1、Designation: D 1153 06Standard Specification forMethyl Isobutyl Ketone1, 2This standard is issued under the fixed designation D 1153; the number immediately following the designation indicates the year oforiginal adoption or, in the case of revision, the year of last revision. A number in parenthese
2、s indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.This standard has been approved for use by agencies of the Department of Defense.1. Scope*1.1 This specification covers methyl isobutyl ketone(99.0 % grade).1.2 For s
3、pecific hazard information and guidance, see thesuppliers Material Safety Data Sheet for materials listed in thisspecification.1.3 The following applies to all specified limits in thisstandard; for purposes of determining conformance with thisstandard, an observed value or a calculated value shall b
4、erounded off “to the nearest unit” in the last right-hand digitused in expressing the specificatio limit, in accordance with therounding-off method of Practice E 29.1.4 This standard does not purport to address all of thesafety concerns, if any, associated with its use. It is theresponsibility of th
5、e user of this standard to establish appro-priate safety and health practices and determine the applica-bility of regulatory limitations prior to use.2. Referenced Documents2.1 ASTM Standards:3D 268 Guide for Sampling and Testing Volatile Solventsand Chemical Intermediates for Use in Paint and Relat
6、edCoatings and MaterialD 1078 Test Method for Distillation Range of VolatileOrganic LiquidsD 1209 Test Method for Color of Clear Liquids (Platinum-Cobalt Scale)D 1296 Test Method for Odor of Volatile Solvents andDiluentsD 1353 Test Method for Nonvolatile Matter in VolatileSolvents for Use in Paint,
7、Varnish, Lacquer, and RelatedProductsD 1364 Test Method for Water in Volatile Solvents (KarlFischer Reagent Titration Method)D 1476 Test Method for Heptane Miscibility of LacquerSolventsD 1613 Test Method for Acidity in Volatile Solvents andChemical Intermediates Used in Paint, Varnish, Lacquer,and
8、Related ProductsD 3329 Test Method for Purity of Methyl Isobutyl Ketoneby Gas ChromatographyD 4052 Test Method for Density and Relative Density ofLiquids by Digital Density MeterD 5386 Test Method for Color of Liquids Using TristimulusColorimetryE1 Specification for ASTM Liquid-in-Glass Thermometers
9、E29 Practice for Using Significant Digits in Test Data toDetermine Conformance with SpecificationsE 300 Practice for Sampling Industrial Chemicals2.2 U.S. Federal Specification:PPP-C-2020 Chemicals, Liquid, Dry, and Paste: Packagingof43. Properties3.1 Methyl isobutyl ketone (99.0 % grade) shall conf
10、orm tothe following requirements:1This specification is under the jurisdiction of ASTM Committee D01 on Paintand Related Coatings, Materials, and Applications and is the direct responsibility ofSubcommittee D01.35 on Solvents, Plasticizers, and Chemical Intermediates.Current edition approved June 1,
11、 2006. Published June 2006. Originallyapproved in 1951. Last previous edition approved in 2001 as D 1153 94 (2001).2This compound is also known under the name of 2-methyl -4-pentanone.3For referenced ASTM standards, visit the ASTM website, www.astm.org, orcontact ASTM Customer Service at serviceastm
12、.org. For Annual Book of ASTMStandards volume information, refer to the standards Document Summary page onthe ASTM website.4Available from Standardization Documents Order Desk, DODSSP, Bldg. 4,Section D, 700 Robbins Ave., Philadelphia, PA 19111-5098.1*A Summary of Changes section appears at the end
13、of this standard.Copyright ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.Methyl isobutyl ketone wt %, min 99.0Apparent specific gravity:20/20C 0.800 to 0.803or25/25C 0.796 to 0.799Color, Pt-Co units, maxA15Distillation, CInitial boiling point
14、, min 114.0Dry point, max 117.0Nonvolatile matter, mg/100 mL, max 5OdorBnonresidualWater, wt %, maxC0.1Acidity (free acid as acetic acid), wt % , max 0.01Methyl isobutyl carbinol, wt %, max 0.3_AInstrumental Pt-Co color determined by Test Method D 5386 have been shownto have no statistically signifi
15、cant difference from PT-Co color determined by TestMethod D 1209. However, it is not known whether methyl isobutyl ketone was partof the sample set included in the interlaboratory study.BOptional: Test for odor only when agreed upon as necessary by the purchaserand the supplier.CThis quantitative wa
16、ter limit ensures that the material is miscible withoutturbidity with 19 volumes of 99 % heptane at 20C.4. Sampling4.1 The material shall be sampled in accordance withPractice E 300.5. Test Methods5.1 The properties enumerated in this application shall bedetermined in accordance with the following A
17、STM TestMethods:5.1.1 Apparent Specific GravityDetermine the apparentspecific gravity by any convenient method that is accurate tothe third decimal place, the temperature of both specimen andwater being 20 or 25C. See Guide D 268 or Test MethodD 4052.5.1.2 ColorTest Method D 1209.5.1.3 Distillation
18、RangeTest Method D 1078 using anASTM Solvents Distillation Thermometer having a range from98 to 152C and conforming to the requirements for Thermom-eter 41C as prescribed in Specification E1.5.1.4 Nonvolatile MatterTest Method D 1353.5.1.5 OdorTest Method D 1296.5.1.6 WaterTest Method D 1364 or D 14
19、76.5.1.7 AcidityTest Method D 1613.5.1.8 Alcohol and PurityTest Method D 3329.6. Packaging and Package Marking6.1 Package site shall be agreed upon by the purchaser andthe supplier.6.2 Packaging shall conform to applicable carrier rules andregulations or when specified shall conform to Fed. Spec.PPP
20、-C-2020.7. Keywords7.1 ketones; methyl isobutyl ketone (MIBK); solvents;2-methyl-4-pentanoneSUMMARY OF CHANGESCommittee D01.35 has identified the location of selected changes to this standard since the last issue(D 1153 - 94 (2001) that may impact the use of this standard. (Approved June 1, 2006.)(1
21、) Added reference to Practice E29in Scope section.(2) Added Practice E29to list of Referenced Documents.(3) Changed specs limits for apparent specific gravity in 3.1.(4) Added new footnote A in 3.1.(5) Added Test Method D 5386 to list of ReferencedDocuments.ASTM International takes no position respe
22、cting the validity of any patent rights asserted in connection with any item mentionedin this standard. Users of this standard are expressly advised that determination of the validity of any such patent rights, and the riskof infringement of such rights, are entirely their own responsibility.This st
23、andard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed to ASTM Internat
24、ional Headquarters. Your comments will receive careful consideration at a meeting of theresponsible technical committee, which you may attend. If you feel that your comments have not received a fair hearing you shouldmake your views known to the ASTM Committee on Standards, at the address shown belo
25、w.This standard is copyrighted by ASTM International, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959,United States. Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the aboveaddress or at 610-832-9585 (phone), 610-832-9555 (fax), or serviceastm.org (e-mail); or through the ASTM website(www.astm.org).D1153062
