1、BRITISH STANDARDBS EN ISO 16000-9:2006Incorporating corrigenda April 2006 and September 2007Indoor air Part 9: Determination of the emission of volatile organic compounds from building products and furnishing Emission test chamber method ICS 13.040.20g49g50g3g38g50g51g60g44g49g42g3g58g44g55g43g50g56
2、g55g3g37g54g44g3g51g40g53g48g44g54g54g44g50g49g3g40g59g38g40g51g55g3g36g54g3g51g40g53g48g44g55g55g40g39g3g37g60g3g38g50g51g60g53g44g42g43g55g3g47g36g58BS EN ISO 16000-9:2006This British Standard was published under the authority of the Standards Policy and Strategy Committee on 31 March 2006 BSI 200
3、8ISBN 978 0 580 60450 8National forewordThis British Standard is the UK implementation of EN ISO 16000-9:2006, incorporating corrigendum December 2007. It is identical with ISO 16000-9:2006, incorporating corrigendum September 2007. It supersedes DD ENV 13419-1:1999 which is withdrawn.The UK partici
4、pation in its preparation was entrusted by Technical Committee EH/2, Air quality, to Subcommittee EH/2/3, Ambient atmospheres. A list of organizations represented on this subcommittee can be obtained on request to its secretary.This publication does not purport to include all the necessary provision
5、s of a contract. Users are responsible for its correct application. Compliance with a British Standard cannot confer immunity from legal obligations.Amendments/corrigenda issued since publicationAmd. No. Date Comments16349 28 April 2006 Addition of supersession details30 May 2008 Implementation of I
6、SO corrigendum September 2007, correction to references in 9.4 (paragraph 1), with CEN endorsement corrigendum December 2007EUROPEAN STANDARDNORME EUROPENNEEUROPISCHE NORMEN ISO 16000-9February 2006ICS 13.040.20 Supersedes ENV 13419-1:1999 English VersionIndoor air - Part 9: Determination of the emi
7、ssion of volatileorganic compounds from building products and furnishing -Emission test chamber method (ISO 16000-9:2006)Air intrieur - Partie 9: Dosage de lmission de compossorganiques volatils de produits de construction et dobjetsdquipement - Mthode de la chambre dessai dmission(ISO 16000-9:2006)
8、Innenraumluftverunreinigungen - Teil 9: Bestimmung derEmission von flchtigen organischen Verbindungen ausBauprodukten und Einrichtungsgegenstnden -Emissionsprfkammer-Verfahren (ISO 16000-9:2006)This European Standard was approved by CEN on 16 January 2006.CEN members are bound to comply with the CEN
9、/CENELEC Internal Regulations which stipulate the conditions for giving this EuropeanStandard the status of a national standard without any alteration. Up-to-date lists and bibliographical references concerning such nationalstandards may be obtained on application to the Central Secretariat or to an
10、y CEN member.This European Standard exists in three official versions (English, French, German). A version in any other language made by translationunder the responsibility of a CEN member into its own language and notified to the Central Secretariat has the same status as the officialversions.CEN m
11、embers are the national standards bodies of Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France,Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania,Slovakia, Slovenia, Spain, Sweden, Switzerla
12、nd and United Kingdom.EUROPEAN COMMITTEE FOR STANDARDIZATIONCOMIT EUROPEN DE NORMALISATIONEUROPISCHES KOMITEE FR NORMUNGManagement Centre: rue de Stassart, 36 B-1050 Brussels 2006 CEN All rights of exploitation in any form and by any means reservedworldwide for CEN national Members.Ref. No. EN ISO 1
13、6000-9:2006: EIncorporating corrigendum December 2007Foreword This document (EN ISO 16000-9:2006) has been prepared by Technical Committee CEN/TC 264 “Air quality“, the secretariat of which is held by DIN, in collaboration with Technical Committee ISO/TC 146 “Air quality“. This European Standard sha
14、ll be given the status of a national standard, either by publication of an identical text or by endorsement, at the latest by August 2006, and conflicting national standards shall be withdrawn at the latest by August 2006. This document supersedes ENV 13419-1:1999. According to the CEN/CENELEC Inter
15、nal Regulations, the national standards organizations of the following countries are bound to implement this European Standard: Austria, Belgium, Cyprus, Czech Republic, Denmark, Estonia, Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Nether
16、lands, Norway, Poland, Portugal, Romania, Slovakia, Slovenia, Spain, Sweden, Switzerland and United Kingdom. BS EN ISO 16000-9:2006iiiContents Page Foreword iv Introduction . vi 1 Scope 1 2 Normative references 1 3 Terms and definitions .2 4 Symbols and abbreviated terms 4 5 Principle4 6 Emission te
17、st chamber system4 7 Apparatus .6 8 Test conditions 6 9 Verification of the test conditions7 10 Test specimens8 11 Emission test chamber preparation.8 12 Test method8 13 Calculation of area specific emission rates and expression of results.9 14 Performance characteristics 10 15 Test report 10 Annex
18、A (normative) System for quality assurance / quality control11 Annex B (informative) Examples of area specific air flow rates in a model room13 Annex C (informative) General description of an emission test chamber 14 Bibliography 15 BS EN ISO 16000-9:2006iv Foreword ISO (the International Organizati
19、on for Standardization) is a worldwide federation of national standards bodies (ISO member bodies). The work of preparing International Standards is normally carried out through ISO technical committees. Each member body interested in a subject for which a technical committee has been established ha
20、s the right to be represented on that committee. International organizations, governmental and non-governmental, in liaison with ISO, also take part in the work. ISO collaborates closely with the International Electrotechnical Commission (IEC) on all matters of electrotechnical standardization. Inte
21、rnational Standards are drafted in accordance with the rules given in the ISO/IEC Directives, Part 2. The main task of technical committees is to prepare International Standards. Draft International Standards adopted by the technical committees are circulated to the member bodies for voting. Publica
22、tion as an International Standard requires approval by at least 75 % of the member bodies casting a vote. Attention is drawn to the possibility that some of the elements of this document may be the subject of patent rights. ISO shall not be held responsible for identifying any or all such patent rig
23、hts. ISO 16000-9 was prepared by the European Committee for Standardization (CEN) Technical Committee CEN/TC 264, Air quality, in collaboration with Technical Committee ISO/TC 146, Air quality, Subcommittee SC 6, Indoor air, in accordance with the Agreement on technical cooperation between ISO and C
24、EN (Vienna Agreement). ISO 16000 consists of the following parts, under the general title Indoor air: Part 1: General aspects of sampling strategy Part 2: Sampling strategy for formaldehyde Part 3: Determination of formaldehyde and other carbonyl compounds Active sampling method Part 4: Determinatio
25、n of formaldehyde Diffusive sampling method Part 5: Measurement strategy for volatile organic compounds (VOCs) Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TA sorbent, thermal desorption and gas chromatography using MS/FID Part 7: Sam
26、pling strategy for determination of airborne asbestos fibre concentrations Part 8: Determination of local mean ages of air in buildings for characterizing ventilation conditions Part 9: Determination of the emission of volatile organic compounds from building products and furnishing Emission test ch
27、amber method Part 10: Determination of the emission of volatile organic compounds from building products and furnishing Emission test cell method Part 11: Determination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of samples and preparation of
28、 test specimens The following parts are under preparation: Part 12: Sampling strategy for polycyclic aromatic hydrocarbons (PAHs), polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzo-furans )PCDFs) and polychlorinated biphenyls (PCBs) BS EN ISO 16000-9:2006v Part 13: Determination of
29、total (gas and particle-phase) polychlorinated dioxin-like biphenyls and polychlorinated dibenzo-p-dioxins/dibenzofurans Collection on sorbent-backed filters with high-resolution gas chromatographic/mass spectrometric analysis Part 14: Sampling strategy for nitrogen dioxide (NO2) Part 15: Measuremen
30、t of nitrogen dioxide (NO2) Part 16: Detection and enumeration of moulds Sampling of moulds by filtration Part 17: Detection and enumeration of moulds Culture-based method BS EN ISO 16000-9:2006vi Introduction The determination of volatile organic compounds (VOCs) emitted from building products usin
31、g emission test chambers in conjunction with the standardised sampling, storage of samples and preparation of test specimens has objectives such as: to provide manufacturers, builders, and end users with emission data useful for the evaluation of the impact of building products on the indoor air qua
32、lity; to promote the development of improved products. The method can in principle be used for most building products used indoors. BS EN ISO 16000-9:20061Indoor air Part 9: Determination of the emission of volatile organic compounds from building products and furnishing Emission test chamber method
33、 1 Scope This part of ISO 16000 specifies a general laboratory test method for determination of the area specific emission rate of volatile organic compounds (VOCs) from newly produced building products or furnishing under defined climate conditions. The method can also, in principle, be applied to
34、aged products. The emission data obtained can be used to calculate concentrations in a model room. This part of ISO 16000 applies to various emission test chambers used for determination of the emission of volatile organic compounds from building products or furnishing. Sampling, transport and stora
35、ge of materials to be tested, and preparation of test specimens are described in ISO 16000-11. Air sampling and analytical methods for the determination of VOCs are described in ISO 16000-6 and ISO 16017-1 11. A general description of an emission test chamber is given in Annex C of this part of ISO
36、16000. For the determination of formaldehyde emissions from wood-based panels, refer to EN 717-1:2004 12. However, ISO 16000-9 is also applicable to wood-based panels and other building products, in order to determine the emission rate of formaldehyde. The measurement procedure for formaldehyde is d
37、escribed in ISO 16000-3 1. 2 Normative references The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.
38、 ISO 554:1976, Standard atmospheres for conditioning and/or testing Specifications ISO 16000-6:2004, Indoor air Part 6: Determination of volatile organic compounds in indoor and test chamber air by active sampling on Tenax TAsorbent, thermal desorption and gas chromatography using MS/FID ISO 16000-1
39、1, Indoor air Part 11: Determination of the emission of volatile organic compounds from building products and furnishing Sampling, storage of samples and preparation of test specimens BS EN ISO 16000-9:20062 3 Terms and definitions For the purposes of this document, the following terms and definitio
40、ns apply. 3.1 air change rate ratio of the volume of clean air brought into the emission test chamber per hour and the free emission test chamber volume measured in identical units 3.2 air flow rate air volume entering into the emission test chamber per time 3.3 air velocity air speed over the surfa
41、ce of the test specimen 3.4 area specific air flow rate ratio between the supply air flow rate and the area of the test specimen 3.5 building product product produced for incorporation in a permanent manner in construction works 3.6 emission test chamber enclosure with controlled operational paramet
42、ers for the determination of volatile organic compounds emitted from building products 3.7 emission test chamber concentration concentration of a specific volatile organic compound, VOCx, (or group of volatile organic compounds) measured in the emission test chamber outlet 3.8 product loading factor
43、 ratio of exposed surface area of the test specimen and the free emission test chamber volume 3.9 recovery measured mass of a target volatile organic compound in the air leaving the emission test chamber during a given time period divided by the mass of target volatile organic compound added to the
44、emission test chamber in the same time period, expressed in percent NOTE The recovery provides information about the performance of the entire method. 3.10 sample part or piece of a building product that is representative of the production 3.11 specific emission rate qmproduct specific rate describi
45、ng the mass of a volatile organic compound emitted from a product per time at a given time from the start of the test NOTE 1 Area specific emission rate, qm,AS, is used in this part of ISO 16000. Several other specific emission rates can be defined according to different requirements, e.g. length sp
46、ecific emission rate, qm,LS, volume specific emission rate, qm,VS, and unit specific emission rate, qm,US. BS EN ISO 16000-9:20063NOTE 2 The term “area specific emission rate“ is sometimes used in parallel with the term “emission factor“. 3.12 target volatile organic compound product specific volati
47、le organic compound 3.13 test specimen part of the sample specially prepared for emission testing in an emission test chamber in order to simulate the emission behaviour of the material or product that is tested 3.14 total volatile organic compound TVOC sum of the concentrations of identified and un
48、identified volatile organic compounds eluting between and including n-hexane and n-hexadecane. NOTE 1 For quantification of the identified compounds, their individual response is used. The areas of the unidentified peaks are converted on molecular mass basis to concentrations using the toluene respo
49、nse factor 2. NOTE 2 Due to practical reasons to be taken into account for test chambers, this definition differs slightly from that defined in ISO 16000-6:2004. In ISO 16000-6, TVOC are related to the sampling medium Tenax TA1)on which the TVOC are adsorbed. 3.15 volatile organic compound VOC organic compound that is emitted from the test specimen and all those detected in the chamber outlet air NOTE 1 Due to practical reasons to be taken into account for test chambers, this definition d
