1、January 2008DEUTSCHE NORM English price group 6No part of this standard may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS 67.250; 77.150.10!$K:“1
2、402327www.din.deDDIN EN 14392Aluminium and aluminium alloys Requirements for anodised products for use in contact with foodstuffEnglish version of DIN EN 14392:2008-01Aluminium und Aluminiumlegierungen Anforderungen an anodisierte Erzeugnisse, die in Kontakt mit Lebensmitteln kommenEnglische Fassung
3、 DIN EN 14392:2008-01www.beuth.deDocument comprises 10 pagesDIN EN 14392:2008-01 2 National foreword This standard has been prepared by Technical Committee CEN/TC 132 “Aluminium and aluminium alloys”, Working Group WG 9 “Aluminium and aluminium alloys cast and wrought products in contact with food”
4、(Secretariat: AFNOR, France). The responsible German body involved in its preparation was the Normenausschuss Nichteisenmetalle Aluminium. (Nonferrous Metals Standards Committee), Technical Committee NA 066-01-09 AA Anodisch oxidiertes EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN 14392November
5、2007ICS 77.150.10; 67.250English VersionAluminium and aluminium alloys - Requirements for anodisedproducts for use in contact with foodstuffAluminium et alliages daluminium - Spcifications pour lesproduits anodiss destins entrer en contact avec lesalimentsAluminium und Aluminiumlegierungen - Anforde
6、rungen ananodisierte Erzeugnisse, die in Kontakt mit LebensmittelnkommenThis European Standard was approved by CEN on 15 June 2007.CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standa
7、rd without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the CEN Management Centre or to any CEN member.This European Standard exists in three official versions (English, French, German). A version in any other lan
8、guage made by translationunder the responsibility of a CEN member into its own language and notified to the CEN Management Centre has the same status as theofficial versions.CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland
9、,France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal,Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE F
10、R NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2007 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN 14392:2007: EEN 14392:2007 (E) 2 Contents Page Foreword3 1 Scope 4 2 Normative references 4 3 Terms and definitions
11、.4 4 Ordering information.5 5 Chemical composition of the aluminium or aluminium alloy .5 6 Chemical composition of the anodization bath5 7 Sealing 5 7.1 General5 7.2 Composition of the sealing bath5 7.3 Technical parameters of the sealing process.6 7.4 Quality assurance and quality assessment 6 8 D
12、emonstration of conformity with the present standard 7 Annex A (informative) Adeviations8 EN 14392:2007 (E) 3 Foreword This document (EN 14392:2007) has been prepared by Technical Committee CEN/TC 132 “Aluminium and aluminium alloys”, the secretariat of which is held by AFNOR. This document shall be
13、 given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by May 2008 and conflicting national standards shall be withdrawn at the latest by May 2008. Within its programme of work, Technical Committee CEN/TC 132 has entrusted CEN/TC 132/WG
14、9 to prepare the following standard: EN 14392, Aluminium and aluminium alloys Requirements for anodised products for use in contact with foodstuff. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN shall not be held responsible
15、for identifying any or all such patent rights. CEN/TC 132 affirms it is its policy that in the case when a patentee refuses to grant licenses on standardised standard products under reasonable and not discriminatory conditions, then this product shall be removed from the corresponding standard. Acco
16、rding to the CEN/CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Bulgaria, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latv
17、ia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. EN 14392:2007 (E) 4 1 Scope This European Standard specifies requirements for coloured or uncoloured anodic oxidation coatings on wrought and cast prod
18、ucts in aluminium and aluminium alloys for use in contact with food. These requirements cover the chemical composition of the bath, the sealing and the properties of the obtained anodic oxidation coatings. They do not cover dyestuffs and pigments but do cover the metallic deposits produced by electr
19、olytic colouring. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies. EN 601,
20、Aluminium and aluminium alloys Castings Chemical composition of castings for use in contact with foodstuff EN 602, Aluminium and aluminium alloys Wrought products Chemical composition of semi products used for the fabrication of articles for use in contact with foodstuff EN 10204, Metallic products
21、Types of inspection documents EN 12258-1:1998, Aluminium and aluminium alloys Terms and definitions Part 1: General terms EN 12373-1, Aluminium and aluminium alloys Anodizing Part 1: Method for specifying decorative and protective anodic oxidation coatings on aluminium EN 12373-4, Aluminium and alum
22、inium alloys Anodizing Part 4: Estimation of loss of absorptive power of anodic oxidation coatings after sealing by dye spot test with prior acid treatment EN 12373-5, Aluminium and aluminium alloys Anodizing Part 5: Assessment of quality of sealed anodic oxidation coatings by measurement of admitta
23、nce EN 12373-7, Aluminium and aluminium alloys Anodizing Part 7: Assessment of quality of sealed anodic oxidation coatings by measurement of the loss of mass after immersion in phosphoric acid/chromic acid solution with prior acid treatment 3 Terms and definitions For the purposes of this document,
24、the terms and definitions given in EN 12258-1:1998 and the following apply. 3.1 anodic oxidation coating coating obtained by an electrolytic oxidation process, having protective, decorative or functional properties 3.2 sealing treatment of anodic oxide coating to reduce porosity and the absorption c
25、apacity of the coating by hydrothermal processes carried out after anodising EN 14392:2007 (E) 5 3.3 order document document or set of documents agreed between supplier and purchaser at the time of ordering NOTE An order document can be an order of the purchaser confirmed by the supplier or a quotat
26、ion of the supplier confirmed by the purchaser. 4 Ordering information In addition to the information necessary for sufficient definition of the product and its properties as defined by EN 12373-1, order documents shall contain the following information: a) the number of this European Standard; b) a
27、ny requirement on the periodicity of inspection certificates (see Clause 8). 5 Chemical composition of the aluminium or aluminium alloy The chemical composition of the aluminium or aluminium alloys for use in contact with food, intended to be anodised, shall comply with the requirements of EN 601 or
28、 EN 602, as applicable. 6 Chemical composition of the anodization bath The anodization of aluminium or aluminium alloy products intended to be in contact with foodstuff shall be carried out in a diluted aqueous solution of one or more of the following acids: sulfuric acid; sulfomaleic acid; sulfosal
29、icylic acid; oxalic acid; sulfophtalic acid; phosphoric acid. 7 Sealing 7.1 General The anodic oxidation coating shall be sealed unless the coating has been produced in a bath containing only diluted phosphoric acid, or unless the product on which the anodic oxidation coating has been produced will
30、receive another organic or inorganic coating prior to use in contact with food. 7.2 Composition of the sealing bath Sealing shall be done in distilled or demineralized water, which may contain appropriate additives. The inspection certificate shall confirm that the additives and their respective con
31、centrations in the sealing bath comply with current legal requirements. EN 14392:2007 (E) 6 7.3 Technical parameters of the sealing process All the technical parameters of the sealing process, especially the temperature and pH of the bath, the duration of the treatment and the nature and concentrati
32、on of additives shall be chosen to minimise the absorptive power of the anodic oxidation coating and maximise its chemical resistance and to minimizer the migration of potentially hazardous additives. 7.4 Quality assurance and quality assessment The producer shall set up a suitable quality assurance
33、 system in order to monitor the quality of the sealing. The method described in EN 12373-4 and EN 12373-5 shall be used for routine control, and the method described in EN 12373-7 for calibration purpose. NOTE Quality assurance and quality assessment can be done in the framework of a recognised Euro
34、pean quality label such as QUALANOD1). 1)QUALANOD c/o AC Treuhand AG P.O. Box 1507 Tdistrasse 47 CH 8002 Zrich EN 14392:2007 (E) 7 8 Demonstration of conformity with the present standard The anodizing of aluminium and aluminium alloys products for use in contact with food shall be carried out in the
35、 framework of a quality assurance system. This quality assurance system shall allow traceability of a delivered lot to the parameters of the production process that are relevant to the present standard (see Clauses 5 to 7). The manufacturer shall establish an inspection certificate “3.1“ according t
36、o EN 10204 which certifies compliance of the delivered products with the requirements of the present standard. Unless otherwise agreed upon between manufacturer and purchaser, this certificate can be issued at the discretion of the manufacturer either for each delivered lot, or periodically for all
37、products delivered under the present standard within a period of time not exceeding twelve months. EN 14392:2007 (E) 8 Annex A (informative) Adeviations A- deviation: National deviation due to regulations, the alteration of which is for the time being outside the competence of the CEN/CENELEC member
38、. This European Standard does not fall under any Directive of the EU. In the relevant CEN/ CENELEC countries these A-deviations are valid instead of the provisions of the European Standard until they have been removed. Deviation 7.1 (France) The Order of 27th August 1987 concerning aluminium or aluminium alloys materials and objects in contact with foodstuffs, products and food drinks, article 5, enumerates authorized acids put in contact with the above products intended for the French territory.