1、 Standard Test Method Laboratory Testing of Metals for Resistance to Sulfide Stress Cracking and Stress Corrosion Cracking in H2S Environments This NACE International standard represents a consensus of those individual members who have reviewed this document, its scope, and provisions. Its acceptanc
2、e does not in any respect preclude anyone, whether he or she has adopted the standard or not, from manufacturing, marketing, purchasing, or using products, processes, or procedures not in conformance with this standard. Nothing contained in this NACE International standard is to be construed as gran
3、ting any right, by implication or otherwise, to manufacture, sell, or use in connection with any method, apparatus, or product covered by Letters Patent, or as indemnifying or protecting anyone against liability for infringement of Letters Patent. This standard represents minimum requirements and sh
4、ould in no way be interpreted as a restriction on the use of better procedures or materials. Neither is this standard intended to apply in all cases relating to the subject. Unpredictable circumstances may negate the usefulness of this standard in specific instances. NACE International assumes no re
5、sponsibility for the interpretation or use of this standard by other parties and accepts responsibility for only those official NACE International interpretations issued by NACE International in accordance with its governing procedures and policies which preclude the issuance of interpretations by i
6、ndividual volunteers. Users of this NACE International standard are responsible for reviewing appropriate health, safety, environmental, and regulatory documents and for determining their applicability in relation to this standard prior to its use. This NACE International standard may not necessaril
7、y address all potential health and safety problems or environmental hazards associated with the use of materials, equipment, and/or operations detailed or referred to within this standard. Users of this NACE International standard are also responsible for establishing appropriate health, safety, and
8、 environmental protection practices, in consultation with appropriate regulatory authorities if necessary, to achieve compliance with any existing applicable regulatory requirements prior to the use of this standard. CAUTIONARY NOTICE: NACE International standards are subject to periodic review, and
9、 may be revised or withdrawn at any time in accordance with NACE technical committee procedures. NACE International requires that action be taken to reaffirm, revise, or withdraw this standard no later than five years from the date of initial publication and subsequently from the date of each reaffi
10、rmation or revision. The user is cautioned to obtain the latest edition. Purchasers of NACE International standards may receive current information on all standards and other NACE International publications by contacting the NACE International FirstService Department, 15835 Park Ten Place, Houston,
11、Texas 77084-5145 (telephone +1 281-228-6200). Approved 2016-04-18 Revised 2016-03-29 Revised 2005-12-03 NACE International 15835 Park Ten Place Houston, Texas 77084-5145 +1 281-228-6200 ISBN 1-57590-036-X 2016 NACE InternationalANSI/NACE TM0177-2016 Item No. 21212 ANSI/NACE TM0177-2016 NACE Internat
12、ional i _ Foreword This standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide (H2S). This phenomenon is generally termed sulfide stress cracking (SSC) when operating at
13、 room temperature and stress corrosion cracking (SCC) when operating at higher temperatures. In recognition of the variation with temperature and with different materials this phenomenon is herein called environmental cracking (EC). For the purposes of this standard, EC includes only SSC, SCC, and h
14、ydrogen stress cracking (HSC). The primary purpose of this standard is to facilitate conformity in testing so that data from different sources can be compared on a common basis. Consequently, this standard aids the evaluation and selection of all types of metals and alloys, regardless of their form
15、or application, for service in H2S environments. This standard contains methods for testing metals using tensile, bent-beam, C-ring, and double-cantilever-beam (DCB) test specimens. Certain ASTM(1) standard test methods have been listed as references for supplementary tests, creating a comprehensive
16、 test method standard. In addition, the four-point bent-beam test method is also referenced as a supplementary test.1,2 This standard is intended for use by laboratory and materials personnel to facilitate conformity in testing. SSC of metals exposed to oilfield environments containing H2S was recog
17、nized as a materials failure problem by 1952. Laboratory data and field experience have demonstrated that even extremely low concentrations of H2S may be sufficient to lead to SSC failure of susceptible materials. In some cases, H2S can act synergistically with chlorides to produce corrosion and cra
18、cking (SSC and other mode) failures. However, laboratory and operating experiences have also indicated to materials engineers the optimum selection and specification of materials having minimum susceptibility to SSC. This standard covers test methods for SSC (at room temperature) and SCC (at elevate
19、d temperature), but other failure modes (e.g., hydrogen blistering, hydrogen-induced cracking HIC, chloride stress corrosion cracking SCC, pitting corrosion, and mass-loss corrosion) must also be considered when selecting materials for use in sour (H2S -containing) environments. The need for better
20、understanding of the variables involved in EC of metals in oilfield environments and better correlation of data has become apparent for several reasons. New design requirements by the oil and gas production industries call for higher-strength materials that, in general, are more susceptible to EC th
21、an lower-strength alloys. These design requirements have resulted in extensive development programs to obtain more resistant alloys and/or better heat treatments. At the same time, users in the petroleum refining and synthetic fuels industries are pushing present materials much closer to their mecha
22、nical limits. Room-temperature (SSC) failures in some alloys generally are believed to result from hydrogen embrittlement (HE). When hydrogen is cathodically evolved on the surface of a metal (as by corrosion or cathodic charging), the presence of H2S (and other compounds, such as those containing c
23、yanides and arsenic) tends to cause hydrogen atoms to enter the metal rather than to form hydrogen molecules that cannot enter the metal. In the metal, hydrogen atoms diffuse to regions of high triaxial tensile stress or to some microstructural configurations where they become trapped and decrease t
24、he ductility of the metal. Although there are several kinds of cracking damage that can occur in metals, delayed brittle fracture of metals resulting from the combined action of corrosion in an aqueous sulfide environment and tensile stresses (failure may occur at stresses far below the yield stress
25、) is the phenomenon known as SSC. In some cases, however, failure may be the result of localized anodic corrosion processes that may or may not involve hydrogen. In such instances, failure is the result of anodic stress corrosion cracking (SCC). Such failures have historically been termed SSC even t
26、hough their cause may not be hydrogen. This standard was originally published in 1977 by NACE International Task Group T-1F-9, a component of Unit Committee T-1F, “Metallurgy of Oilfield Equipment.” The standard was revised in 1986, 1990, and 1996 by Task Group T-1F-9. It was revised in 2005 and 201
27、6 by Task Group (TG) 085, “Sulfide Corrosion Cracking: Metallic Materials Testing Techniques.” TG 085 is administered by Specific Technology Group (STG) 32, “Oil and Gas ProductionMetallurgy,” and is sponsored by STG 62, “Corrosion Monitoring and (1) ASTM International (ASTM), 100 Barr Harbor Dr., W
28、est Conshohocken, PA 19428-2959. ANSI/NACE TM0177-2016 ii NACE International MeasurementScience and Engineering Applications.” The standard is issued by NACE under the auspices of STG 32. In NACE standards, the terms shall, must, should, and may are used in accordance with the definitions of these t
29、erms in the NACE Publications Style Manual. The terms shall and must are used to state a requirement, and are considered mandatory. The term should is used to state something good and is recommended, but is not considered mandatory. The term may is used to state something considered optional.ANSI/NA
30、CE TM0177-2016 NACE International iii _ NACE International Standard Test Method Laboratory Testing of Metals for Resistance to Sulfide Stress Cracking and Stress Corrosion Cracking in H2S Environments Contents 1. General . 1 2. Environmental Cracking Testing Variability . 2 3. Reagents . 3 4. Test S
31、pecimens and Material Properties . 3 5. Test Vessels and Fixtures . 4 6. Test Solutions . 4 7. Testing at Elevated Temperature/Pressure . 7 8. Method ANACE Standard Tensile Test . 11 9. Method BNACE Standard Bent-Beam Test . 14 10. Method CNACE Standard C-Ring Test 14 11. Method DNACE Standard Doubl
32、e Cantilever Beam Test 14 References 56 APPENDIX Appendix A Safety Considerations in Handling H2S Toxicity (Nonmandatory) 58 Appendix B Explanatory Notes on Environmental Cracking Test Method (Nonmandatory) . 59 Appendix C Determination of H2S Concentration in Test Solution by Iodometric Titration (
33、Nonmandatory) 60 Appendix D Recommendations for Determining Mechanical Quality Assurance of Test Results for Method D (DCB Test) 28 (Nonmandatory) . 63 Appendix E Recommended Method for Determining KIapplied and KLIMIT for the Method D (DCB) Test 29 (Nonmandatory) ) 66 FIGURES Figure 1: Flow Chart o
34、f Significant Factors Influencing the Selection of an NDE Inspection Method 8 Figure 2: Schematic Arrangement of Test Equipment for Method BNACE Standard Bent-Beam Test, Method CNACE Standard C-Ring Test, and Method DNACE Standard Double-Cantilever-Beam Test 9 Figure 3: Tensile Test Specimens . 12 F
35、igure 4: Constant-Load (Dead-Weight) Device 14 Figure 5: Sustained-Load Devices . 15 Figure 6: Applied Stress vs. Log (Time-to-Failure) . 22 Figure 7: Dimensional Drawing of the Standard Bent-Beam Test Specimen 23 Figure 8: Typical Stressing Fixture for Bent-Beam Test Specimen) . 26 Figure 9: Dimens
36、ional Drawing of the C-Ring Test Specimen . 33 Figure 10: Location of Hardness Impressions on DCB Specimen . 42 Figure 11(a): Dimensional Drawing of the DCB Specimen 45 TABLES Table 1 NACE Uniform Material Testing Report Form (Part 1): Testing in Accordance with NACE Standard TM0177(A) Method ANACE
37、Standard Tensile Test . 19 Table 2 NACE Uniform Material Testing Report Form (Part 1): Testing in Accordance with NACE Standard TM0177(A) Method BNACE Standard Bent-Beam Test . 29 Table 3 ANSI/NACE TM0177-2016 NACE International iv NACE Uniform Material Testing Report Form (Part 1): Testing in Accor
38、dance with NACE Standard TM0177(A) Method CNACE Standard C-Ring Test 37 Table 4 Arm Displacements for API and Other Grade Oilfield Tubular Steels in Solution A and 100% H2S 46 Table 5 Arm Displacement for API 5CT Grade C110 in Solution D and 7% H2S . 46 Table 6 Suggested Arm Displacements for Select
39、ed Alloys and Strength Levels in Solution A and 100% H2S 47 Table 7 NACE Uniform Material Testing Report Form (Part 1): Testing in Accordance with NACE Standard TM0177(A) Method DNACE Standard DCB Test . 53 _ ANSI/NACE TM0177-2016 1 NACE International _ Section 1: General 1.1 This standard covers th
40、e testing of metals subjected to tensile stresses for resistance to cracking failure in low-pH aqueous environments containing H2S. Carbon and low-alloy steels are commonly tested for EC resistance at room temperature where SSC susceptibility is typically high. For other types of alloys, the correla
41、tion of EC susceptibility with temperature is more complicated. 1.2 This standard describes reagents, test specimens, and equipment to use; discusses base material and test specimen properties; and specifies the test procedures to follow. This standard describes four test methods: Method AStandard T
42、ensile Test Method BStandard Bent-Beam Test Method CStandard C-Ring Test Method DStandard Double-Cantilever-Beam (DCB) Test Sections 1 through 7 of this standard give general comments that apply to all four test methods. Sections 8 through 11 indicate the test method to follow for each type of test
43、specimen. General guidelines to help to determine the suitability of each test method are given at the beginning of each test method description (Sections 8 through 11). Reporting of the test results is also discussed. 1.3 Metals can be tested for resistance to EC at temperatures and pressures that
44、are either ambient (atmospheric) or elevated. 1.3.1 For testing at ambient conditions, the test procedures can be summarized as follows: Stressed test specimens are immersed in acidified aqueous environments containing H2S. Applied loads at convenient increments can be used to obtain EC data. 1.3.2
45、For testing at temperatures higher than 27 C (80 F), at either atmospheric or elevated pressure, Section 7 describes an alternative test technique. All methods (A, B, C, and D) are adaptable to this technique. 1.4 This standard may be used for release or acceptance testing to ensure that the product
46、 meets a certain minimum level of EC resistance as prescribed in API(2) Specification 5CT,3 ISO(3) 11960,4 or as prescribed by the user or purchaser. This standard may also provide a quantitative measure of the products EC resistance for research or informational purposes. This rating may be based o
47、n: Method AThe highest no-failure uniaxial tensile stress in 720 hours. Method BThe statistically based critical stress factor (Sc) for a 50% probability of failure in 720 hours. Method CThe highest no-failure circumferential stress in 720 hours. Method DThe average KISSC (threshold stress intensity
48、 factor for SSC) for valid tests of replicate test specimens. 1.5 Safety Precautions: H2S is an extremely toxic gas that must be handled with care. (See Appendix A Nonmandatory). (2) American Petroleum Institute (API), 1220 L St. NW, Washington, DC 20005-4070. (3) International Organization for Standardization (ISO), Chemin de Blandonnet 8. Case Postale 401, 1214 Vermier, Geneva, Switzerland. ANSI/NACE TM0177-2016 NACE International 2 _ Section 2: Environmental Cracking Testing Variability 2.1 Interpretation of stress corrosion test results i
