1、MIL-H-2477b 68 999990b 0575982 b MILITARY SPECIFICATION HYDRAZINE TEST KIT, NAVAL SHIPBOARD (METRIC) !METRIC I MIL-H-Z4776(SH) 8 June 1992 This specification is approved for use by the Naval Sea Systems Command, Department of the Navy, and is available for use by all Departments and Agencies of the
2、Department of Defense. 1. SCOPE 1.1 Scope. This specification covers a water testing outfit using an organic dye for the determination of hydrazine in feedwater and boiler water. 2. APPLICABLE DOCUMENTS 2.1 Government documents. 2.1.1 Specifications, standards, and handbooks. The following specifica
3、- tions, standards, and handbooks form a part of this document to the extent specified herein. Unless otherwise specified, the issues of these documents are those listed in the issue of the Department of Defense Index of Specifications and Standards (DODISS) and supplement thereto, cited in the soli
4、citation (see 6.2). SPECIFICATIONS FEDERAL PPP-F-320 - Fiberboard, Corrugated and Solid, Sheer Stock (Con- tainer Grade) and Cut Shapes MILI TARY MIL-P-116 - Preservation, Methods of. MIL-L-19140 - Lumber and Plywood, Fire Retardant Treated STANDARDS FEDERAL FED-STD-313 - Material Safety Data, Trans
5、portation Data and Disposal Data for Hazardous Materials Furnished to Government Activities Beneficial comments (recommendations, additions, deletions) and any pertinent data which may be of use in improving this document should be addressed to: Commander, Naval Sea Systems Command, SEA 5523, Depart
6、ment of the Navy, Washington, DC 20362-5101 by using the self-addressed Standardization Document Improvement Proposal (DD Form 1426) appearing at the end of this document or by letter. AMSC NIA FSC 6810 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Provided by IHS
7、Not for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-H-24776 68 m 777770b 0575783 8 m MIL I TARY MIL-STD-2073-1 - DOD Material Procedures for Development and Ap- plication of Packaging Requirements (Unless otherwise indicated, copies of federal and military specific
8、ations, standards, and handbooks are available from the Standardization Documents Order Desk, Building 4D 700 Robbins Avenue, Philadelphia, PA 19111-5094. 2.2 Non-Government publications. The following documents form a part of this document to the extent specified herein. Unless otherwise specified,
9、 the issues of the documents which are DOD adopted are those listed in the issue of the DODISS cited in the solicitation. Unless otherwise specified, the issues of documents not listed in the DODISS are the issues of the documents cited in the solicitation (see 6.2). AMERICAN SOCIETY FOR TESTING AND
10、 MATERIALS (ASTM) D 1385 - Standard Test Method for Hydrazine in Water. D 3951 - Standard Practice for Commercial Packaging. (DoD adopted) (Application for copies should be addressed to the American Society for Testing and Materials, 1916 Race Street, Philadelphia, PA 19103.) (Non-Government standar
11、ds and other publications are normally available from the organizations that prepare or distribute the documents. These documents also may be available in or through libraries or other informational services.) 2.3 Order of precedence. In the event of a conflict between the text of this document and
12、the references cited herein, (except for related associated detail specifications, specification sheets, or MS standards), the text of this document takes precedence. Nothing in this document, however, supersedes applicable laws and regulations unless a specific exemption has been obtained. 3. REQUI
13、REMENTS 3.1 Definition. The hydrazine test kit measures the amount of hydrazine present in feedwater and boiler water at both the parts per billion (p/b) and the parts per million (plm) level. The kit consists of a plastic sample with breaking device, evacuated ampoules containing test chemicals, an
14、d high and low range color comparators. 3.2 First article. When specified (see 6.2), a sample shall be subjected to first article inspection (see 6.4) in accordance with 4.2.1. 3.3 Characteristics. 3.3.1 Performance. The hydrazine test kit shall measure the amount of hydrazine in feedwater and boile
15、r water between O and 500 p/b using the low range comparator and between O and 100 plm using the high-range conparator at a sample 2 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,- e MIL-H-24776 68 9999906 0575984 T W MIL-H-Z4776(SH) I O temperature
16、 of 21 to 38 degrees Centigrade (OC). The value obtained shall be equal to the readable value nearest to the actual hydrazine level of the sample or to the next readable value above or below this value. Both comparators shall read O when no hydrazine is present. A readable value is defined as equal
17、to the value of a color standard, the average of two adjacent color standards, or greater than the highest color standard. 3.3.2 Physical characteristics. 3.3.2.1 Component parts. The hydrazine test kit shall consist of the following: (a) One low range colorimetric comparator. (b) One high range col
18、orimetric comparator. (c) One box of 30 ampoules. (d) One sample cup. (e) One storage case. 3.3.2.1.1 Low range colorimetric comparator. Details and dimensions of the low range color comparator used for making the hydrazine determinations shall be as shown on figure 1. The comparator shall consist o
19、f a transparent tube in which eight liquid filled, sealed glass standard color ampoules are mounted and enclosed. There shall be a center space into which the test ampoule can be inserted for color comparison. The comparator shall have the color standards representing O, 10, 30, 50, 70, 100, 300, an
20、d 500 p/b hydrazine. These color standards shall range in color from clear to light yellow to yellow. The standard color ampoules shall be fabricated to the same dimensions as the test ampoules, 3.3.2.1.3. The comparator shall be marked with the date of manufacture. The com- parator shall yield the
21、results as specified in table I when tested as specified in 4.5.1. TABLE I. Hydrazine solution values for low range comparator. Standard ( p/b hydrazine) Accepted values (P/b) O 10 30 50 70 1 O0 300 500 O 5, 10, 20 30 * 10.0 50 * 10.0 60, 70, 85 85, 100, 200 300 * 100 400, 500, greater than 500 3.3.
22、2.1.2 Hinh range colorimetric comparator. Details and dimensions of the high range color comparator used for making the hydrazine determinations shall be as shown on figure 2. The high range comparator shall consist of a rack in which nine liquid filled, sealed glass standard color ampoules are moun
23、ted. The comparator shall have the color standards representing O, 5, 10, 15, 20, 40, 60, 3 I Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-H-24776 68 m 9999906 0575985 II P 80, and 100 p/m hydrazine. These color standards shall range in color
24、from clear to yellow to yellowish orange. the same dimensions as the test ampoules, 3.3.2.1.3. The comparator shall be marked with the date of the manufacture. The comparator shall yield the results as specified in table II when tested as specified in 4.5.1. The standard color ampoules shall be fabr
25、icated to TABLE II. Hydrazine solution values for high range comparator. Standard (p/m hydrazine) Accepted values (Ph) O 5 10 15 20 40 60 80 100 O 5 I 2.5 10 i 2.5 15 I 2.5 22.5, 20, 30 40 i 10.0 60 f 10.0 80 f 10.0 90, 100, greater than 100 3.3.2.1.3 Test ampoules. Details and dimensions of the tes
26、t ampoules used in determining the hydrazine content shall be as shown on figure 3. They shall be made of glass, flat on one end and drawn to a tapered hermetically sealed closure at the other end. The tapered end shall be scored so that it breaks easily and evenly. A color-forming reagent shall be
27、contained in each ampoule. This color- forming reagent shall be clear to pale yellow in color with no sediment present. The ampoule shall contain a vacuum so it will self fill when placed in the sample to be tested and the tip is broken. When filled, the ampoule shall contain the sample and reagent.
28、 A small inert gas bubble shall be present in the broken ampoule to facilitate mixing of the sample and reagent. The ampoules shall be packaged 30 to a box with each ampoule in an individual paper divider to hold the ampoules in an orderly manner and to provide some cushioning as shown on figure 3.
29、The ampoules shall yield the results as specified in tables I and II when tested as specified in 4.5.2. Each box of ampoules shall be marked with the date of manufacture. 3.3.2.1.4 Sample CUP. The sample cup shall provide a reservoir for the sample into which the ampoule may be placed, such that whe
30、n the tip of the ampoule is broken, sample will be drawn into the ampoule. The sample cup shall be fabricated from clear plastic, at least 1 mm thick, and require no more than 30 mL of sample. The breaking device shall be an integral part of the cup. The cup shall rinse easily to prevent cross conta
31、mination of the samples. 3.3.2.1.5 StoraRe case. The storage case shall be of corrosion resistant material (that is, plastic or coated steel) with individual compartments for each component of the test kit. Each item in the kit shall be accessible without having to remove another item. The kit shall
32、 provide protection against breakage during normal handling. Packing material shall be used inside the case to prevent breakage during shipment. The case shall close securely using a snap or latch 4 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-I .
33、 MIL-H-29776 68 m 9979906 0575986 3 MIL-H-Z4776(SH) 3.3.3 Color standard stability. The Low Range Comparator and the High Range Comparator shall give the values specified in table I and table II, respectively, for 2 years from the date of manufacture when tested as specified in 4.5.1. 3.3.4 Ampoule
34、stability. The ampoules shall give the values specified in tables I and II for 3 years from the date of manufacture when tested as specified in 4.5.2. 3.4 Material safety data sheet (MSDS). The contracting activity shall be provided a MSDS at the time of contract award. accordance with the requireme
35、nts of FED-STD-313. The MSDS shall be included with each shipment of the material covered by this specification (see 5.5 and 6.5). The MSDS shall be provided in 4. QUALITY ASSURANCE PROVISIONS 4.1 Responsibility for inspection. Unless otherwise specified in the contract or purchase order, the contra
36、ctor is responsible for the performance of all inspection requirements (examinations and tests) as specified herein. Except as otherwise specified in the contract or purchase order, the contractor may use his own or any other facilities suitable for the performance of the inspection requirements spe
37、cified herein, unless disapproved by the Government. The Govern- ment reserves the right to perform any of the inspections set forth in this specification where such inspections are deemed necessary to ensure supplies and services conform to prescribed requirements. 4.1.1 Responsibility for complian
38、ce. All items shall meet all requirements of sections 3 and 5. The inspection set forth in this specification shall become a part of the contractors overall inspection system or quality program. The absence of any inspection requirements in the specification shall not relieve the contractor of the r
39、esponsibility of ensuring that all products or supplies submitted to the Government for acceptance comply with all requirements of the contract. Sampling inspection, as part of the manufacturing operations, is an acceptable practice to ascertain conformance to requirements, however, this does not au
40、thorize submission of known defective material, either indicated or actual, nor does it commit the Government to accept defective material. 4.2 Classification of inspections. The inspection,requirements specified herein are classified as follows: (a) First article inspection (see 4.2.1). (b) Quality
41、 conformance inspection (see 4.2.2). 5 Provided by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-H-24776 68 = 9999906 0575987 5 3.3.2.1.1 through 3.3.2.1.5 3.3.2.1.1 3.3.2.1.2 3.3.2.1.3 . 4.4.1 4.5.1 4.5.1 4.5.2 4.2.1 First article inspection. First articl
42、e inspection shall consist of the examinations and tests shown in table III (see 6.4). Unless otherwise specified (see 6.2), the Naval Ship Systems Systems Engineering Station (NAVSSES), Code 053D, Philadelphia, PA 19112-5083 is responsible for the performance of all inspection requirements. TABLE I
43、II. First article inspection. Inspection Visual and dimensional examination Low range comparator High range comparator Ampou 1 e Requirement I Test method 4.2.2 Quality conformance inspection. Quality conformance inspection shall consist of the visual and dimensional. examination of table III, the c
44、omparator test of 4.5.1, and the ampoule test of 4.5.2 selected in accordance with table IV from each inspection lot (see 6.3). 4.3 Samplinq. 4.3.1 Inspection lot. For purposes of sampling, a lot shall consist of all complete test kits or component parts produced in one batch, in the same facility,
45、under the same conditions, with the same materials and being offered at one time. 4.3.2 Sampling for quality conformance inspection. A random sample of complete test kits or component parts shall be selected from each lot as specified in table IV and inspected in accordance with 4.4.1, 4.5.1 and 4.5
46、.2. If one or more defects is found in any sample, the entire lot shall be rejected. The contractor has the option of screening 100 percent (X) of the rejected lot for the defective characteristic(s) or providing a new lot which shall be inspected in accordance with the sampling plan herein. 6 Provi
47、ded by IHSNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-MIL-H-24776 68 W 9999906 0575988 7 MIL-H-Z4776(SH) Lot size TABLE IV. Sampling for quality conformance inspection. Sample size 50 or less 51 to 90 91 to 150 151 to 280 281 to 500 501 to 1200 4.4 Examination.
48、 5 7 11 13 16 19 4.4.1 Visual and dimensional examination. Each of the complete testing kits or component parts selected in accordance with table IV shall be visually and dimensionally examined to verify compliance with this specification. In addition, the low range and high range comparators and te
49、st ampoules shall be examined for evidence of breakage, leakage and unsatisfactory closure. 4.5 Tests. 4.5.1 Comparator test. The accuracy of the comparator shall be verified using standard hydrazine solutions prepared in accordance with ASTM D 1385. Standard solutions shall be prepared equal to zero p/m hydrazine and at least three other standards covering the range of the comparator to be tested. The standard solutions shall be treated with para-dimethylaminoben
