1、 141102010 . (FAME) EN 14110:2003Fat and oil derivatives Fatty acid methyl esters (FAME) Determination of methanol content(IDT) 27 2002 . 184- , 1.02004 . 1 - ( ) , 42 31 3 27 2010 . 1125-4 14110:2003 - . (FAME). - (N 14110:2003 Fat and oil derivatives Fatty acid methyl esters (FAME) Determination o
2、f methanolcontent). - , 5 , - . () . - , , 2012 , - - II 1411020101 .12 13 .14 15 .26 27 38 .39 410 5 () 6 () FAME, .7 () ( ) .8III 141102010 . (FAME) Fat and oil derivatives. Fatty acid methyl esters (FAME).Determination of methanol content 201207011 - (FAME) . 0,01 % . 0,5 % . - FAME, .2 - : 4259:
3、2006 . - (EN ISO 4259:2006, Petroleum products Determination and application ofprecision data in relation to methods of test)3 80 C , . , - -. , . . - . , - .4 . . ., .4.1 99,5 %.4.2 2- 99,5 % ( ).4.3 FAME 0,001 % .1 141102010 FAME - . FAME 90 C .4.4 - , 99 %.5 5.1 20 3.5.2 (, (TFE) Viton1) .5.3 10
4、0,1 .5.4 500 , ( ).5.5 .5.6 1, 2, 5 3.5.7 10 25 3.5.8 , , ( ), - .5.9 , . , (, DB12),SE302) (, DBWAX2), CAR-BOWAX2) 0,5 . - 1012).5.10 - 1 % , , , . . -, , - . , , .5.11 0,0001 .5.12 80 C.5.13 60 C.6 6.1 -, - , , - 1,5 2-.1 :- DB1 ( 30 , 0,32 , 3 );- ( 50 3/);- 150 C;- 50 C;- - () 40 ;- 500 .1) , .2
5、) , -.2 1411020102 :- 80 C;- 45 ;- 500 .6.2 -.7 FAME (4.3) ( ) , . , , 1. .7.1 (0,5 % . FAME) 25 3(253) FAME (4.3) (112 c177 0,1) (142 ) (5.3). - . - .7.2 (0,1 % . FAME)53 25 3- FAME (4.3).7.3 (0,01 % . FAME)13 10 3- FAME (4.3).8 8.1 8.2 : - ( ), ( ).8.1 , .- . 5.10.8.1.1 (5.1) (5 c177 0,01) (5.3) 5
6、 2- (4.2). . 10 (5.12) , 45 . (5.4) 60 C (5.13). 500 ( ) . F - ; 0,01F =()()CSCSiimm,(1) m , % .;Si 2-;i 2- , % .;( 5 2- 5,0 , i= 0,0785 % .);Sm .3 141102010 , , 15 %. , , 7. ( 0,7) 8.1.2.8.1.2 , 8.1.1. m, % ., m=FS CSiim,(2) F , 8.1.1;Sm ;Ci 2- , % .;( 5 2- 5,0 , i= 0,0785 % .);Si 2-.8.2 , - . , .8.2.1 2 3 . - . . , , . d y, Cm= + bSm, (3) Cm , % .;a , (e/d);b , (1/d);d ;e y;Sm . 0,95, - , , 7.8.2.2 , 8.2.1. Cm(%.) (3) 0,01 % .9 , - . -( ) 0,01 % . 0,20 % .9.1 , -4 141102010 , r = 0,056 + 0,001 (4) ( ).9.2 , - , R = 0,221X + 0,003 (5)
