NSF 60-2017 Drinking Water Treatment Chemicals - Health Effects.pdf

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1、NSF International Standard / American National StandardNSF/ANSI 60 - 2017Drinking Water Treatment Chemicals -Health Effects NSF International, an independent, not-for-profit, non-governmental organization, is dedicated to being the leading global provider of public health and safety-based risk manag

2、ement solutions while serving the interests of all stakeholders. This Standard is subject to revision. Contact NSF to confirm this revision is current. Users of this Standard may request clarifications and interpretations, or propose revisions by contacting: Chair, Joint Committee on Drinking Water

3、Treatment Chemicals c/o NSF International 789 North Dixboro Road, P.O. Box 130140 Ann Arbor, Michigan 48113-0140 USA Phone: (734) 769-8010 Telex: 753215 NSF INTL FAX: (734) 769-0109 E-mail: infonsf.org Web: http:/www.nsf.orgi NSF/ANSI 60 2017 NSF International Standard/ American National Standard fo

4、r Drinking Water Additives Drinking water treatment chemicals Health effects Standard Developer NSF International NSF International Board of Directors Designated as an ANSI Standard April 23, 2017 American National Standards Institute ii Prepared by The NSF Joint Committee on Drinking Treatment Chem

5、icals Recommended for Adoption by The NSF Council of Public Health Consultants Adopted by NSF International December 1987 Revised June 1988 Revised September 2003 Revised September 2014 Revised October 1988 Editorial Revision October 2003 Revised February 2015 Revised May 1996 Addendum December 2003

6、 Revised October 2015 Revised November 1996 Revised November 2004 Revised September 2016 Revised September 1997 Addendum May 2005 Addendum February 2017 Revised October 1999 Revised November 2005 Revised October 2017 Revised May 2000 Revised May 2009 Revised November 2000 Revised December 2009 Revis

7、ed February 2001 Revised May 2011 Addendum September 2001 Addendum March 2012 Revised June 2002 Revised August 2012 Addendum August 2002 Revised January 2014 Published by NSF International PO Box 130140, Ann Arbor, Michigan 48113-0140, USA For ordering copies or for making inquiries with regard to t

8、his Standard, please reference the designation “NSF/ANSI 60 2017.” Copyright 2017 NSF International Previous editions 2016, 2015, 2014, 2013, 2012, 2011, 2010, 2009, 2005, 2004, 2003, 2002, 2001, 2000, 1999, 1997, 1996, 1988, 1987 Unless otherwise specified, no part of this publication may be reprod

9、uced or utilized in any form or by any means, electronic or mechanical, including photocopying and microfilm, without permission in writing from NSF International. Printed in the United States of America. iii Disclaimers1 NSF International (NSF), in performing its functions in accordance with its ob

10、jectives, does not assume or undertake to discharge any responsibility of the manufacturer or any other party. The opinions and findings of NSF represent its professional judgment. NSF shall not be responsible to anyone for the use of or reliance upon this Standard by anyone. NSF shall not incur any

11、 obligations or liability for damages, including consequential damages, arising out of or in connection with the use, interpretation of, or reliance upon this Standard. Participation in NSFs Standards development activities by a representative of a regulatory agency (federal, state, or local) shall

12、not be construed as the agencys endorsement of NSF, its policies, or any of its Standards. This document has been reviewed by the Office of Drinking Water, U.S. Environmental Protection Agency, and approved for publication. Approval does not signify that the contents necessarily reflect the views an

13、d policies of USEPA nor does mention of trade names or commercial products constitute endorsement or recommendation for use. Partial funding by USEPA for the development and implementation of NSF Standard 60 (USEPA Cooperative Agreement #CR-812144) and participation of USEPA representatives in the s

14、tandards development or implementation activities do not constitute USEPAs endorsement of NSF, NSFs policies, or the Standard. NSF Standards provide basic criteria to promote and protect public health. Provisions for safety have not been included in this Standard because governmental agencies or oth

15、er national standards-setting organizations provide safety requirements. Unless otherwise referenced as normative, the Annexes are not considered an integral part of NSF Standards. They are provided as general guidelines to the manufacturer, regulatory agency, user, or certifying organization. 1 The

16、 information contained in this Disclaimer is not part of this American National Standard (ANS) and has not been processed in accordance with ANSIs requirements for an ANS. As such, this Disclaimer may contain material that has not been subjected to public review or a consensus process. In addition,

17、it does not contain requirements necessary for conformance to the Standard. This page is intentionally left blank. v Contents 1 Purpose, scope, and normative references 1 1.1 Purpose 1 1.2 Scope . 1 1.3 Normative references . 1 1.4 Alternate chemicals 2 1.5 Significant figures and rounding . 2 2 Def

18、initions . 2 3 General requirements . 4 3.1 General. 4 3.2 Formulation submission and review . 5 3.3 Sampling, preparation, and analysis of samples . 6 3.4 Contaminant concentrations 6 3.5 Product labeling . 6 3.6 Formulation control 7 3.7 Product traceability . 7 3.8 Conformity assessment requireme

19、nts . 8 3.9 Product security . 8 4 Coagulation and flocculation chemicals . 10 4.1 Coverage 10 4.2 Definitions 10 4.3 General requirements 11 4.4 Sample requirements . 11 4.5 Sample preparation 11 4.6 Analysis 12 4.7 Normalization . 12 4.8 Evaluation of contaminant concentrations . 12 5 Chemicals fo

20、r corrosion and scale control, softening, precipitation, sequestering, and pH adjustment17 5.1 Coverage 17 5.2 Definitions 17 5.3 General requirements 17 5.4 Sample requirements . 18 5.5 Sample preparation 18 5.6 Analysis 18 5.7 Normalization . 18 5.8 Evaluation of contaminant concentrations . 18 6

21、Disinfection and oxidation chemicals . 25 6.1 Coverage 25 6.2 Definitions 25 6.3 General requirements 25 6.4 Sample requirements . 25 6.5 Sample preparation 26 6.6 Analysis 26 6.7 Normalization . 26 6.8 Evaluation of contaminant concentrations . 27 7 Miscellaneous treatment applications. 30 7.1 Cove

22、rage 30 7.2 Definitions 30 7.3 General requirements 30 7.4 Sample requirements . 31 7.5 Sample preparation 31 7.6 Analysis 31 7.7 Normalization . 31 7.8 Evaluation of contaminant concentrations . 31 8 Miscellaneous water supply products . 36 8.1 Coverage 36 vi 8.2 Definitions 36 8.3 General requirem

23、ents 36 8.4 Sample requirements . 37 8.5 Sample preparation 37 8.6 Analysis 37 8.7 Normalization of contaminant concentrations 37 8.8 Evaluation of contaminant concentrations . 41 Annex A Toxicology review and evaluation procedures . 45 Annex B Sampling, preparation, and analysis of samples 73 Annex

24、 C Normative drinking water criteria 99 Annex D Chemical product index 231 Annex E Revisions to the evaluation of bromate 239 Annex F Examples of tamper evidence for bulk shipments 241 vii Foreword2 In response to a competitive request for proposals from the U.S. Environmental Protection Agency (USE

25、PA), a Consortium led by NSF International (NSF) agreed to develop voluntary third-party consensus standards and a certification program for all direct and indirect drinking water additives. Other members of the Consortium include the Water Research Foundation (formerly the American Water Works Asso

26、ciation Research Foundation), the Association of State Drinking Water Administrators, the Conference of State Health and Environmental Managers, and the American Water Works Association. (COSHEM has since become inactive as an organization.) Each organization was represented on a steering committee

27、with oversight responsibility for the administration of the cooperative agreement. The Steering Committee provided guidance on overall administration and management, and the member organizations will remain active after the expiration of the cooperative agreement. The standards were developed using

28、a voluntary consensus process. All parties at interest were represented, including regulatory agencies, industry, and water suppliers; consultants; and other users of products covered by the standards. Two standards for additives products have been adopted. NSF/ANSI 61: Drinking water system compone

29、nts - Health effects currently covers indirect additives. NSF/ANSI 60, and subsequent product certification against it, will replace the USEPA Additives Advisory Program for drinking water treatment chemicals. For more information with regard to USEPAs actions, refer to the July 7, 1988 Federal Regi

30、ster (53FR25586). NSF/ANSI 60 has been developed to establish minimum requirements for the control of potential adverse human health effects from products added to water for its treatment. It does not attempt to include product performance requirements, which are currently addressed in standards est

31、ablished by such organizations as the American Water Works Association, the American Society for Testing and Materials, and the American National Standards Institute. Because this Standard complements the standards of these organizations, it is recommended that products also meet the appropriate req

32、uirements specified in the standards of such organizations. The Standard and the accompanying text are intended for voluntary use by certifying organizations, utilities, regulatory agencies, and/or manufacturers as a basis of providing assurances that adequate health protection exists for covered pr

33、oducts. All references to gallons (gal) are in U.S. gallons. This version of NSF/ANSI 60 2017 includes the following revisions: Issue 76 This issue added language permitting the use of highly substituted carboxymethyl ( 0.4) for drilling and remediation of water wells. Issue 77 Language regarding hy

34、pochlorite storage in section 6 was clarified. Issue 78 Updates were made to several pass/fail values in Annex C - Drinking Water Criteria 2 The information contained in this Foreword is not part of this American National Standard (ANS) and has not been processed in accordance with ANSIs requirement

35、s for an ANS. As such, this Foreword may contain material that has not been subjected to public review or a consensus process. In addition, it does not contain requirements necessary for conformance to the Standard. viii This Standard was developed by the NSF Joint Committee on Drinking Water Additi

36、ves Treatment Chemicals using the consensus process described by the American National Standards Institute. Suggestions for improvement of this Standard are welcome. This Standard is maintained on a Continuous Maintenance schedule and can be opened for comment at any time. Comments should be sent to

37、 Chair, Joint Committee on Drinking Water Additives Treatment Chemicals at standardsnsf.org, or c/o NSF International, Standards Department, PO Box 130140, Ann Arbor, Michigan 48113-0140, USA. ix Consortium Organizations NSF International Popularly referred to as NSF, NSF International is a non-comm

38、ercial agency. It is incorporated under the laws of Michigan as a not-for-profit organization devoted to research, education, and service. It seeks to solve problems involving man and his environment. It wishes to promote health and enrich the quality of life through conserving and improving that en

39、vironment. Its fundamental principle of operation is to serve as a neutral medium in which business and industry, official regulatory agencies, and the public come together to deal with problems involving products, equipment, procedures, and services related to health and the environment. It is conc

40、eived and administered as a public service organization. NSF is perhaps best known for its role in developing Standards and Criteria for equipment, products, and services that bear upon health. NSF was the lead organization in the Consortium responsible for developing this Standard. NSF conducts res

41、earch; tests and evaluates equipment, products, and services for compliance with standards and criteria; and grants and controls the use of NSF registered Marks. NSF offers product certification (Listing Services) for all products covered by its Standards. Each program has established policies gover

42、ning the associated product evaluation, Listing Services, follow-up and enforcement activities. The NSF Listing Mark is widely recognized as a sign that the product or service to which it relates complies with the applicable NSF Standard(s). Water Research Foundation The mission of the Water Researc

43、h Foundation (WRF) is to sponsor practical, applied research in behalf of the drinking water industry of North America. The scope of the research program embraces all aspects of water supply operation, from development and maintenance of water resources to treatment technologies and water quality is

44、sues, from storage and distribution system operations to health effects studies and utility planning and management activities. WRF serves as the centralized industry institution for planning, managing, and funding cooperative research and development in drinking water, including the subsequent tran

45、sfer of technology and results for practical application by the water utility community. WRFs purpose in this cooperative program is to provide a communication link with the water utilities throughout North America and serve as the focal point for identification of research needs of the water supply

46、 industry with respect to the additives program. The Association of State Drinking Water Administrators The Association of State Drinking Water Administrators (ASDWA) is a non-profit organization whose eligible membership is comprised of drinking water program administrators in each of the 50 states

47、 and seven U.S. territories. Through the organization, representatives speak with a collective voice to Congressional committees, the United States Environmental Protection Agency, professional and trade associations, water utilities, and the general public on issues related to state drinking water

48、programs. With its mission of protecting the public health through assurance of high quality drinking water, and promoting responsible, reasonable, and feasible drinking water programs at the state and federal levels, the Association is a valued contributor to the consortium and to the program. It p

49、rovides the link between the additives program and the state drinking water programs. The Conference of State Health and Environmental Managers The Conference of State Health and Environmental Managers (COSHEM), known formerly as the Conference of State Sanitary Engineers (CSSE), is currently inactive as an organization. It brought to the consortium expertise and involvement of state health and environmental program managers. The Conference was the focal point for health concerns of all state environmental programs, including drinking x water, wastewater, air, s

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