1、raising standards worldwideNO COPYING WITHOUT BSI PERMISSION EXCEPT AS PERMITTED BY COPYRIGHT LAWBSI Standards PublicationFootwear Footwear industry guideline for substances of very high concern (Annex XIV of REACH)PD CEN/TR 16417:2012Copyright European Committee for Standardization Provided by IHS
2、under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-National forewordThis Published Document is the UK implementation of CEN/TR 16417:2012. The UK participation in its preparation was entrusted to Technical CommitteeTCI/69, Footwear, leather and c
3、oated fabrics.A list of organizations represented on this committee can be obtained on request to its secretary.This publication does not purport to include all the necessary provisions of a contract. Users are responsible for its correct application. The British Standards Institution 2012Published
4、by BSI Standards Limited 2012 ISBN 978 0 580 77219 1 ICS 61.060Compliance with a British Standard cannot confer immunity from legal obligations.This Published Document was published under the authority of the Standards Policy and Strategy Committee on 30 November 2012.Amendments issued since publica
5、tionDate Text affectedPUBLISHED DOCUMENTPD CEN/TR 16417:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-TECHNICAL REPORT RAPPORT TECHNIQUE TECHNISCHER BERICHT CEN/TR 16417 Oc
6、tober 2012 ICS 61.060 English Version Footwear - Footwear industry guideline for substances of very high concern (Annex XIV of REACH) Chaussures - Lignes directrices pour lindustrie de la chaussure relatives aux substances extrmement proccupantes (Annexe XIV du REACH) Schuhe - Leitfaden fr die Schuh
7、industrie fr sehr bedenkliche Substanzen (Anhang XIV von REACH) This Technical Report was approved by CEN on 27 August 2012. It has been drawn up by the Technical Committee CEN/TC 309. CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denma
8、rk, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE
9、FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG Management Centre: Avenue Marnix 17, B-1000 Brussels 2012 CEN All rights of exploitation in any form and by any means reserved worldwide for CEN national Members. Ref. No. CEN/TR 16417:2012: EPD CEN/TR 16417:2012Copyri
10、ght European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-CEN/TR 16417:2012 (E) 2 Contents Page Foreword 31 Scope 42 Terms and definitions .43 SVHC potentially present in the footwear industry 5
11、3.1 General 53.2 SVHC included in Annex XIV of REACH 63.3 SVHC included in the candidate list of Annex XIV of REACH .7Annex A (informative) Available test methods for the identification of the substances of very high concern given in the future REACH- Annex XIV 16Bibliography . 22PD CEN/TR 16417:201
12、2Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-CEN/TR 16417:2012 (E) 3 Foreword This document (CEN/TR 16417:2012) has been prepared by Technical Committee CEN/TC 309 “Footwear”
13、, the secretariat of which is held by AENOR. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent rights. PD CEN/TR 16417:2012Copyright European Co
14、mmittee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-CEN/TR 16417:2012 (E) 4 1 Scope This Technical Report is intended to provide information on the chemicals listed in the Candidate List / Annex XIV of t
15、he Regulation (EC) 1907/2006, also known as REACH (Registration, Evaluation, Authorisation and Restriction of Chemicals) and their usage and presence in the footwear industry. The Annex XIV, overseen by the ECHA (European Chemicals Agency), is a list of substances subject to authorisation, substance
16、s of very high concern (SVHC). Before the inclusion of a substance in the Annex XIV, the procedure is strictly fixed: A European member state shall propose it to ECHA. ECHA inform all the member states and a first enquiry is carried out in order to include the substance to the candidate list of Anne
17、x XIV. After the agreement of the members state, ECHA includes the substances in the candidate list to Annex XIV. As soon as a substance has been included in the candidate list, it should be taken into account exactly as a SVHC. ECHA prioritises the substances from the Candidate List to determine wh
18、ich ones should be included in the Authorisation List (Annex XIV of REACH) and therefore, subject to authorisation. ECHA regularly submits recommendations to the European Commission, who will decide on the substances to be included in the Authorisation List. Following the evaluation of the Annex XIV
19、 substances, ECHA can take the decision to restrict the substances. This restriction may take the form of an authorisation for use, an authorisation only for specific applications in specified fields or, in some cases, a complete ban on the use of the substance. During the evaluation process, these
20、chemicals are not forbidden or limited in use. The regulation requires that the user shall be informed if one or more of these substances are present in any part of the article in quantity over 0,1 % by weight. This Technical Report shows which of these chemicals may be present in footwear materials
21、 and the footwear industry in order to help shoe manufacturers to collect mandatory information from suppliers regarding the content of these chemicals and, at same time, allow them to provide accurate information to their customers. The test methods reported in Annex A are informative only to ident
22、ify where these chemicals may be found and control the use along the supply chain where their suppliers are not under the jurisdiction of the REACH Regulation. Taking into account final decision of the European Commission, ECHA, implements the Annex XIV and the candidate list to Annex XIV of REACH,
23、every 6 months. This revision interval is difficult to follow by the standardization procedures. Therefore, this document reflects the situation at the date of 20thDecember 2011. This document will be annually revised. This Technical Report does not concern the substances for which restriction have
24、been already enacted under Annex XVII of REACH. NOTE Chemicals that are restricted under Annex XVII, are identified as a category 1 chemical in CEN ISO/TR 16178. 2 Terms and definitions For the purposes of this document, the following terms and definitions apply. PD CEN/TR 16417:2012Copyright Europe
25、an Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-CEN/TR 16417:2012 (E) 5 2.1 Very Persistent and Very Bioaccumulative substance vPvB substance that fulfils the criteria of both the sections below
26、: a) Persistence 1) the half-life in marine, fresh- or estuarine water is higher than 60 days, or 2) the half-life in marine, fresh- or estuarine water sediment is higher than 180 days, or 3) the half-life in soil is higher than 180 days. b) Bioaccumulation 1) the bioconcentration factor is greater
27、than 5 000. 2.2 Persistent, Bioaccumulative and Toxic substance PBT substance that fulfils all three of the criteria of the sections below: a) Persistence 1) the half-life in marine water is higher than 60 days, or 2) the half-life in fresh- or estuarine water is higher than 40 days, or 3) the half-
28、life in marine sediment is higher than 180 days, or 4) the half-life in fresh- or estuarine water sediment is higher than 120 days, or 5) the half-life in soil is higher than 120 days. b) Bioaccumulation 1) the bioconcentration factor (BCF) is higher than 2 000. c) Toxicity 1) the long-term no-obser
29、ved effect concentration (Noec) for marine or freshwater organisms is less than 0,01 mg/l, or 2) the substance is classified as carcinogenic (category 1 or 2), mutagenic (category 1 or 2) or toxic for reproduction (category 1, 2, or 3), or 3) there is other evidence of chronic toxicity, as identifie
30、d by the classifications: T, R48, or Xn, R48 according to Directive 67/548/EEC. 3 SVHC potentially present in the footwear industry 3.1 General The following subclauses contain tables with the substances of very high concern (SVHC) that could be found in the footwear or in the footwear components. P
31、D CEN/TR 16417:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-CEN/TR 16417:2012 (E) 6 3.2 SVHC included in Annex XIV of REACH Table 1 includes the substances of very high co
32、ncern included, at the moment of publication of this Technical Report, in Annex XIV of REACH (see Regulation (EU) N 143/2011 of February 2011). Table 1 Identification of substances of very high concern included in Annex XIV of REACH Regulation (EU) N143/2011 17thFebruary 2011 ID Substance name CAS n
33、umber EC number Group Reason for inclusion Occurrence in Footwear 1.1 5-tert-butyl-2,4,6-trinitro-m-xylene (musk xylene) 81-15-2 201-329-4 vPvB (article 57e) Not used in footwear or footwear components 1.2 4,4- Diaminodiphenylmethane 101-77-9 202-974-4 Aryl amine Carcinogenic (article 57a) Not used
34、as a free compound This substance can be detected after the degradation of: azo colorant, see Annex XVII of Reach) PU material, (false positive result is possible, generated as a marker in testing of PU material) 1.3 Hexabromocyclododecane (HBCDD) and all major diastereoisomers identified ( HBCDD, -
35、HBCDD, -HBCDD) 25637-99-4 and 3194-55-6 (134237-51-7, 134237-50-6, 134237-52-8) 247-148-4and 221-695-9 PBT (article 57d) Not used in footwear or footwear components (flame retardant for electronics) 1.4a Bis (2-ethyl(hexyl)phthalate) (DEHP) 117-81-7 204-211-0 phthalate Toxic for reproduction (articl
36、e 57c) Possible (concentration higher than 0,1 % possible) 1.5aBenzyl butyl phthalate (BBP) 85-68-7 201-622-7 phthalate Toxic for reproduction (article 57c) Possible (concentration higher than 0,1 % possible) 1.6aDibutyl phthalate (DBP) 84-74-2 201-557-4 phthalate Toxic for reproduction (article 57c
37、) Possible (concentration higher than 0,1 % possible) aThese substances are especially important for footwear and footwear components. PD CEN/TR 16417:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted with
38、out license from IHS-,-,-CEN/TR 16417:2012 (E) 7 3.3 SVHC included in the candidate list of Annex XIV of REACH The following tables include the substances of very high concern included, at the moment of publication of this Technical Report, in the candidate list of Annex XIV of REACH. Different tabl
39、es have been drafted to identify the date of inclusion in the candidate list. Table 2 Identification of substances of very high concern included in the candidate list for Annex XIV of REACH Date of inclusion 28thOctober 2008 ID Substance name CAS Number EC Number Group Reason for inclusion Occurrenc
40、e in Footwear 2.1 Bis(tributyltin) oxide (TBTO) 56-35-9 200-268-0 Substances containing tin PBT (article 57d) Not used in footwear or footwear components Use in the past as a preservative agent 2.2aAnthracene 120-12-7 204-371-1 PAHs PBT (article 57d) PAH compound Possible contaminant (recycled mater
41、ials or leather fat liquor) 2.3 Lead hydrogen arsenate 7784-40-9 232-064-2 Arsenic compounds Carcinogenic and toxic for reproduction (articles 57 a and 57 c) Not used in footwear or footwear components 2.4 Triethyl arsenate 15606-95-8 427-700-2 Arsenic compounds Carcinogenic (article 57a) Not used i
42、n footwear or footwear components 2.5 Diarsenic pentaoxide 1303-28-2 215-116-9 Arsenic compounds Carcinogenic (article 57a) Not used in footwear or footwear components 2.6 Diarsenic trioxide 1327-53-3 215-481-4 Arsenic compounds Carcinogenic (article 57a) Not used in footwear or footwear components
43、2.7 Sodium dichromate 7789-12-0 and 10588-01-9 234-190-3 Substances containing chromate Carcinogenic, mutagenic and toxic for reproduction (articles 57a, 57b and 57c) Not used in footwear or footwear components (Cr VI possible in leather at low concentration) 2.8aAlkanes, C10-13,chloro Short Chain C
44、hlorinated paraffins (SCCP) 85535-84-8 287-476-5 Chlorinated aliphates PBT and vPvB (articles 57 d and 57 e) Possible (flame retardant for textile or fat liquor for leather) aThese substances are especially important for footwear and footwear components. PD CEN/TR 16417:2012Copyright European Commit
45、tee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-CEN/TR 16417:2012 (E) 8 Table 3 Identification of substances of very high concern included in the candidate list for Annex XIV of REACH Dates of inclusion
46、13thJanuary 2010 ID Substance name CAS Number EC Number Group Reason for inclusion Occurrence in Footwear 3.1 Coal tar pitch, high temperature 65996-93-2 266-028-2 PAHs Carcinogenic, PBT and vPvB (articles 57a, 57d and 57e) Not used in footwear or footwear components 3.2aDiisobutyl phthalate 84-69-5
47、 201-553-2 Phthalates Toxic for reproduction (article 57c) Possible (concentration higher than 0,1 % possible) 3.3 Tris(2-chloroethyl)phosphate (TCEP) 115-96-8 204-118-5 Tris(2-chloroethyl)phosphate (TCEP) Toxic for reproduction (article 57c) Not used in footwear or footwear components (flame retard
48、ant for furniture, plasticiser for PU-PVC) PD CEN/TR 16417:2012Copyright European Committee for Standardization Provided by IHS under license with CENNot for ResaleNo reproduction or networking permitted without license from IHS-,-,-CEN/TR 16417:2012 (E) 9 Table 3 Identification of substances of very high concern included in the candidate list for Annex XIV of REACH Dates of inclusion 13thJanuary 2010 (continued) ID Substance name CAS Number EC Number Group Reason for inclusion Occurrence in Footwear 3.4 2,4-Dinitrotolue
