1、Designation: E 1628 94 (Reapproved 2000)Standard Practice forPreparing Material Safety Data Sheets to IncludeTransportation and Disposal Data for the General ServicesAdministration1This standard is issued under the fixed designation E 1628; the number immediately following the designation indicates
2、the year oforiginal adoption or, in the case of revision, the year of last revision. A number in parentheses indicates the year of last reapproval. Asuperscript epsilon (e) indicates an editorial change since the last revision or reapproval.INTRODUCTIONThere is a need to provide information about ha
3、zardous materials in a systematic way. A guide isrequired to direct those who manufacture, distribute, and use such materials on how to present thenecessary information for a bid or proposal to the General Services Administration.1. Scope1.1 This practice describes how to prepare the informationon h
4、azardous materials as required for employee safety andhealth programs. This practice also provides information onwhat data are required for the safe handling, storage, use,transportation, and environmentally acceptable disposal ofthese materials.2. Referenced Documents2.1 In all cases the current ed
5、ition of the document in effecton the data of invitation for bids or request for a proposal shallapply.2.2 ANSI Standards:2Z400.1 Guideline for the Preparation of Material SafetyData SheetsZ129.1 Hazardous Industrial Chemicals-Precautionary La-beling2.3 U.S. Code of Federal Regulation:310 CFR Energy
6、29 CFR 1910.1200 Hazard Communication29 CFR 1926 Construction Safety and Health Standards39 CFR Postal Service40 CFR Protection of Environment49 CFR 172.101 Hazardous Materials Regulations49 CFR 172.102 Hazardous Materials Regulations49 CFR 171.8 Hazardous Materials Regulations2.4 Other Standards:Ha
7、zardous Products Act (Schedule II)-WHMIS-ControlledProduct Regulations4DOT-HM-181 Regulations5Dangerous Goods Regulations6International Maritime Dangerous Goods Code7AFR 71-4 Packaging and Materials Handling-Preparationof Hazardous Materials for Military Air Shipment8EEC Preparation Directive9EEC Ha
8、zardous Substances Directive9EEC Classification and Labeling of Dangerous Substance93. Terminology3.1 Definitions:3.1.1 exclusionsarticles, as defined by 29 CFR 1910.1200(c), which are not known to pose any physical or health hazardsunder normal conditions of use. These definitions do not applyto en
9、vironmental agents or conditions such as: radiation, noise,heat, cold, etc.3.1.2 hazardous chemicalany chemical which is a physi-cal hazard or a health hazard. Definitions 29 CFR 1910.1200(c).3.1.3 health hazarda chemical for which there is statisti-cally significant evidence based on at least one s
10、tudy conductedin accordance with established scientific principles that acuteor chronic health effects may occur in exposed employees. Theterm health hazard includes chemicals which are carcinogens,toxic or highly toxic agents, reproductive toxins, irritants,1This practice is under the jurisdiction
11、of ASTM Committee E-34 on Occupa-tional Health and Safety and is the direct responsibility of Subcommittee E34.40 onHazard Communications.Current edition approved Sept. 15, 1994. Published November 1994.2Available from American National Standards Institute, 11 W. 42nd St., 13thFloor, New York, NY, 1
12、0036.3Available from Superintendent of Documents, U.S. Government PrintingOffice, Washington, DC 20402.4Available from WHMIS Div., Products Safety Branch, Consumer and Corpo-rate Affairs Canada, Place de Portage Phase, 50 Victoria St., Hull, QC K1A OC9.5Available from Department of Transportation, R
13、esearch and Special ProgramsAdmin., Office of Hazardous Materials Transportation (DHM 51), Washington, DC20590-0001.6Available from International Air Transportation Assn., 200 Peel St., Montreal,Quebec, Canada H3A 2R4.7Available from International Maritime Organization, Intergovernmental Mari-time O
14、rganization, 4 Albert Embankment, London, SE1, 75R England.8Available from U.S. Air Force Regulations NTIS, Springfield, VA 22161.9Available from Office for Publications of the European Communities, 2 RueMercier, L-2985, Luxembourg.1Copyright ASTM, 100 Barr Harbor Drive, West Conshohocken, PA 19428-
15、2959, United States.corrosives, sensitizers, hepatotoxins, nephrotoxins, neurotox-ins, agents which act on the haematopoietic systems and agentswhich damage the lungs, skin, eyes, or mucous membranes.3.1.4 physical hazarda chemical for which there is scien-tifically valid evidence that it is a combu
16、stible liquid, acompressed gas, explosive, flammable, and organic peroxide,an oxidizer, pyrophoric, unstable (reactive) or water-reactive.4. Summary of Practice4.1 This practice indicates what information is required toprepare a General Services Administration bid or proposal. Theinformation to be p
17、rovided includes material safety data sheet,transportation, and disposal data.5. Significance and Use5.1 This practice was developed at the request of theGeneral Services Administration of the United States govern-ment. It is intended to provide guidance and assistance toanyone charged with the resp
18、onsibility of creating or reviewingmaterial safety data sheets (MSDS) for accuracy. Such sheetsare required of any vendor who provides goods or serviceswhich may be hazardous in any way. This guide is not a legaldocument and does not purport to officially represent therequirements of the Occupationa
19、l Safety and Health Adminis-tration Hazard Communication Standard, requirements of EPA(Environmental Protection Agencys Emergency Planning andCommunity Right-To-Know Act), the laws of any state ormunicipality, or the laws of any foreign nation.6. Composition of MSDS6.1 The current version of 29 CFR
20、1910.1200 shall be usedto determine the appropriate information that is required inMSDS for the United States.6.2 ANSI Z400.1 should be used where appropriate. It isrecommended that the proposed phrases contained therein beused where possible.6.3 When new information is available through recognizeds
21、ources, then a revision to a MSDS shall be done within threemonths. (Some jurisdictions require shorter notification peri-ods.)6.4 The information provided in a MSDS shall meet all therequirements of 29 CFR 1910.1200 and shall be as complete aspossible. Where information cannot be found through reco
22、g-nized sources then the words “not available” or an equivalentshall be used. An abbreviation is not recommended. If anabbreviation is used, it should be clearly defined in the MSDS.6.5 Where information is required that does not pertain to asubstance for which a MSDS is being prepared, the words “n
23、otapplicable” or an equivalent shall be used. An abbreviation isnot recommended. If an abbreviation is used, it should beclearly defined in the MSDS.6.6 The preparation of MSDS for countries other than theUnited States often requires additional information. Appropri-ate regulations of the countries
24、must be reviewed to identifywhat additional information must be supplied. For Canada, theHazardous Products Act and Controlled Products Regulationsshould be consulted. For Europe (EEC) the Classification andLabelling of Dangerous substances should be consulted.7. Handling and Storage7.1 The MSDS sha
25、ll indicate when special care must betaken in the handling of materials.7.2 The MSDS shall indicate how materials should bestored to prevent any spills from contaminating the environ-ment or presenting a hazard to employees (that is, dikes, undera roof (cover), in an enclosure, sufficient ventilatio
26、n, etc.)7.3 For reactive substances, MSDS shall indicate howmaterials should be stored so that incompatible substances arenot placed next to each other either vertically or horizontally;that is, oxidizers beside reducers, acids beside bases, etc.7.4 If the material is affected by an environmental co
27、ndition,MSDS shall indicate how materials should be safely stored sothat environmental conditions (sunlight, heat, cold, etc.) do notcreate health and safety hazards.8. Transportation8.1 The MSDS shall be combined with the necessarytransportation documents prepared according to the regulationsgiven
28、by DOT in HM-181.8.2 The following information is required by General Ser-vices Administration in addition to the MSDS:8.2.1 The mode of transportation for the substance,8.2.2 The proper shipping name of the substance.8.2.3 The identification number specified for the shippingname in 49 CFR 172.101.8
29、.2.4 The reportable quantity (RQ), if the substance is listedin the appendix to 49 CFR 172.101.8.2.5 The hazard class of the material,8.2.6 Information for the inner container label should use,where appropriate, the wording specified in ANSI Z129.1.8.2.7 The material of construction of the inner con
30、tainer (theone in direct contact with the substance) and the capacity of theinner container.8.3 In addition when applicable, General Services Admin-istration also requires the following be provided:8.3.1 The number of the DOT specification container,8.3.2 The DOT exemption number or Department of De
31、-fense (DOD) certification control number,8.3.3 Indication of limited quantity as defined by 49 CFR171.8,8.3.4 The chemical name of any aerosol propellants usedwith the substance (should appear in the ingredients section ofthe MSDS), and8.3.5 The total weight of all active Class A and B compo-nents
32、of an explosive that includes primary explosives, sec-ondary explosives, pyrotechnics, and propellants.8.4 Preparation of these additional documents will requirethe use of 10 CFR, 29 CFR 1926, 39 CFR, 40 CFR, 49 CFR172.102, Dangerous Goods Regulations, International Mari-time Dangerous Goods Code, A
33、FR 714, and EEC PreparationDirective and the list of materials in Appendix X1.8.5 The preparation of transportation and hazard communi-cation labels for countries other than the United States oftenrequires additional or different information. HM-181 andforeign hazard communications regulations, such
34、 as CanadasE 16282WHMIS regulations and EECs Dangerous substances direc-tive, must be reviewed for appropriate requirements. Appro-priate regulations of other countries should also be reviewed asnecessary.9. Spill/Disposal Information9.1 The MSDS shall provide sufficient information to de-termine wh
35、at course of action must be taken in the case ofproduct spillage.9.2 The MSDS shall indicate that materials shall be dis-posed of in accordance with all local, state, or federal regula-tions.9.3 The MSDS shall indicate the appropriate actions fordisposal. Actions should also include information abou
36、t per-sonal protective equipment that must be worn while theproduct is being handled.9.3.1 If a material is combined with others material(s) toform a waste, then further precautions might have to be taken.10. Keywords10.1 disposal; hazardous materials; information; materialsafety data sheet; prepara
37、tion; transportation; writingAPPENDIX(Nonmandatory Information)X1. RESOURCESX1.1 The following are additional sources of informationfor preparing documents for the General Services Administra-tion:X1.1.1 Threshold Limit Values for Chemical Substancesand Physical Agents and Biological Exposure Indice
38、s10X1.1.2 Encyclopedia of Occupational Health and Safety11X1.1.3 Registry of Toxic Effects of Chemical Substances(RTECS)12X1.1.4 Hazardous Materials Identification System(HMIS)13X1.1.5 UN-Recommendations on the Transportation ofDangerous Goods14The American Society for Testing and Materials takes no
39、 position respecting the validity of any patent rights asserted in connectionwith any item mentioned in this standard. Users of this standard are expressly advised that determination of the validity of any suchpatent rights, and the risk of infringement of such rights, are entirely their own respons
40、ibility.This standard is subject to revision at any time by the responsible technical committee and must be reviewed every five years andif not revised, either reapproved or withdrawn. Your comments are invited either for revision of this standard or for additional standardsand should be addressed t
41、o ASTM Headquarters. Your comments will receive careful consideration at a meeting of the responsibletechnical committee, which you may attend. If you feel that your comments have not received a fair hearing you should make yourviews known to the ASTM Committee on Standards, at the address shown bel
42、ow.This standard is copyrighted by ASTM, 100 Barr Harbor Drive, PO Box C700, West Conshohocken, PA 19428-2959, United States.Individual reprints (single or multiple copies) of this standard may be obtained by contacting ASTM at the above address or at610-832-9585 (phone), 610-832-9555 (fax), or serv
43、iceastm.org (e-mail); or through the ASTM website (www.astm.org).10Available from Conference of Governmental and Industrial Hygienists(ACGIH), 1014 Broadway, Cincinnati, OH 45202.11Available from International Labour Agency Organization (ILO), 4 Rue DesMorillons, CH-1211, Geneva 22, Switzerland.12Av
44、ailable from National Institute for Occupational Safety and Health(NIOSH), Division of Physical Sciences and Engineering, Cincinnati, OH.13Available from National Paint and Coating Assn. (NPCA), 1500 Rhode IslandAve., Washington, DC 20005.14Available from United Nations, United Nations Bldg., New York, NY 10017.E 16283
