1、 ENGINEERING MATERIAL SPECIFICATIONDate Action Revisions 2006 05 03 N-STATUS Replaced by WSS-M4D933-A1 A. Reaume/M. Masserant 2006 04 11 Revised Inserted 3.0; Deleted 3.1, 3.2, 3.8, 3.9 & 4 1991 10 03 Released NB00I10043054128 L.A. Graham Printed copies are uncontrolled Copyright 2006, Ford Global T
2、echnologies, LLC Page 1 of 5 POLYAMIDE 6 (PA6), MODIFIED, FLEXIBLE EXTRUSION WSB-M4D828-A MOLDING COMPOUND NOT TO BE USED FOR NEW DESIGN 1. SCOPE The material defined by this specification is a type 6 polyamide (nylon) polyacrylic elastomer (AMC) modified, flexible extrusion molding compound. 2. APP
3、LICATION This specification was released originally for material used in the seat belt track. NOTICE: This material absorbs and retains moisture. Part design and tolerances must accommodate changes in part dimensions and physical properties due to moisture absorption or loss in the service/assembly
4、environment. 3. REQUIREMENTS 3.0 STANDARD REQUIREMENTS FOR PRODUCTION MATERIALS Material suppliers and part producers must conform to the Companys Standard Requirements For Production Materials (WSS-M99P1111-A). 3.3 CONDITIONING AND TEST CONDITIONS All test values indicated herein are based on mater
5、ial and specimens with moisture content not exceeding 0.2% (test according to ISO 960, Method B/ASTM D 789). All test materials immediately after processing have to be sealed in containers that are impermeable to water vapor. If the moisture content exceeds 0.2%, condition the material for a minimum
6、 of 16 h at 40 - 50 C at a reduced pressure below 133 Pa. Conduct tests in a controlled atmosphere of 23 +/- 2 C and 50 +/- 5% relative humidity. Individual specimens shall not be removed from closed containers until immediately before testing. 3.4 MOLDING COMPOUND 3.4.2 Melt Temperature 218 - 224 C
7、 (ISO 1218, Method B/ASTM D 789, or DSC - ASTM E 794) 3.5 MOLDED TEST SPECIMEN 3.5.1 Preparation of Test Specimens Unless otherwise specified all tests shall be carried out on injection molded one-end gated test specimens. ENGINEERING MATERIAL SPECIFICATIONWSB-M4D828-A Printed copies are uncontrolle
8、d Copyright 2006, Ford Global Technologies, LLC Page 2 of 5 The following dimensions are required: A. 150 min x 10 x 4.0 +/- 0.2 mm (Tensile Bar, ISO 3167) B. 120 x 10 x 4.0 +/- 0.2 mm Specimens with shorter dimensions shall be cut from the center portion of the test specimen A and/or B. The specime
9、ns shall be prepared according to ISO 294. No annealing allowed. 3.5.2 Density 0.99 - 1.03 g/cm3(ISO 1183, Method A/ASTM D 792, Method A1) 3.5.3 Tensile Strength at Max Load, min 21.8 MPa (ISO R 527/ASTM D 638M, 150 min x 10 x 4.0 +/- 0.2 mm specimen, 50 mm/minute test speed) 3.5.3.1 Elongation at B
10、reak, min 177% (Test Method acc. to para 3.5.3) 3.5.4 Flexural Modulus, min 380 MPa (ISO 178/ASTM D 790M, Method I, Procedure A, 80 x 10 x 4.0 +/- 0.2 mm specimen, 64 mm support span) 3.5.5 Shear Modulus at 23 C 144 - 216 MPa (ASTM D 4065, forced constant amplitude, fixed frequency of 1 Hz +/- 15%,
11、strain level below 1%. Specimen approx. 60 x 10 x 4.0 +/- 0.2 mm cut from the center of specimen A. Specimen length between clamps 35-40 mm. Soak time at each temperature interval - 3 minutes minimum). Additionally, a Shear Modulus vs. Temperature curve shall be plotted for -50 to +210 C temperature
12、 range, at 5 C minimum intervals. The plotted curve must be within tolerance range shown on page 5. 3.5.6 Impact Strength, Izod, min (ISO 180, Method A/ASTM D 256, Method A, 80 x 10 x 4.0 +/- 0.2 mm specimen, 10 specimens for each test) 3.5.6.1 At 23 +/- 2 C No break 3.5.6.2 At -40 +/- 2 C 11 kJ/m23
13、5.6.3 At -29 +/- 2 C No break The test specimens must be conditioned for minimum of 6 h at the above specified temperature prior to impact test. Low temperature testing shall be done within the cold box, if not possible, test can be conducted outside, but within 5 s. ENGINEERING MATERIAL SPECIFICAT
14、IONWSB-M4D828-A Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 3 of 5 3.5.7 Heat Deflection Temperature, min (ISO 75/ASTM D 648, 120 x 10 x 4.0 +/- 0.2 mm specimen) 3.5.7.1 At 1.82 MPa 32 C 3.5.7.2 At 0.45 MPa 35 C 3.5.8 Heat Aging Performance (ISO 188/ASTM D 573,
15、 150 +/- 50 air changes/h, 1000 h at 125 +/- 2 C. After heat aging test specimens are to be conditioned in a desiccator for 3 - 5 h at 23 +/- 2 C. Unaged property values shall be determined at the time of the aged properties determination) 3.5.8.1 Tensile Strength at Change +/- 25% (Test Method per
16、para 3.5.3) 3.5.8.2 Impact Strength, Izod Change +/- 25% (Test Method per para 3.5.6.1, specimens to be notched before heat aging) 3.6 FLAMMABILITY (ISO 3795) Burn Rate, max 100 mm/minute The specimen size required for material approval is 355 x 100 x 1.2 +/- 0.1 mm with a smooth surface. 3.7 FOGGIN
17、G (FLTM BO 116-03) Fog Number, min 75 Formation of excessive amounts of clear film or droplets is cause for rejection. 5. GENERAL INFORMATION The information given below is provided for clarification and assistance in meeting the requirements of this specification. 5.1 COEFFICIENT OF LINEAR THERMAL
18、EXPANSION 12-5/C (ASTM D 696) 5.2 MOLD SHRINKAGE (ISO 2577, approx. 150 x 100 x 3.2 +/- 0.2 mm injection molded specimen) 5.2.1 Molding Shrinkage . After 48 h at 23 +/- 2 C With flow 1.0 - 1.1% Transverse to flow 1.5 - 1.6% ENGINEERING MATERIAL SPECIFICATIONWSB-M4D828-A Printed copies are uncontroll
19、ed Copyright 2006, Ford Global Technologies, LLC Page 4 of 5 5.2.2 Post Shrinkage (Separate specimens required for each test) . After 48 h at 80 C 0.1% . After 30 minutes at 120 C 0.5% 5.3 WATER ABSORPTION 0.64% (ISO 62, 24 h/ASTM D 570, 24 h, 50 +/- 1 mm diameter, 3.2 +/- 0.2 mm thick specimen) 5.4
20、 IMPACT STRENGTH, IZOD, min (ISO 180, Method A/ASTM D 256, Method A, 63.5 x 10 x 4.0 +/- 0.2 mm specimen, 10 specimens minimum) 5.4.1 After Moisture Conditioning No break The notched specimens shall be immersed for 48 h in distilled water at 50 +/- 1 C and subsequently conditioned for 1 h at 23 +/- 2 C and 50 +/- 5% relative humidity prior to test and tested under the same conditions within 1 h. 5.5 RECYCLING CODE SAE PA6 OPTIONAL ENGINEERING MATERIAL SPECIFICATIONWSB-M4D828-A Printed copies are uncontrolled Copyright 2006, Ford Global Technologies, LLC Page 5 of 5
