verification procedure) 59 Annex A (informative) Findings from the field tests (analytical interferences). 61 Annex B (
20、informative) Emission factors 65 Annex C (informative) Uncertainty of activity data . 67 Annex D (informative) Overview on terms in a cement plant 73 Bibliography . 75 DIN EN 19694-3:2016-10 EN 19694-3:2016 (E) 4 European foreword This document (EN 19694-3:2016) has been prepared by Technical Commit
21、tee CEN/TC 264 “Air quality”, the secretariat of which is held by DIN. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by January 2017, and conflicting national standards shall be withdrawn at the la
22、test by January 2017. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. This document has been prepared under a mandate M/478 given to C
23、EN by the European Commission and the European Free Trade Association. EN 19694, Stationary source emissions Determination of greenhouse gas (GHG) emissions in energy-intensive industries is a series of standards that consists of the following parts: Part 1: General aspects Part 2: Iron and steel in
24、dustry Part 3: Cement industry Part 4: Aluminium industry Part 5: Lime industry Part 6: Ferroalloy industry According to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cr
25、oatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
26、 the United Kingdom. DIN EN 19694-3:2016-10 EN 19694-3:2016 (E) 5 Introduction This European Standard for the cement industry has been based on the WBCSD/CSI and WRI: “CO2and Energy Accounting and Reporting Standard for the Cement Industry” 1. Overview of cement manufacturing process Cement manufact
27、ure includes three main process steps (see Figure 1): a) preparing of raw materials and fuels; b) producing clinker, an intermediate, through pyro-processing of raw materials; c) grinding and blending clinker with other products (“mineral components”) to make cement. There are two main sources of di
28、rect CO2emissions in the production process: calcination of raw materials in the pyro-processing stage, and combustion of kiln fuels. These two sources are described in more detail below. Other CO2sources include direct GHG emissions from non-kiln fuels (e.g. dryers for cement constituents products,
29、 room heating, on-site transports and on-site power generation), and indirect GHG emissions from, e.g. external power production and transports. Non-CO2greenhouse gases covered by the Kyoto Protocol1, apart from carbon monoxide (CO) methane (CH4) and nitrous oxide (N2O), are not relevant in the ceme
30、nt context, in the sense that direct GHG emissions of these gases are negligible. Figure 1 Process steps in cement manufacture (source: Ellis 2000, based on Ruth et al. 2000) 1Methane (CH4), nitrous oxide (N2O), sulfur hexafluoride (SF6), partly halogenated fluorohydrogencarbons (HFC) and perfluorat
31、ed hydrocarbons (PFC) DIN EN 19694-3:2016-10 EN 19694-3:2016 (E) 6 Table 1 Overview of input places of materials Raw meal Input place Raw materials from natural resources Raw mill Alternative raw materials Raw mill Raw material flows for clinker production Input place Raw meal Kiln feed Fuel ashes B
32、urner or precalciner or fuel dryer Additional raw materials not part of the kiln feed Kiln inlet Fuels flows for clinker and cement production Input place Fossil fuels Burner or precalciner or fuel dryer or raw material dryer Alternative fuels Burner or precalciner or fuel dryer or raw material drye
33、r Alternative fossil fuels Burner or precalciner or fuel dryer or raw material dryer Mixed fuels Burner or precalciner or fuel dryer or raw material dryer Biomass fuels Burner or precalciner or fuel dryer or raw material dryer Cement kiln dust Output place Dust return Preheater Filter dust Precipita
34、tor / filter By pass dust Bypass filter Cement constituents based products Output place Clinker Kiln (cooler) Cement Cement mill Blast furnace slag Cement mill or grinding station Fly ash Cement mill or grinding station Gypsum Cement mill or grinding station Cooler dust Cooler, is normally added to
35、the clinker flow to the clinker silo Cement kiln dust Preheater or precipitator or filter or bypass filter Limestone Cement mill or grinding station Burnt shale Cement mill or grinding station Pozzolana Cement mill or grinding station Silica fume Cement mill or grinding station DIN EN 19694-3:2016-1
36、0 EN 19694-3:2016 (E) 7 CO2from calcination of raw materials In the clinker production process, CO2is released due to the chemical decomposition of calcium, magnesium and other carbonates (e.g. from limestone) into lime: CaCO3+ heat CaO + CO2MgCO3+ heat MgO + CO2This process is called “calcining“ or
37、 “calcination“. It results in direct CO2emissions through the kiln stack. When considering CO2emissions due to calcination, two components may be distinguished: CO2from raw materials actually used for clinker production, these raw materials are fully calcined in the clinker production process; CO2fr
38、om raw materials leaving the kiln system as partly calcined cement kiln dust (CKD), or as normally fully calcined bypass dust. CO2from actual clinker production is proportional to the lime content of the clinker,2, which in turn varies little in time or between different cement plants. As a result,
39、the CO2emission factor per tonne of clinker is fairly stable with a default value in this standard of 525 kg CO2/t clinker (IPCC default: 510 kg CO2/t clinker, CSI default: 525 kg CO2/t clinker 19). The amount of kiln dust leaving the kiln system varies greatly with kiln types and cement quality sta
40、ndards, ranging from practically zero to over one hundred kilograms per tonne of clinker. The associated emissions are likely to be relevant in some countries or installations. CO2emissions from calcination of raw materials may be calculated by two methods which are in principle equivalent: Either b
41、ased on the amount and chemical composition of the products (clinker plus dust leaving the kiln system, output methods B1 and B2), or based on the amount and composition of the raw materials entering the kiln (input methods A1 and A2). See 7.2.1, 7.2.2 for details. CO2from organic carbon in raw mate
42、rials The raw materials used for clinker production usually contain a small fraction of organic carbon, which may be expressed as total organic carbon (TOC) content. Organic carbon in the raw meal is converted to CO2during pyro-processing. The contribution of this component to the overall CO2emissio
43、ns of a cement plant is typically very small (about 1 % or less). The organic carbon contents of raw materials may, however, vary substantially between locations and between the types of materials used. For example, the resulting emissions may be relevant if a cement company organization (used in th
44、is standard) consumes large quantities of certain types of fly ash or shale as raw materials entering the kiln. CO2from fuels for kiln operation The cement industry traditionally uses various fossil fuels to operate cement kilns, including coal, petroleum coke, fuel oil, and natural gas. Fuels deriv
45、ed from waste materials have become important substitutes for traditional fossil fuels. These alternative fuels (AF) include fossil fuel-derived fractions such as, e.g. waste oil and plastics, as well as biomass-derived fractions such as waste wood and dewatered sludge from wastewater treatment. Fur
46、thermore fuels are increasingly used which contain both fossil and biogenic carbon (mixed fuels), like e.g. (pre-treated) municipal and (pre-treated) industrial wastes (containing plastics, textiles, paper etc.) or waste tyres (containing natural and synthetic rubber). 2A second, but much smaller fa
47、ctor is the CaO and MgO content of the raw materials and additives used. DIN EN 19694-3:2016-10 EN 19694-3:2016 (E) 8 Both traditional fossil and alternative fuels result in direct CO2emissions through the kiln stack. However, biomass and bioliquids are considered “climate change-neutral“ in accorda
48、nce with IPCC definitions. Use of alternative (biomass- or fossil-derived) fuels may, in addition, lead to important emission reductions elsewhere, for instance from waste incineration plants or landfills. Mineral components (MIC) are natural and artificial materials with latent hydraulic properties
49、. Examples of MIC include natural pozzolana, blast furnace slag, and fly ash. In addition, gypsum is within this standard labelled as MIC. MICs are added to clinker to produce blended cement. In some instances, pure MICs are directly added to the concrete by the ready-mix or construction company. Use of MICs leads to an equivalent reduction of direct CO2emissions associated with clinker production, both from calcination and fuel combustion. A
