1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationBS EN ISO 1833-17:2010Textiles Quantitativechemical analysisPart 17: Mixtures of chlorofibres(homopolymers of vinyl chloride) andcertain other fibres (method using sulfuricacid)
2、(ISO 1833-17:2006)BS EN ISO 1833-17:2010 BRITISH STANDARDNational forewordThis British Standard is the UK implementation of EN ISO1833-17:2010. It is identical to ISO 1833-17:2006. It supersedes BS4407:1988 which will be withdrawn on publication of the otherparts of the BS EN ISO 1833 series.The UK
3、participation in its preparation was entrusted to TechnicalCommittee TCI/80, Chemical testing of textiles.A list of organizations represented on this committee can beobtained on request to its secretary.This publication does not purport to include all the necessaryprovisions of a contract. Users are
4、 responsible for its correctapplication. BSI 2011ISBN 978 0 580 72138 0ICS 59.060.01; 59.060.20Compliance with a British Standard cannot confer immunity fromlegal obligations.This British Standard was published under the authority of theStandards Policy and Strategy Committee on 28 February 2011.Ame
5、ndments issued since publicationDate Text affectedEUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN ISO 1833-17 October 2010 ICS 59.060.01 English Version Textiles - Quantitative chemical analysis - Part 17: Mixtures of chlorofibres (homopolymers of vinyl chloride) and certain other fibres (metho
6、d using sulfuric acid) (ISO 1833-17:2006) Textiles - Analyse chimique quantitative - Partie 17: Mlanges de chlorofibres (homopolymres de chlorure de vinyle) et de certaines autres fibres (mthode lacide sulfurique) (ISO 1833-17:2006) Textilien - Quantitative chemische Analysen - Teil 17: Mischungen a
7、us Chlorfasern (Homopolymere des Vinylchlorids) und bestimmten anderen Fasern (Schwefelsure-Verfahren) (ISO 1833-17:2006) This European Standard was approved by CEN on 12 September 2010. CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for givi
8、ng this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN Management Centre or to any CEN member. This European Standard exists in three official ver
9、sions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as the official versions. CEN members are the national standards bodies of Austria, Belgiu
10、m, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EUROPEAN COMMIT
11、TEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2010 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. EN ISO 1833-17:2010: EBS EN ISO 1833-17:20
12、10EN ISO 1833-17:2010 (E) 3 Foreword The text of ISO 1833-17:2006 has been prepared by Technical Committee ISO/TC 38 “Textiles” of the International Organization for Standardization (ISO) and has been taken over as EN ISO 1833-17:2010 by Technical Committee CEN/TC 248 “Textiles and textile products”
13、 the secretariat of which is held by BSI. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by April 2011, and conflicting national standards shall be withdrawn at the latest by April 2011. Attention i
14、s drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. According to the CEN/CENELEC Internal Regulations, the national standards organizations of the fo
15、llowing countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Sl
16、ovakia, Slovenia, Spain, Sweden, Switzerland and the United Kingdom. Endorsement notice The text of ISO 1833-17:2006 has been approved by CEN as a EN ISO 1833-17:2010 without any modification. BS EN ISO 1833-17:2010ISO 1833-17:2006(E) ISO 2006 All rights reserved iiiForeword ISO (the International O
17、rganization for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been estab
18、lished has the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardizat
19、ion. International Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting
20、. Publication as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such p
21、atent rights. ISO 1833-17 was prepared by Technical Committee ISO/TC 38, Textiles. This first edition of ISO 1833-17 cancels and replaces Clause 16 of ISO 1833:1977. ISO 1833:1977 will be cancelled and replaced by ISO 1833-1, ISO 1833-3, ISO 1833-4, ISO 1833-5, ISO 1833-6, ISO 1833-7, ISO 1833-8, IS
22、O 1833-9, ISO 1833-10, ISO 1833-11, ISO 1833-12, ISO 1833-13, ISO 1833-14, ISO 1833-15, ISO 1833-16, ISO 1833-17, ISO 1833-18 and ISO 1833-19. ISO 1833 consists of the following parts, under the general title Textiles Quantitative chemical analysis: Part 1: General principles of testing Part 2: Tern
23、ary fibre mixtures Part 3: Mixtures of acetate and certain other fibres (method using acetone) Part 4: Mixtures of certain protein and certain other fibres (method using hypochlorite) Part 5: Mixtures of viscose, cupro or modal and cotton fibres (method using sodium zincate) Part 7: Mixtures of poly
24、amide and certain other fibres (method using formic acid) Part 8: Mixtures of acetate and triacetate fibres (method using acetone) Part 9: Mixtures of acetate and triacetate fibres (method using benzyl alcohol) Part 10: Mixtures of triacetate or polylactide and certain other fibres (method using dic
25、hloromethane) Part 11: Mixtures of cellulose and polyester fibres (method using sulfuric acid) Part 12: Mixtures of acrylic, certain modacrylics, certain chlorofibres, certain elastanes and certain other fibres (method using dimethylformamide) Part 13: Mixtures of certain chlorofibres and certain ot
26、her fibres (method using carbon disulfide/acetone) BS EN ISO 1833-17:2010ISO 1833-17:2006(E) iv ISO 2006 All rights reserved Part 14: Mixtures of acetate and certain chlorofibres (method using acetic acid) Part 15: Mixtures of jute and certain animal fibres (method by determining nitrogen content) P
27、art 16: Mixtures of polypropylene fibres and certain other fibres (method using xylene) Part 17: Mixtures of chlorofibres (homopolymers of vinyl chloride) and certain other fibres (method using sulfuric acid) Part 18: Mixtures of silk and wool or hair (method using sulfuric acid) Part 19: Mixtures o
28、f cellulose fibres and asbestos (method by heating) Part 21: Mixtures of chlorofibres, certain modacrylics, certain elastanes, acetates, triacetates and certain other fibres (method using cyclohexanone) The following parts are under preparation: Part 6: Mixtures of viscose or certain types of cupro
29、or modal or lyocell and cotton fibres (method using formic acid and zinc chloride) Part 20: Mixtures of elastane and certain other fibres (method using dimethylacetamide) Part 22: Mixtures of viscose or certain types of cupro or modal or lyocell and flax fibres (method using formic acid and zinc chl
30、orate) Part 23: Mixtures of polyethylene and polypropylene (method using cyclohexanone) Part 24: Mixtures of polyester and some other fibres (method using phenol and tetrachloroethane) BS EN ISO 1833-17:2010INTERNATIONAL STANDARD ISO 1833-17:2006(E) ISO 2006 All rights reserved 1Textiles Quantitativ
31、e chemical analysis Part 17: Mixtures of chlorofibres (homopolymers of vinyl chloride) and certain other fibres (method using sulfuric acid) 1 Scope This part of ISO 1833 specifies a method, using sulfuric acid, to determine the percentage of chlorofibres, after removal of non-fibrous material, in t
32、extiles made of binary mixtures of chlorofibres based on homopolymers of vinyl chloride (after-chlorinated or not) and cotton, viscose, cupro, modal, acetate, triacetate, polyamide, polyester, certain acrylic and certain modacrylic fibres. The modacrylics concerned are those which give a limpid solu
33、tion when immersed in concentrated sulfuric acid ( = 1,84 g/ml). This method can be used, particularly in place of the methods described in ISO 1833-12 and ISO 1833-13, in all cases where a preliminary test shows that the chlorofibres do not dissolve completely either in dimethylformamide or in the
34、azeotropic mixture of carbon disulfide and acetone. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including
35、 any amendments) applies. ISO 1833-1, Textiles Quantitative chemical analysis Part 1: General principles of testing 3 Principle The constituent other than the chlorofibre is dissolved from a known dry mass of the mixture with concentrated sulfuric acid ( = 1,84 g/ml). The residue, consisting of the
36、chlorofibre, is collected, washed, dried and weighed; its mass, corrected if necessary, is expressed as a percentage of the dry mass of the mixture. The percentage of the second constituent is obtained by the difference. 4 Reagents Use the reagents described in ISO 1833-1 together with those given i
37、n 4.1, 4.2 and 4.3. 4.1 Sulfuric acid, concentrated ( = 1,84 g/ml). BS EN ISO 1833-17:2010ISO 1833-17:2006(E) 2 ISO 2006 All rights reserved4.2 Sulfuric acid, 50 % (mass fraction) aqueous solution. Prepare this reagent by adding carefully, while cooling, 400 ml of sulfuric acid (4.1) to 500 ml of di
38、stilled water. After cooling this solution to room temperature, dilute the solution to 1 l with water. 4.3 Ammonia, dilute solution. Dilute 60 ml of concentrated ammonia solution ( = 0,880 g/ml) to 1 I with distilled water. 5 Apparatus Use the apparatus described in ISO 1833-1 together with those gi
39、ven in 5.1 and 5.2. 5.1 Conical flask, of minimum capacity 200 ml, glass stoppered. 5.2 Glass rod, with flattened end. 6 Test procedure Follow the general procedure given in ISO 1833-1, and then proceed as follows. To the specimen contained in the flask, add 100 ml of the sulfuric acid (4.1) per gra
40、m of specimen. Allow the contents of the flask to remain at room temperature for 10 min, and during that time, stir the test specimen occasionally by means of the glass rod. If a woven or knitted fabric is being treated, wedge it between the wall of flask and the glass rod and exert a light pressure
41、 in order to separate the material dissolved by the sulfuric acid. Decant the liquid through the weighed filter crucible. Add a fresh portion of 100 ml of the sulfuric acid (4.1) to the flask and repeat the same operation. Transfer the contents of the flask to the filter crucible, and transfer the f
42、ibrous residue there with the aid of the glass rod. If necessary, add a little concentrated sulfuric acid (4.1) to the flask in order to remove any fibres adhering to the wall. Drain the filter crucible using suction. After emptying or changing the filter-flask, wash the residue in the crucible succ
43、essively with the 50 % sulfuric acid solution (4.2), the distilled or deionized water, the ammonia solution, and finally with the distilled or deionized water, draining the crucible using suction after each addition until the water drained from the crucible is neutral. Do not apply suction during th
44、e washing operation, but only after the liquid has drained through the crucible. Finally, dry the crucible and residue, then cool and weigh them. 7 Calculation and expression of results Calculate the results as described in the general instructions of ISO 1833-1. The value of d is 1,00. 8 Precision
45、For homogeneous mixtures of textile materials, the confidence limits of results obtained by this method are not greater than 1 for the confidence level of 95 %. BS EN ISO 1833-17:2010ISO 1833-17:2006(E) ISO 2006 All rights reserved 3Bibliography 1 ISO 1833-12, Textiles Quantitative chemical analysis
46、 Part 12: Mixtures of acrylic, certain modacrylics, certain chlorofibres, certain elastanes and certain other fibres (method using dimethylformamide) 2 ISO 1833-13, Textiles Quantitative chemical analysis Part 13: Mixtures of certain chlorofibres and certain other fibres (method using carbon disulfi
47、de/acetone) This page deliberately left blankThis page deliberately left blankBSI is the independent national body responsible for preparing British Standardsand other standards-related publications, information and services. It presents the UK view on standards in Europe and at the international le
48、vel. It is incorporated by Royal Charter.British Standards Institution (BSI)raising standards worldwideBSI Group Headquarters389 Chiswick High Road London W4 4AL UKTel +44 (0)20 8996 9001Fax +44 (0)20 8996 Standards are updated by amendment or revision. Users of British Stan-dards should make sure
49、that they possess the latest amendments or editions.It is the constant aim of BSI to improve the quality of our products and serv-ices. We would be grateful if anyone finding an inaccuracy or ambiguity whileusing this British Standard would inform the Secretary of the technical com-mittee responsible, the identity of which can be found on the inside frontcover.Tel: +44 (0)20 8996 9001 Fax: +44 (0)20 8996 7001BSI offers Members
