1、March 2014 Translation by DIN-Sprachendienst.English price group 11No part of this translation may be reproduced without prior permission ofDIN Deutsches Institut fr Normung e. V., Berlin. Beuth Verlag GmbH, 10772 Berlin, Germany,has the exclusive right of sale for German Standards (DIN-Normen).ICS
2、83.180!%,.“2099311www.din.deDDIN EN 13999-1Adhesives Short term method for measuring the emission properties of low-solventor solvent-free adhesives after application Part 1: General procedure;English version EN 13999-1:2013,English translation of DIN EN 13999-1:2014-03Klebstoffe Kurzzeit-Verfahren
3、zum Messen der Emissionseigenschaften von lsemittelarmen oderlsemittelfreien Klebstoffen nach der Applikation Teil 1: Allgemeines Verfahren;Englische Fassung EN 13999-1:2013,Englische bersetzung von DIN EN 13999-1:2014-03Adhsives Mthode de mesurage rapide des caractristiques missives des adhsifs ten
4、eur faibleou nulle en solvant aprs application Partie 1: Mode opratoire gn ral;Version anglaise EN 13999-1:2013,Traduction anglaise de DIN EN 13999-1:2014-03SupersedesDIN EN 13999-1:2006-11www.beuth.deDocument comprises 19 pagesIn case of doubt, the German-language original shall be considered autho
5、ritative.02.14DIN EN 13999-1:2014-03 2 A comma is used as the decimal marker. National foreword This document (EN 13999-1:2013) has been prepared by Technical Committee CEN/TC 193 “Adhesives” (Secretariat: AENOR, Spain). The responsible German body involved in its preparation was the Normenausschuss
6、 Kunststoffe (Plastics Standards Committee), Working Committee NA 054-04-06 AA Klebstoffe Terminologie; physikalisch-chemische Prfungen. The DIN Standard corresponding to the International Standard referred to in this document is as follows: ISO 16000-6 DIN ISO 16000-6 Amendments This standard diffe
7、rs from DIN EN 13999-1:2006-11 as follows: a) the foreword now includes a “Safety Statement” and an “Environmental Statement”; b) the definition of VOC has been brought in line with CEN/TS 16516 (Subclause 3.1); c) requirements for the test apparatus (Clause 5) have been brought in line with CEN/TS
8、16516; d) the pre-conditioning operating temperature has been changed from (23 2) C to (23 1) C (Subclause 6.2); e) requirements have been adapted to the new CLP Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging
9、of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006; requirements for the sampling and analysis of emitted substances (Subclause 7.5) have been modified; carcinogenic and sensitizing compounds concentration (Subclause 8.2
10、) has been revised; carcinogenic and sensitizing substances (Annex A) have been revised; f) Annex B (informative) has been deleted because the theoretical background explaining the determination of the specific emission rate is already given in Subclause 8.3.2; g) normative references have been upda
11、ted; h) the standard has been editorially revised. Previous editions DIN V ENV 13999-1: 2001-12 DIN EN 13999-1: 2006-11 DIN EN 13999-1:2014-03 3 National Annex NA (informative) Bibliography DIN ISO 16000-6, Indoor air Part 6: Determination of volatile organic compounds in indoor and test chamber air
12、 by active sampling on Tenax TA sorbent, thermal desorption and gas chromatography using MS/FID DIN EN 13999-1:2014-03 4 This page is intentionally blank EUROPEAN STANDARD NORME EUROPENNE EUROPISCHE NORM EN 13999-1 December 2013 ICS 83.180 Supersedes EN 13999-1:2006English Version Adhesives - Short
13、term method for measuring the emission properties of low-solvent or solvent-free adhesives after application - Part 1: General procedure Adhsifs - Mthode de mesurage rapide des caractristiques missives des adhsifs teneur faible ou nulle en solvant aprs application - Partie 1: Mode opratoire gnral Kl
14、ebstoffe - Kurzzeit-Verfahren zum Messen der Emissionseigenschaften von lsemittelarmen oder lsemittelfreien Klebstoffen nach der Applikation - Teil 1: Allgemeines Verfahren This European Standard was approved by CEN on 19 October 2013. CEN members are bound to comply with the CEN/CENELEC Internal Re
15、gulations which stipulate the conditions for giving this European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN me
16、mber. This European Standard exists in three official versions (English, French, German). A version in any other language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management Centre has the same status as the official versions.
17、 CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Polan
18、d, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and United Kingdom. EUROPEAN COMMITTEE FOR STANDARDIZATION COMIT EUROPEN DE NORMALISATION EUROPISCHES KOMITEE FR NORMUNG CEN-CENELEC Management Centre: Avenue Marnix 17, B-1000 Brussels 2013 CEN All rights of exploitation i
19、n any form and by any means reserved worldwide for CEN national Members. Ref. No. EN 13999-1:2013: EEN 13999-1:2013 (E) 2 Contents Page Foreword 3 Introduction .5 1 Scope 6 2 Normative references 6 3 Terms and definitions .6 4 Principle 6 5 Apparatus .7 5.1 General 7 5.2 Support .7 5.3 Adhesive coat
20、ing device .7 5.4 Emission test chamber .7 5.5 Air supply and mixing facilities 8 5.6 Air sampling devices .9 5.7 Devices for desorption and analysis .9 6 Adhesive sample9 6.1 General 9 6.2 Pre-conditioning 9 6.3 Preparation of a test specimen 9 7 Procedure 10 7.1 Number of determinations . 10 7.2 P
21、reconditioning of the test chamber 10 7.3 Operation of the test chamber . 10 7.4 Starting of the test 10 7.5 Sampling and analysis of emitted substances 10 8 Expression of results . 11 8.1 Calculations . 11 8.2 Carcinogenic and sensitizing compounds concentration . 11 8.3 Volatile organic compounds
22、11 8.3.1 General . 11 8.3.2 Determination of the specific emission rate at the sampling times 11 8.3.3 Determination of the empirical parameters a and b 12 9 Test report . 13 Annex A (normative) Carcinogenic and sensitizing substances 14 Bibliography . 15 DIN EN 13999-1:2014-03 EN 13999-1:2013 (E) 3
23、 Foreword This document (EN 13999-1:2013) has been prepared by Technical Committee CEN/TC 193 “Adhesives”, the secretariat of which is held by AENOR. This European Standard shall be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest b
24、y June 2014, and conflicting national standards shall be withdrawn at the latest by June 2014. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. CEN and/or CENELEC shall not be held responsible for identifying any or all such patent
25、 rights. This document supersedes EN 13999-1:2006. EN 13999-1:2013 includes the following significant technical changes with respect to EN 13999-1:2006: a) In general, the text is adapted to the new CLP Regulation No 1272/2008 11. b) In 6.3, a new Note 2 is added, emphasizing the need that materials
26、 be tested under same conditions using the spreading techniques and the coat weights specific for each application. c) In 7.5, the sampling time is changed (the sampling time at 24 h is eliminated, a sampling time at 72 h is added), and a note is added concerning the possibility of other sampling ti
27、mes, e.g. after 28 days. d) “Specific cumulative emission” (previous 8.3.3) is eliminated. e) The examples from Note to Annex A are eliminated. EN 13999, under the general title Adhesives Short -term method for measuring the emission properties of low-solvent or solvent-free adhesives after applicat
28、ion, consists of the following parts: Part 1: General procedure Part 2: Determination of volatile organic compounds Part 3: Determination of volatile aldehydes Part 4: Determination of volatile diisocyanates SAFETY STATEMENT Persons using this document should be familiar with the normal laboratory p
29、ractice, if applicable. This document does not purport to address all of the safety problems, if any, associated with its use. It is the responsibility of the user to establish appropriate safety and health practices and to ensure compliance with any regulatory conditions. ENVIRONMENTAL STATEMENT It
30、 is understood that some of the material permitted in this European Standard may have negative environmental impact. As technological advantages lead to acceptable alternatives for these materials, they will be eliminated from this European Standard to the extent possible. At the end of the test, th
31、e user of this European Standard should take care to carry out an appropriate disposal of the wastes, according to local regulation. According to the CEN-CENELEC Internal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austr
32、ia, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia, Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, DIN EN 13999-1:2014-03 EN 13999-1:2013 (E) 4 Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portuga
33、l, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and the United Kingdom. DIN EN 13999-1:2014-03 EN 13999-1:2013 (E) 5 Introduction Solvent-free and low-solvent adhesives may release considerable long-term emissions of volatile chemical compounds. Any documentation of emission chara
34、cteristics requires a test method that includes all relevant and potentially hazardous substances. It is essential that the test be reliable and reproducible, give results in a short time to be useful for decisions for development projects, verify that carcinogenic or sensitizing volatile substances
35、 are substantially absent, characterize the emission properties of the adhesive. This can be achieved by sampling the atmosphere around the applied adhesive kept in an environmental test chamber at controlled ambient conditions. DIN EN 13999-1:2014-03 EN 13999-1:2013 (E) 6 1 Scope This European Stan
36、dard describes a conventional standard method for assessing potential emissions from adhesives after their application. This European Standard applies only to “solvent-free” and “low-solvent” adhesives as they are defined in EN 923:2005+A1:2008. The adhesives shall be applicable at room temperature.
37、 2 Normative references The following documents, in whole or in part, are normatively referenced in this document and are indispensable for its application. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amen
38、dments) applies. EN 923:2005+A1:2008, Adhesives Terms and definitions EN 1067, Adhesives Examination and preparation of samples for testing EN 13999-2, Adhesives Short term method for measuring the emission properties of low-solvent or solvent-free adhesives after application Part 2: Determination o
39、f volatile organic compounds EN 13999-3, Adhesives Short term method for measuring the emission properties of low-solvent or solvent-free adhesives after application Part 3: Determination of volatile aldehydes EN 13999-4, Adhesives Short term method for measuring the emission properties of low-solve
40、nt or solvent-free adhesives after application Part 4: Determination of volatile diisocyanates EN ISO 15605, Adhesives Sampling (ISO 15605) EN ISO 16000-9:2006, Indoor air Part 9: Determination of the emission of volatile organic compounds from building products and furnishing Emission test chamber
41、method (ISO 16000-9:2006) ISO 554, Standard atmospheres for conditioning and/or testing Specifications ISO 16000-6:2011, Indoor air Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TA sorbent, thermal desorption and gas chromatography usi
42、ng MS or MS-FID 3 Terms and definitions For the purposes of this document, the terms and definitions given in EN 923:2005+A1:2008, EN ISO 16000-9:2006 and ISO 16000-6:2011 and the following apply. 3.1 volatile organic compounds VOC all volatile organic compounds eluting between and including n-hexan
43、e and n-hexadecane on a gas chromatographic column Note 1 to entry: The measurement is carried out using a capillary column coated with 5 % phenyl / 95 % methyl-poly-siloxane. 4 Principle The test determines the emissions of volatile organic substances from adhesive coatings. Very volatile and mainl
44、y particle bound compounds are not detected with the described procedures. The test is performed in an DIN EN 13999-1:2014-03 EN 13999-1:2013 (E) 7 emission test chamber (Figure 1) at specified constant temperature, relative humidity, air mixing and air exchange. A measurement of the concentrations
45、of the compounds of interest in the air of the exhaust pipe is considered representative of the air in the whole test chamber. Sampling and analysis of the non-polar and slightly polar volatile organic compounds, as defined in ISO 16000-6, shall be carried out as described in EN 13999-2. Sampling an
46、d analysis of the volatile aldehydes shall be carried out as described in EN 13999-3. Sampling and analysis of the volatile isocyanates shall be carried out as described in EN 13999-4. The test includes: qualitative and quantitative determination of carcinogenic and sensitizing substances in an earl
47、y stage after the application of the adhesive sample, determination of the VOC specific emission rate at two points of time. NOTE There are specific applications for which an emission test cell (as described in EN ISO 16000-10 9) can be easier to handle than the emission test chamber, for instance w
48、hen a sample is too small to be properly applied into the test chamber. In these cases, it is possible to apply the procedures as given in this European Standard with the exception that a test cell is used instead of the test chamber. However, as the air flow rate across the sample is higher than wi
49、th the chamber method, the results can only be used with supporting correlation data. 5 Apparatus 5.1 General The test apparatus shall be comprised of the following main components: support, air supply and mixing facilities, emission test chamber with monitoring and control systems, air sampling devices and devices for desorption and analysis. 5.2 Support A clean stainless steel plate or a glass plate shall be used as a substrate for the adhesive to be applied. 5.3 Adh
